The simple homodinuclear M-M single bonds for group II and XII elements are difficult to obtain as a result of the fulfilled s2electronic configurations,consequently,a dicationic prototype is often utilized to design ...The simple homodinuclear M-M single bonds for group II and XII elements are difficult to obtain as a result of the fulfilled s2electronic configurations,consequently,a dicationic prototype is often utilized to design the M^+-M^+single bond.Existing studies generally use sterically bulky organic ligands L^-to synthesize the compounds in the L^--M^+-M^+-L-manner.However,here we report the design of Mg-Mg and Zn-Zn single bonds in two ligandless clusters,Mg2B7-and Zn2B7-,using density functional theory methods.The global minima of both of the clusters are in the form of M2^2+(B7^3-),where the M-M single bonds are positioned above a quasi-planar hexagonal B7 moiety.Chemical bonding analyses further confirm the existence of Mg-Mg and Zn-Zn single bonds in these clusters,which are driven by the unusually stable B7^3-moiety that is bothσandπaromatic.Vertical detachment energies of Mg2B7-and Zn2B7-are calculated to be 2.79 e V and 2.94 e V,respectively,for the future comparisons with experimental data.展开更多
The current separator with air dense medium fluidized bed can only turn out two products at the same time with a single separating density. The double density fluidized bed means that two separating areas with differe...The current separator with air dense medium fluidized bed can only turn out two products at the same time with a single separating density. The double density fluidized bed means that two separating areas with different densities are formed in a fluidized cascade. In each separating area, the bed density is uniform and meets the technical requirement of coal preparation respectively. Therefore, the processed materials can be separated into three products according to density. In this paper, the fluidized behaviors of binary dense media were experimentally studied and the distribution characteristics of particle concentration and bed density in different bed structure were discussed. The segregation and mixing mechanisms of binary dense media were analyzed. It was testified that the pyramidal part designed in the bed structure played a key role in the formation of double density fluidized bed. The pyramidal part intensified the segregation of binary particles between two separating areas and strengthened the mixing in the low density area, which made for the density uniform of the area.展开更多
基金supported by the National Key R&D Program of China(No.2018YFE0115000)the Natural Science Foundation of Tianjin City(No.19JCYBJC19600)。
文摘The simple homodinuclear M-M single bonds for group II and XII elements are difficult to obtain as a result of the fulfilled s2electronic configurations,consequently,a dicationic prototype is often utilized to design the M^+-M^+single bond.Existing studies generally use sterically bulky organic ligands L^-to synthesize the compounds in the L^--M^+-M^+-L-manner.However,here we report the design of Mg-Mg and Zn-Zn single bonds in two ligandless clusters,Mg2B7-and Zn2B7-,using density functional theory methods.The global minima of both of the clusters are in the form of M2^2+(B7^3-),where the M-M single bonds are positioned above a quasi-planar hexagonal B7 moiety.Chemical bonding analyses further confirm the existence of Mg-Mg and Zn-Zn single bonds in these clusters,which are driven by the unusually stable B7^3-moiety that is bothσandπaromatic.Vertical detachment energies of Mg2B7-and Zn2B7-are calculated to be 2.79 e V and 2.94 e V,respectively,for the future comparisons with experimental data.
文摘The current separator with air dense medium fluidized bed can only turn out two products at the same time with a single separating density. The double density fluidized bed means that two separating areas with different densities are formed in a fluidized cascade. In each separating area, the bed density is uniform and meets the technical requirement of coal preparation respectively. Therefore, the processed materials can be separated into three products according to density. In this paper, the fluidized behaviors of binary dense media were experimentally studied and the distribution characteristics of particle concentration and bed density in different bed structure were discussed. The segregation and mixing mechanisms of binary dense media were analyzed. It was testified that the pyramidal part designed in the bed structure played a key role in the formation of double density fluidized bed. The pyramidal part intensified the segregation of binary particles between two separating areas and strengthened the mixing in the low density area, which made for the density uniform of the area.
