The flexibility of MIP technology to meet market demand is mainly introduced in this study. Their commercial application and technical principle are analyzed too. The MIP technology with wide feed adaptability can for...The flexibility of MIP technology to meet market demand is mainly introduced in this study. Their commercial application and technical principle are analyzed too. The MIP technology with wide feed adaptability can form a good combination with other technologies. The MIP technology has been applied extensively in China. Based on this platform, the CGP, MIP-LTG and MIP-DCR technologies have been developed, which can further improve the flexibility of MIP technology. Based on its novel reaction control technique with a sole sequential two-zone riser, the MIP users can easily switch to different operating modes between producing either more clean gasoline and propylene or diesel through changing the catalysts and varying the operating conditions. That offers MIP users with enough production flexibility and a rational production arrangement to meet the market demand. The MIP-DCR technology with less dry gas and coke yields can provide a more flexible operating mode since the catalysts to oil ratio has become an independent variable.展开更多
The applicability of a commercial Pt-Sn/Al2O3 isobutane dehydrogenation catalyst in dehydrogenation of propane was studied. Catalyst performance tests were carded out in a fixed-bed quartz reactor under different oper...The applicability of a commercial Pt-Sn/Al2O3 isobutane dehydrogenation catalyst in dehydrogenation of propane was studied. Catalyst performance tests were carded out in a fixed-bed quartz reactor under different operating conditions. Generally, as the factors improving propane conversion decrease the propylene selectivity, the optimal operating condition to maximize propylene yield is expected. The optimal condition was obtamed by the experimental design method. The investigated parameters were temperature, hydrogen/hydrocarbon （HE/HC） ratio and space velocity, being changed in three levels. Constrains such as the susceptibility of the catalyst components to sintering or phase transformation were also taken into account. Activity, selectivity and stability of the catalyst were considered as the measured response factors, while the space-time-yield （STY） was considered as the variable to be optimized due to its commercial interest. A STY of 16 mol.kg^-1.h^-1 was achieved under the optimal conditions of T= 620 ℃, H2/HC = 0.6 and, weight hourly space velocity （WHSV） = 2.2 h^-1. Single carbon-carbon bond rupture was found to be the main route for the formation of lower hydrocarbon byproducts.展开更多
文摘The flexibility of MIP technology to meet market demand is mainly introduced in this study. Their commercial application and technical principle are analyzed too. The MIP technology with wide feed adaptability can form a good combination with other technologies. The MIP technology has been applied extensively in China. Based on this platform, the CGP, MIP-LTG and MIP-DCR technologies have been developed, which can further improve the flexibility of MIP technology. Based on its novel reaction control technique with a sole sequential two-zone riser, the MIP users can easily switch to different operating modes between producing either more clean gasoline and propylene or diesel through changing the catalysts and varying the operating conditions. That offers MIP users with enough production flexibility and a rational production arrangement to meet the market demand. The MIP-DCR technology with less dry gas and coke yields can provide a more flexible operating mode since the catalysts to oil ratio has become an independent variable.
基金Supported by the Petrochemical Research&Technology Co. of National Petrochemical Co.
文摘The applicability of a commercial Pt-Sn/Al2O3 isobutane dehydrogenation catalyst in dehydrogenation of propane was studied. Catalyst performance tests were carded out in a fixed-bed quartz reactor under different operating conditions. Generally, as the factors improving propane conversion decrease the propylene selectivity, the optimal operating condition to maximize propylene yield is expected. The optimal condition was obtamed by the experimental design method. The investigated parameters were temperature, hydrogen/hydrocarbon （HE/HC） ratio and space velocity, being changed in three levels. Constrains such as the susceptibility of the catalyst components to sintering or phase transformation were also taken into account. Activity, selectivity and stability of the catalyst were considered as the measured response factors, while the space-time-yield （STY） was considered as the variable to be optimized due to its commercial interest. A STY of 16 mol.kg^-1.h^-1 was achieved under the optimal conditions of T= 620 ℃, H2/HC = 0.6 and, weight hourly space velocity （WHSV） = 2.2 h^-1. Single carbon-carbon bond rupture was found to be the main route for the formation of lower hydrocarbon byproducts.
