On the basis of hydrodynamic and scaling-up studies, a pilot-plant-scale thermal spouted bed reactor (50 mm in ID and 1500 mm in height) was designed and fabricated by scaling-down cold simulators. It was tested for m...On the basis of hydrodynamic and scaling-up studies, a pilot-plant-scale thermal spouted bed reactor (50 mm in ID and 1500 mm in height) was designed and fabricated by scaling-down cold simulators. It was tested for making syngas via catalytic partial oxidation (CPO) of methane by air. The effects of various operating conditions such as operating pressure and temperature, feed composition, and gas flowrate etc. on the CPO process were investigated. CH4 conversion of 92.2% and selectivity of 92.3% and 83.3% to CO and H2, respectively, were achieved at the pressure of 2.1 MPa. It was found that when the spouted bed reactor was operated within the stable spouting flow regime, the temperature profiles along the bed axis were much more uniform than those operated within the fixed-bed regime. The CH4 conversion and syngas selectivity were found to be close to thermodynamic equilibrium limits. The results of the present investigation showed that spouted bed could be considered as a potential type of chemical reactor for the CPO process of methane.展开更多
The discrepancy between pseudo-homogeneous one-dimensional model and pseudo-homogeneous two-dimensional model is studied. It is found that there are great differences between two models. This paper compares the maximu...The discrepancy between pseudo-homogeneous one-dimensional model and pseudo-homogeneous two-dimensional model is studied. It is found that there are great differences between two models. This paper compares the maximum and minimum values of the radial temperature in the hot spot in case that a single exothermic reaction is carried out, a correlation is obtained with pseudo-homogeneous one-dimensional model to describe the entire reactor behavior. A new runaway criterion, based on the occurrence of inflection in the hot spot locus, is developed for the case of pseudo-homogeneous two-dimensional model. This criterion predicts the maximum allowable temperature for safe operation and the regions of runaway, respectively. The calculated results show that, compared with the results based on pseudo-homogeneous one-dimensional model, runaway will easily occur when the radial temperature gradient has to be considered.展开更多
Recently, microreactors have become available to be fabricated and used safely. The performance of these microreactors depends on the behavior of the multiphase flow hydrodynamics. Gas-liquid flow through T-junction m...Recently, microreactors have become available to be fabricated and used safely. The performance of these microreactors depends on the behavior of the multiphase flow hydrodynamics. Gas-liquid flow through T-junction microchannel reactor is simulated numerically using VOF （volume of fluid） method. 2-D （Two-dimensional） and 3-D （three-dimensional） models of the T-junction microchannel reactor were introduced to the simulations. Both 2-D and 3-D simulations for nitrogen-water flow were performed in the FLUENT （Fluent. Inc.） computational fluid dynamics package. The third direction effect has been studied by comparing the results of the 2-D and 3-D simulations with the published experimental data. Also, the bubble slug length was calculated for the 2-D and 3-D simulations. Furthermore, the hydrodynamics of the flow was studied for the 2-D and 3-D simulations, and compared with other experimental data. The pressure drop, mean bubble velocity, the velocity distribution and the void fraction were calculated and found to be in good agreement with published data.展开更多
The paper describes the instrumentation for studying temperature and void reactivity effects that were developed at VR-I zero power reactor. Further are described its operational parameters, fields and ways of its uti...The paper describes the instrumentation for studying temperature and void reactivity effects that were developed at VR-I zero power reactor. Further are described its operational parameters, fields and ways of its utilization as well as issues connected to its implementation into the reactor core.展开更多
基金Supported by the Doctorate Discipline Foundation of the Ministry of Education of China(No.2000042053)& China National Petroleum Co
文摘On the basis of hydrodynamic and scaling-up studies, a pilot-plant-scale thermal spouted bed reactor (50 mm in ID and 1500 mm in height) was designed and fabricated by scaling-down cold simulators. It was tested for making syngas via catalytic partial oxidation (CPO) of methane by air. The effects of various operating conditions such as operating pressure and temperature, feed composition, and gas flowrate etc. on the CPO process were investigated. CH4 conversion of 92.2% and selectivity of 92.3% and 83.3% to CO and H2, respectively, were achieved at the pressure of 2.1 MPa. It was found that when the spouted bed reactor was operated within the stable spouting flow regime, the temperature profiles along the bed axis were much more uniform than those operated within the fixed-bed regime. The CH4 conversion and syngas selectivity were found to be close to thermodynamic equilibrium limits. The results of the present investigation showed that spouted bed could be considered as a potential type of chemical reactor for the CPO process of methane.
基金Supported by the Tianjin Natural Science Foundation.
文摘The discrepancy between pseudo-homogeneous one-dimensional model and pseudo-homogeneous two-dimensional model is studied. It is found that there are great differences between two models. This paper compares the maximum and minimum values of the radial temperature in the hot spot in case that a single exothermic reaction is carried out, a correlation is obtained with pseudo-homogeneous one-dimensional model to describe the entire reactor behavior. A new runaway criterion, based on the occurrence of inflection in the hot spot locus, is developed for the case of pseudo-homogeneous two-dimensional model. This criterion predicts the maximum allowable temperature for safe operation and the regions of runaway, respectively. The calculated results show that, compared with the results based on pseudo-homogeneous one-dimensional model, runaway will easily occur when the radial temperature gradient has to be considered.
文摘Recently, microreactors have become available to be fabricated and used safely. The performance of these microreactors depends on the behavior of the multiphase flow hydrodynamics. Gas-liquid flow through T-junction microchannel reactor is simulated numerically using VOF （volume of fluid） method. 2-D （Two-dimensional） and 3-D （three-dimensional） models of the T-junction microchannel reactor were introduced to the simulations. Both 2-D and 3-D simulations for nitrogen-water flow were performed in the FLUENT （Fluent. Inc.） computational fluid dynamics package. The third direction effect has been studied by comparing the results of the 2-D and 3-D simulations with the published experimental data. Also, the bubble slug length was calculated for the 2-D and 3-D simulations. Furthermore, the hydrodynamics of the flow was studied for the 2-D and 3-D simulations, and compared with other experimental data. The pressure drop, mean bubble velocity, the velocity distribution and the void fraction were calculated and found to be in good agreement with published data.
文摘The paper describes the instrumentation for studying temperature and void reactivity effects that were developed at VR-I zero power reactor. Further are described its operational parameters, fields and ways of its utilization as well as issues connected to its implementation into the reactor core.
