Mg-x(Ti0.9 Zr0.2 Mn1.5 Cr0.3)(x=20%,30%,40%) (mass fraction) composite powders were prepared by reactive ball milling with hydrogen and their hydrogen storage properties and microstructure were investigated by XRD,SEM...Mg-x(Ti0.9 Zr0.2 Mn1.5 Cr0.3)(x=20%,30%,40%) (mass fraction) composite powders were prepared by reactive ball milling with hydrogen and their hydrogen storage properties and microstructure were investigated by XRD,SEM and pressure-composition-temperature measurement.The results show that the composites have 3.83%-5.07%hydrogen capacity at 553 K and good hydrogenation kinetics,even at room temperature.Among them,the milled Mg-30%(Ti0.9Zr0.2Mn1.5Cr0.3)composite has the highest hydrogenation kinetics as it can quickly absorb 2.1%hydrogen at 373 K,3.5%in 2 000 s at 473 K,even 3.26%in 60 s at 553 K under 3 MPa hydrogen pressure.The improved hydrogenation properties come from the catalytic effect of Ti0.9 Zr0.2 Mn1.5 Cr0.3 particles dispersed uniformly on the surface of Mg particles.展开更多
A cable dome has no stiffness or load carrying capacity unless it has been prestressed.Analyses of cable domes are based on successful prestressing designs,making force finding analysis very important.A new force find...A cable dome has no stiffness or load carrying capacity unless it has been prestressed.Analyses of cable domes are based on successful prestressing designs,making force finding analysis very important.A new force finding method named the imbal-ance force iterative method is proposed,which can overcome some limitations of the integrity feasible prestressing method.For instance,even if groups are assigned by mistake,the pretension distribution that satisfies the known geometry form can also be found.This method possess good stability and calculation efficiency,and a case study indicates that it is applicable to the force finding of large and complicated cable domes.On the other hand,form finding analysis of cable domes is also a key engineering problem.However,rigid displacement occurs in this process,which makes the analysis more complex.In this pa-per,the dynamic relaxation method was selected,and the problem of rigid displacement was therefore effectively solved.The method includes two steps:first,the stretching cables are released,and secondly,an axial force is imposed on the two ends of each released cable.This method is convenient in its calculation and clear in its conception.A case study indicates that the method is suitable for the simulation of the construction process of various cable domes and cable-strut tension structures.Moreover,a form finding experiment was conducted on a model of a cable dome with a diameter of 4.8 m by tensing diagonal cables.The behavior of the model in the form finding process was investigated.The experimental results indicate that the ini-tial lengths of members and prestress loss are key issues in cable domes design.The results also prove that the methods of form finding and force finding proposed in this paper are reliable and effective.展开更多
A novel lateral flow immunoassay biosensor,combining the receptor-ligand reaction and antigen-antibody reaction was developed for the detection of β-lactam antibiotics in milk. The receptor protein, the carboxy-termi...A novel lateral flow immunoassay biosensor,combining the receptor-ligand reaction and antigen-antibody reaction was developed for the detection of β-lactam antibiotics in milk. The receptor protein, the carboxy-terminal domain of β-lactam sensor-transducer mutant from Bacillus.licheniformis, served as the recognition element. Colloidal gold(CG)-labelled receptor antibody-receptor ternary complex was applied as a signal transducer probe. The presence ofβ-lactams was identified through a color change in the test zone, where the reaction between the complex of CG/antireceptor antibody/receptor and β-lactam antigen on the test line could be inhibited by β-lactam residues in the sample,thus leading to a reduction in color signal. Based on the indirect labeling of the receptor with an antibody as a linker, the ability to detect 33 β-lactams was below or near the corresponding maximum residue limit. The proposed lateral flow immunoassay biosensor appears to be an excellent field-based screening tool for the qualitative screening of β-lactams in milk.展开更多
基金Projects(20833009,20873148,U0734005) supported by the National Natural Science Foundation of ChinaProject(2010CB631303) supported by the National Basic Research Program of China+2 种基金Project(2009A11GX052) supported by Dalian Science and Technology Foundation,ChinaProject(KFJJ10-1Z) supported by the State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,ChinaProject(Y4090507) supported by the Zhejiang Basic Research Program of China
文摘Mg-x(Ti0.9 Zr0.2 Mn1.5 Cr0.3)(x=20%,30%,40%) (mass fraction) composite powders were prepared by reactive ball milling with hydrogen and their hydrogen storage properties and microstructure were investigated by XRD,SEM and pressure-composition-temperature measurement.The results show that the composites have 3.83%-5.07%hydrogen capacity at 553 K and good hydrogenation kinetics,even at room temperature.Among them,the milled Mg-30%(Ti0.9Zr0.2Mn1.5Cr0.3)composite has the highest hydrogenation kinetics as it can quickly absorb 2.1%hydrogen at 373 K,3.5%in 2 000 s at 473 K,even 3.26%in 60 s at 553 K under 3 MPa hydrogen pressure.The improved hydrogenation properties come from the catalytic effect of Ti0.9 Zr0.2 Mn1.5 Cr0.3 particles dispersed uniformly on the surface of Mg particles.
文摘A cable dome has no stiffness or load carrying capacity unless it has been prestressed.Analyses of cable domes are based on successful prestressing designs,making force finding analysis very important.A new force finding method named the imbal-ance force iterative method is proposed,which can overcome some limitations of the integrity feasible prestressing method.For instance,even if groups are assigned by mistake,the pretension distribution that satisfies the known geometry form can also be found.This method possess good stability and calculation efficiency,and a case study indicates that it is applicable to the force finding of large and complicated cable domes.On the other hand,form finding analysis of cable domes is also a key engineering problem.However,rigid displacement occurs in this process,which makes the analysis more complex.In this pa-per,the dynamic relaxation method was selected,and the problem of rigid displacement was therefore effectively solved.The method includes two steps:first,the stretching cables are released,and secondly,an axial force is imposed on the two ends of each released cable.This method is convenient in its calculation and clear in its conception.A case study indicates that the method is suitable for the simulation of the construction process of various cable domes and cable-strut tension structures.Moreover,a form finding experiment was conducted on a model of a cable dome with a diameter of 4.8 m by tensing diagonal cables.The behavior of the model in the form finding process was investigated.The experimental results indicate that the ini-tial lengths of members and prestress loss are key issues in cable domes design.The results also prove that the methods of form finding and force finding proposed in this paper are reliable and effective.
基金financially supported by the National Key R&D Program of China (2019YFC1606603)。
文摘A novel lateral flow immunoassay biosensor,combining the receptor-ligand reaction and antigen-antibody reaction was developed for the detection of β-lactam antibiotics in milk. The receptor protein, the carboxy-terminal domain of β-lactam sensor-transducer mutant from Bacillus.licheniformis, served as the recognition element. Colloidal gold(CG)-labelled receptor antibody-receptor ternary complex was applied as a signal transducer probe. The presence ofβ-lactams was identified through a color change in the test zone, where the reaction between the complex of CG/antireceptor antibody/receptor and β-lactam antigen on the test line could be inhibited by β-lactam residues in the sample,thus leading to a reduction in color signal. Based on the indirect labeling of the receptor with an antibody as a linker, the ability to detect 33 β-lactams was below or near the corresponding maximum residue limit. The proposed lateral flow immunoassay biosensor appears to be an excellent field-based screening tool for the qualitative screening of β-lactams in milk.
