To optimize industrial Fischer-Tropsch (IT) synthesis with the slurry bubble column reactor (SBCR) and iron- based catalyst, a comprehensive process model for IT synthesis that includes a detailed SBCR model, gas ...To optimize industrial Fischer-Tropsch (IT) synthesis with the slurry bubble column reactor (SBCR) and iron- based catalyst, a comprehensive process model for IT synthesis that includes a detailed SBCR model, gas liquid separation model, simplified CO2 removal model and tail gas cycle model was developed. An effective iteration algorithm was proposed to solve this process model, and the model was validated by industrial demonstration experiments data (SBCR with 5.8 m diameter and 30 m height), with a maximum relative error 〈 10% for predicting the SBCR performances. Subsequently, the proposed model was adopted to optimize the industrial SBCR performances simultaneously considering process and reactor parameters variations. The results show that C5+yield increases as catalyst loading increases within 10-70 ton and syngas H2/CO value decreases within 1.3-1.6, but it doesn't increase obviously when the catalyst loading exceeds 45 ton (about 15 wt% concentration). Higher catalyst loading will result in higher difficulty for wax/catalyst separation and higher catalyst cost. There- fore, the catalyst loading (45 ton) is recommended for the industrial demonstration SBCR operation at syngas H2/ CO = 1.3, and the C5 + yield is about 402 ton" per day, which has an about 16% increase than the industrial dem- onstration run result.展开更多
Danckwert’s method was used to determine the specific interfacial area, a, and the individual mass transfer coefficient, kL, during absorption of CO2 in a bubble column with an anionic surfactant in the carbonate-bi...Danckwert’s method was used to determine the specific interfacial area, a, and the individual mass transfer coefficient, kL, during absorption of CO2 in a bubble column with an anionic surfactant in the carbonate-bicarbonate buffer solution and NaAsO2 as catalyst, the presence of which decreases the specific interfacial area and the individual mass transfer coefficient. The specific interfacial area and the individual mass transfer coefficient increase with increasing su- perficial gas velocity. The specific interfacial area decreases whereas the individual mass transfer coefficient increases with increasing temperature. The results of experiments were used to determine the dependence of a, kL, and kLa on the surface tension, the temperature of the absorption phase, and the superficial velocity of the gas. The calculated results from the correlation were found to be within 10% deviation from the actual experimental results.展开更多
Acetic anhydride is the important organic chemical raw material, and is used widely in chemical industry,pharmaceutical industry, dyes, spices and other fields. In this paper, the process of carbonylation of methyl ac...Acetic anhydride is the important organic chemical raw material, and is used widely in chemical industry,pharmaceutical industry, dyes, spices and other fields. In this paper, the process of carbonylation of methyl acetate in rhodium iodine catalyst system was studied, and the suitable reaction conditions were determined.At the same time, the kinetic model was established. The optimum reaction conditions were as follows: the reaction pressure was 5 MPa, the hydrogen content was 8%, the amount of iodomethane was 15%, the amount of lithium iodide was 3%, the reaction temperature was 150 ℃ and the reaction time is 3 h. Under the above reaction conditions, the selectivity of the reaction is close to 100% and the conversion is as high as 92%. The macroscopic kinetic model of the reaction was established in the temperature range of 120 ℃–150 ℃. The reaction is an irreversible reaction without the formation of by-products and the dynamic equation is also given in the Conclusions section.展开更多
The CGP series FCC catalysts for manufacture of clean gasoline and propylene and the catalyst RSC-2006 for processing inferior residuum with high yield of light distillates are novel catalysts jointly developed by Qil...The CGP series FCC catalysts for manufacture of clean gasoline and propylene and the catalyst RSC-2006 for processing inferior residuum with high yield of light distillates are novel catalysts jointly developed by Qilu Catalyst Branch Company of SINOPEC Corp. and the Research Institute of Petroleum Processing (RIPP). The results of commercial application of these catalysts have revealed that they can satisfactorily meet the requirements for environmental protection, good economic benefits and capability for processing inferior FCC feed under new circumstances.展开更多
Ethoxylation and propoxylation reactions are performed in the industry to produce mainly non-ionic surfactants and ethylene oxide(EO)–propylene oxide(PO) copolymers.Both the reactions occur in gas–liquid reactors by...Ethoxylation and propoxylation reactions are performed in the industry to produce mainly non-ionic surfactants and ethylene oxide(EO)–propylene oxide(PO) copolymers.Both the reactions occur in gas–liquid reactors by feeding gaseous EO,PO or both into the reactor containing a solution of an alkaline catalyst(KOH or Na OH).Non-ionic surfactants are produced by using liquid starters like fatty alcohols,fatty acids or alkyl-phenols,while when the scope is to prepare EO–PO copolymers the starter can be a mono-or multi-functional alcohol of low molecular weight.Both reactions are strongly exothermic,and EO and PO,in some conditions,can give place to runaway and also to explosive side reactions.Therefore,the choice of a suitable reactor is a key factor for operating in safe conditions.A correct reactor design requires:(i) the knowledge of the kinetic laws governing the rates of the occurring reactions;(ii) the role of mass and heat transfer in affecting the reaction rate;(iii) the solubility of EO and PO in the reacting mixture with the non-ideality of the reacting solutions considered;(iv) the density of the reacting mixture.All these aspects have been studied by our research group for different starters of industrial interest,and the data collected by using semibatch well stirred laboratory reactors have been employed for the simulation of industrial reactors,in particular Gas–Liquid Spray Tower Loop Reactors.展开更多
Batch processes are important in chemical industry,in which operators usually play a major role and hazards may arise by their inadvertent acts.In this paper,based on hazard and operability study and concept of qualit...Batch processes are important in chemical industry,in which operators usually play a major role and hazards may arise by their inadvertent acts.In this paper,based on hazard and operability study and concept of qualitative simulation,an automatic method for adverse consequence identification for potential maloperation is proposed.The qualitative model for production process is expressed by a novel directed graph.Possible operation deviations from normal operating procedure are identified systematically by using a group of guidewords.The proposed algorithm is used for qualitative simulation of batch processes to identify the effects of maloperations.The method is illustrated with a simple batch process and a batch reaction process.The results show that batch processes can be simulated qualitatively and hazards can be identified for operating procedures including maloperations.After analysis for possible plant maloperations,some measures can be taken to avoid maloperations or reduce losses resulted from maloperations.展开更多
Equity theory was proposed by John.Stacey.Adams. Under the background in China, nor matter the staff in state owned enterprises with better pay or the compliant workers feel unfair remuneration. Is the unfairness obje...Equity theory was proposed by John.Stacey.Adams. Under the background in China, nor matter the staff in state owned enterprises with better pay or the compliant workers feel unfair remuneration. Is the unfairness objective reality or caused by special cultural environment in China? The paper deeply observes the inapplicability of equity theory in China and reaction of it on productivity.展开更多
This paper investigates steady-state and dynamic simulation of an industrial fixed-bed ethylene oxide reactor. A mathematical heterogeneous one-dimensional model is developed for simulation of reactor performance in t...This paper investigates steady-state and dynamic simulation of an industrial fixed-bed ethylene oxide reactor. A mathematical heterogeneous one-dimensional model is developed for simulation of reactor performance in the presence of long term deactivation of silver/a-alumina catalyst. In this paper, steady-state model of the reactor is solved and results of steady state simulation are fed to dynamic simulator as initial condition. When results of dynamic simulation are compared with industrial reactor data, it is found that there were good agreements between simulation results and industrial data. The proposed model is also validated by industrial process data for a period of 1100 operating days.展开更多
The p-xylene(PX) oxidation process is of great industrial importance because of the strong demand of the global polyester fiber.A steady-state model of the PX oxidation has been studied by many researchers.In our prev...The p-xylene(PX) oxidation process is of great industrial importance because of the strong demand of the global polyester fiber.A steady-state model of the PX oxidation has been studied by many researchers.In our previous work,a novel industrial p-xylene oxidation reactor model using the free radical mechanism based kinetics has been developed.However,the disturbances such as production rate change,feed composition variability and reactor temperature changes widely exist in the industry process.In this paper,dynamic simulation of the PX oxidation reactor was designed by Aspen Dynamics and used to develop an effective plantwide control structure,which was capable of effectively handling the disturbances in the load and the temperature of the reactor.Step responses of the control structure to the disturbances were shown and served as the foundation of the smooth operation and advanced control strategy of this process in our future work.展开更多
This paper introduces the mathematical model of ammonia and urea reactors and suggested three methods for designing a special purpose controller. The first proposed method is Adaptive model predictive controller, the ...This paper introduces the mathematical model of ammonia and urea reactors and suggested three methods for designing a special purpose controller. The first proposed method is Adaptive model predictive controller, the second is Adaptive Neural Network Model Predictive Control, and the third is Adaptive neuro-fuzzy sliding mode controller. These methods are applied to a multivariable nonlinear system as an ammonia–urea reactor system. The main target of these controllers is to achieve stabilization of the outlet concentration of ammonia and urea, a stable reaction rate, an increase in the conversion of carbon monoxide(CO) into carbon dioxide(CO_2) to reduce the pollution effect, and an increase in the ammonia and urea productions, keeping the NH_3/CO_2 ratio equal to 3 to reduce the unreacted CO_2 and NH_3, and the two reactors' temperature in the suitable operating ranges due to the change in reactor parameters or external disturbance. Simulation results of the three controllers are compared. Comparative analysis proves the effectiveness of the suggested Adaptive neurofuzzy sliding mode controller than the two other controllers according to external disturbance and the change of parameters. Moreover, the suggested methods when compared with other controllers in the literature show great success in overcoming the external disturbance and the change of parameters.展开更多
Heteropoly acids(HPA) are well known for their versatile solid acid catalysis in diverse chemical reactions, however they suffer from low surface area(<10 m^2/g) and leaching into the reactions media, which reduce ...Heteropoly acids(HPA) are well known for their versatile solid acid catalysis in diverse chemical reactions, however they suffer from low surface area(<10 m^2/g) and leaching into the reactions media, which reduce their prospects as industrial catalyst.Herein, a novel hybrid material HPW@Zr-BTC,composed of 12-tungstophoric acid(HPW) and Zr^(Ⅳ)-benzene tri-carboxylate(Zr-BTC) metal-organic framework(MOF), was prepared via one-pot solvothermal method. Excellent HPW loading up to 32.3 wt% was achieved, and HPW@Zr-BTC composite proved to be highly stable, besides the crystalline morphology of Zr-BTC was intact. The catalytic activity of the hybrid composite was explored via Friedel-Crafts acylation of anisole with benzoyl chloride.The 28.2 wt% HPW@Zr-BTC showed excellent catalytic performance, with 99.4% anisole conversion and 97.6% yield(pmethoxybenzophenone) under solvent free conditions. Excellent retention of catalytic activity was achieved after at least five consecutive runs due to non-observable HPW leaching. The promising activity and stability of the catalyst forecasted its potential industrial applications.展开更多
A resource-based economy is an economic system driven by the exploitation of mineral resources and dominated by the energy, mineral and other resource sectors. In resource- rich areas, there is often an investment bia...A resource-based economy is an economic system driven by the exploitation of mineral resources and dominated by the energy, mineral and other resource sectors. In resource- rich areas, there is often an investment bias toward the resource sector because of the existence of a threshold for investment in human capital in the manufacturing sector. Once the resource sector is dominant, it has a particular atwaction effect on the economic factors; its expansion and spread have a viscosity effect on industry families;, and the sunk costs and path dependence that emerge as industrialization evolves have a lock-in effect on the role of resources. This may give rise to development path dependence and the trap of resource advantage, resulting in a self-strengthening mechanism in resource-based economies. The key to escaping this trap is to break down the resource sector's original self-perpetuating mechanism and path dependence, introduce learning and innovation, adjust mechanisms far the distribution of resource benefits and realize industry coordination and transformational economic development.展开更多
基金Supported by the National Key R&D Program of China(2017YFB0602500)
文摘To optimize industrial Fischer-Tropsch (IT) synthesis with the slurry bubble column reactor (SBCR) and iron- based catalyst, a comprehensive process model for IT synthesis that includes a detailed SBCR model, gas liquid separation model, simplified CO2 removal model and tail gas cycle model was developed. An effective iteration algorithm was proposed to solve this process model, and the model was validated by industrial demonstration experiments data (SBCR with 5.8 m diameter and 30 m height), with a maximum relative error 〈 10% for predicting the SBCR performances. Subsequently, the proposed model was adopted to optimize the industrial SBCR performances simultaneously considering process and reactor parameters variations. The results show that C5+yield increases as catalyst loading increases within 10-70 ton and syngas H2/CO value decreases within 1.3-1.6, but it doesn't increase obviously when the catalyst loading exceeds 45 ton (about 15 wt% concentration). Higher catalyst loading will result in higher difficulty for wax/catalyst separation and higher catalyst cost. There- fore, the catalyst loading (45 ton) is recommended for the industrial demonstration SBCR operation at syngas H2/ CO = 1.3, and the C5 + yield is about 402 ton" per day, which has an about 16% increase than the industrial dem- onstration run result.
文摘Danckwert’s method was used to determine the specific interfacial area, a, and the individual mass transfer coefficient, kL, during absorption of CO2 in a bubble column with an anionic surfactant in the carbonate-bicarbonate buffer solution and NaAsO2 as catalyst, the presence of which decreases the specific interfacial area and the individual mass transfer coefficient. The specific interfacial area and the individual mass transfer coefficient increase with increasing su- perficial gas velocity. The specific interfacial area decreases whereas the individual mass transfer coefficient increases with increasing temperature. The results of experiments were used to determine the dependence of a, kL, and kLa on the surface tension, the temperature of the absorption phase, and the superficial velocity of the gas. The calculated results from the correlation were found to be within 10% deviation from the actual experimental results.
文摘Acetic anhydride is the important organic chemical raw material, and is used widely in chemical industry,pharmaceutical industry, dyes, spices and other fields. In this paper, the process of carbonylation of methyl acetate in rhodium iodine catalyst system was studied, and the suitable reaction conditions were determined.At the same time, the kinetic model was established. The optimum reaction conditions were as follows: the reaction pressure was 5 MPa, the hydrogen content was 8%, the amount of iodomethane was 15%, the amount of lithium iodide was 3%, the reaction temperature was 150 ℃ and the reaction time is 3 h. Under the above reaction conditions, the selectivity of the reaction is close to 100% and the conversion is as high as 92%. The macroscopic kinetic model of the reaction was established in the temperature range of 120 ℃–150 ℃. The reaction is an irreversible reaction without the formation of by-products and the dynamic equation is also given in the Conclusions section.
文摘The CGP series FCC catalysts for manufacture of clean gasoline and propylene and the catalyst RSC-2006 for processing inferior residuum with high yield of light distillates are novel catalysts jointly developed by Qilu Catalyst Branch Company of SINOPEC Corp. and the Research Institute of Petroleum Processing (RIPP). The results of commercial application of these catalysts have revealed that they can satisfactorily meet the requirements for environmental protection, good economic benefits and capability for processing inferior FCC feed under new circumstances.
文摘Ethoxylation and propoxylation reactions are performed in the industry to produce mainly non-ionic surfactants and ethylene oxide(EO)–propylene oxide(PO) copolymers.Both the reactions occur in gas–liquid reactors by feeding gaseous EO,PO or both into the reactor containing a solution of an alkaline catalyst(KOH or Na OH).Non-ionic surfactants are produced by using liquid starters like fatty alcohols,fatty acids or alkyl-phenols,while when the scope is to prepare EO–PO copolymers the starter can be a mono-or multi-functional alcohol of low molecular weight.Both reactions are strongly exothermic,and EO and PO,in some conditions,can give place to runaway and also to explosive side reactions.Therefore,the choice of a suitable reactor is a key factor for operating in safe conditions.A correct reactor design requires:(i) the knowledge of the kinetic laws governing the rates of the occurring reactions;(ii) the role of mass and heat transfer in affecting the reaction rate;(iii) the solubility of EO and PO in the reacting mixture with the non-ideality of the reacting solutions considered;(iv) the density of the reacting mixture.All these aspects have been studied by our research group for different starters of industrial interest,and the data collected by using semibatch well stirred laboratory reactors have been employed for the simulation of industrial reactors,in particular Gas–Liquid Spray Tower Loop Reactors.
文摘Batch processes are important in chemical industry,in which operators usually play a major role and hazards may arise by their inadvertent acts.In this paper,based on hazard and operability study and concept of qualitative simulation,an automatic method for adverse consequence identification for potential maloperation is proposed.The qualitative model for production process is expressed by a novel directed graph.Possible operation deviations from normal operating procedure are identified systematically by using a group of guidewords.The proposed algorithm is used for qualitative simulation of batch processes to identify the effects of maloperations.The method is illustrated with a simple batch process and a batch reaction process.The results show that batch processes can be simulated qualitatively and hazards can be identified for operating procedures including maloperations.After analysis for possible plant maloperations,some measures can be taken to avoid maloperations or reduce losses resulted from maloperations.
文摘Equity theory was proposed by John.Stacey.Adams. Under the background in China, nor matter the staff in state owned enterprises with better pay or the compliant workers feel unfair remuneration. Is the unfairness objective reality or caused by special cultural environment in China? The paper deeply observes the inapplicability of equity theory in China and reaction of it on productivity.
文摘This paper investigates steady-state and dynamic simulation of an industrial fixed-bed ethylene oxide reactor. A mathematical heterogeneous one-dimensional model is developed for simulation of reactor performance in the presence of long term deactivation of silver/a-alumina catalyst. In this paper, steady-state model of the reactor is solved and results of steady state simulation are fed to dynamic simulator as initial condition. When results of dynamic simulation are compared with industrial reactor data, it is found that there were good agreements between simulation results and industrial data. The proposed model is also validated by industrial process data for a period of 1100 operating days.
基金Supported by the Major State Basic Research Development Program of China(2012CB720500)the National Natural Science Foundation of China(U1162202)+2 种基金the Shanghai Second Polytechnic University Key Discipline Construction(4th term)-Control Theory&Control Engineering(XXKPY1308)the Cultivation Program of Young Teachers in Colleges and Universities of Shanghai(ZZegdl4013)the School Foundation of Shanghai Second Polytechnic University(EGD14XQD02)
文摘The p-xylene(PX) oxidation process is of great industrial importance because of the strong demand of the global polyester fiber.A steady-state model of the PX oxidation has been studied by many researchers.In our previous work,a novel industrial p-xylene oxidation reactor model using the free radical mechanism based kinetics has been developed.However,the disturbances such as production rate change,feed composition variability and reactor temperature changes widely exist in the industry process.In this paper,dynamic simulation of the PX oxidation reactor was designed by Aspen Dynamics and used to develop an effective plantwide control structure,which was capable of effectively handling the disturbances in the load and the temperature of the reactor.Step responses of the control structure to the disturbances were shown and served as the foundation of the smooth operation and advanced control strategy of this process in our future work.
文摘This paper introduces the mathematical model of ammonia and urea reactors and suggested three methods for designing a special purpose controller. The first proposed method is Adaptive model predictive controller, the second is Adaptive Neural Network Model Predictive Control, and the third is Adaptive neuro-fuzzy sliding mode controller. These methods are applied to a multivariable nonlinear system as an ammonia–urea reactor system. The main target of these controllers is to achieve stabilization of the outlet concentration of ammonia and urea, a stable reaction rate, an increase in the conversion of carbon monoxide(CO) into carbon dioxide(CO_2) to reduce the pollution effect, and an increase in the ammonia and urea productions, keeping the NH_3/CO_2 ratio equal to 3 to reduce the unreacted CO_2 and NH_3, and the two reactors' temperature in the suitable operating ranges due to the change in reactor parameters or external disturbance. Simulation results of the three controllers are compared. Comparative analysis proves the effectiveness of the suggested Adaptive neurofuzzy sliding mode controller than the two other controllers according to external disturbance and the change of parameters. Moreover, the suggested methods when compared with other controllers in the literature show great success in overcoming the external disturbance and the change of parameters.
基金supported by a grant from the National Social Sciences Fund project "Exploitation of Coal Resources and Regional Economic Development" (Approval Number:08BJL052)a grant from the Program for Supporting Outstanding Young Academic Leaders in Shanxi Higher Education Institutions
基金supported by the National Key Research and Development Program of China(2016YFB0601303)the National Natural Science Foundation of China(51374193,21676278)+1 种基金Key Program of National Natural Science Foundation of China(9143420)Chinese Academy of Sciences,State Administration of Foreign Experts Affairs(CAS/SAFEA)International Partnership Program for Creative Research Teams(20140491518)
文摘Heteropoly acids(HPA) are well known for their versatile solid acid catalysis in diverse chemical reactions, however they suffer from low surface area(<10 m^2/g) and leaching into the reactions media, which reduce their prospects as industrial catalyst.Herein, a novel hybrid material HPW@Zr-BTC,composed of 12-tungstophoric acid(HPW) and Zr^(Ⅳ)-benzene tri-carboxylate(Zr-BTC) metal-organic framework(MOF), was prepared via one-pot solvothermal method. Excellent HPW loading up to 32.3 wt% was achieved, and HPW@Zr-BTC composite proved to be highly stable, besides the crystalline morphology of Zr-BTC was intact. The catalytic activity of the hybrid composite was explored via Friedel-Crafts acylation of anisole with benzoyl chloride.The 28.2 wt% HPW@Zr-BTC showed excellent catalytic performance, with 99.4% anisole conversion and 97.6% yield(pmethoxybenzophenone) under solvent free conditions. Excellent retention of catalytic activity was achieved after at least five consecutive runs due to non-observable HPW leaching. The promising activity and stability of the catalyst forecasted its potential industrial applications.
文摘A resource-based economy is an economic system driven by the exploitation of mineral resources and dominated by the energy, mineral and other resource sectors. In resource- rich areas, there is often an investment bias toward the resource sector because of the existence of a threshold for investment in human capital in the manufacturing sector. Once the resource sector is dominant, it has a particular atwaction effect on the economic factors; its expansion and spread have a viscosity effect on industry families;, and the sunk costs and path dependence that emerge as industrialization evolves have a lock-in effect on the role of resources. This may give rise to development path dependence and the trap of resource advantage, resulting in a self-strengthening mechanism in resource-based economies. The key to escaping this trap is to break down the resource sector's original self-perpetuating mechanism and path dependence, introduce learning and innovation, adjust mechanisms far the distribution of resource benefits and realize industry coordination and transformational economic development.