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用Matano法计算Ti基Al膜的反应扩散系数
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作者 孙达 靳彩霞 《上海金属(有色分册)》 1993年第2期1-4,共4页
本文主要是通过Ti基与Al膜反应动力学提供的浓度分布曲线,用Matano方法计算Ti基Al膜在Ti相变点(880℃)上、下的反应扩散系数,求出扩散激活能,找出了扩散系数与温度和成分的变化规律。
关键词 钛基铝膜 反应扩散系数 Matano法
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结合水对二氧化铅还原反应的影响
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作者 闫智刚 《电动自行车》 2012年第9期20-23,共4页
采用循环伏安、恒流放电以及差热分析等方法分析了物理吸附水和化学结构水对于α-PbO2和β-PbO2在放电过程中的还原反应所起的作用。实验证明水的损失直接导致了PbO2容量和电导的下降。当只有物理吸附水被除去时,α-PbO2和β-PbO2的容... 采用循环伏安、恒流放电以及差热分析等方法分析了物理吸附水和化学结构水对于α-PbO2和β-PbO2在放电过程中的还原反应所起的作用。实验证明水的损失直接导致了PbO2容量和电导的下降。当只有物理吸附水被除去时,α-PbO2和β-PbO2的容量损失不大;而化学结构水被除去时,α-PbO2和β-PbO2的容量都衰减很大,而且α-PbO2所受影响更大。对于扩散系数而言,当只有物理吸附水被除去时,β-PbO2的扩散系数变化很小,而α-PbO2的扩散系数下降很大;化学结构水的损失使得β-PbO2的扩散系数变化很大,而α-PbO2的扩散系数变化很小。 展开更多
关键词 铅酸蓄电池 二氧化铅 物理吸附水 化学结构水 扩散系数:还原反应:影响
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关于带混合边界条件的半线性反应扩散系统解的整体存在性问题
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作者 杨万利 《数学学报(中文版)》 SCIE CSCD 北大核心 1997年第6期805-814,共10页
本文利用Gronwal不等式及对偶技巧,研究了一类带混合边界条件的半线性反应扩散系统解的整体存在性问题,给出一些控制条件,突破了以往加在“Morgan”和上的线性控制,得到解的整体存在性,很大程度上改进和推广了以往... 本文利用Gronwal不等式及对偶技巧,研究了一类带混合边界条件的半线性反应扩散系统解的整体存在性问题,给出一些控制条件,突破了以往加在“Morgan”和上的线性控制,得到解的整体存在性,很大程度上改进和推广了以往结果。 展开更多
关键词 反应扩散系数 混合边界条件 半线性 存在性
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Nonlinear predator-prey singularly perturbed Robin Problems for reaction diffusion systems 被引量:4
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作者 莫嘉琪 韩祥临 《Journal of Zhejiang University Science》 CSCD 2003年第5期511-513,共3页
The nonlinear predator-prey reaction diffusion systems for singularly perturbed Robin Problems are considered. Under suitable conditions, the theory of differential inequalities can be used to study the asymptotic beh... The nonlinear predator-prey reaction diffusion systems for singularly perturbed Robin Problems are considered. Under suitable conditions, the theory of differential inequalities can be used to study the asymptotic behavior of the solution for initial boundary value problems. 展开更多
关键词 NONLINEAR PREDATOR-PREY Reaction diffusion Singular perturbation
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Hydrodynamic dispersion of reactive solute in a Hagen–Poiseuille flow of a layered liquid
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作者 Sudip Debnath Apu Kumar Saha +1 位作者 B.S.Mazumder Ashis Kumar Roy 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第7期862-873,共12页
An analysis of the solute dispersion in the liquid flowing through a pipe by means of Aris–Barton's ‘method of moments', under the joint effect of some finite yield stress and irreversible absorption into th... An analysis of the solute dispersion in the liquid flowing through a pipe by means of Aris–Barton's ‘method of moments', under the joint effect of some finite yield stress and irreversible absorption into the wall is presented in this paper. The liquid is considered as a three-layer liquid where the center region is Casson liquid surrounded by Newtonian liquid layer. A significant change from previous modelling exercises in the study of hydrodynamic dispersion, different molecular diffusivity has been considered for the different region yet to be constant. For all time period, finite difference implicit scheme has been adopted to solve the integral moment equation arising from the unsteady convective diffusion equation. The purpose of the study is to find the dependency of solute transport coefficients on absorption parameter, yield stress, viscosity ratio, peripheral layer variation and in addition with various diffusivity coefficients in different liquid layers. This kind of study may be useful for understanding the dispersion process in the blood flow analysis. 展开更多
关键词 Casson liquid Yield stress Axial-dispersion coefficient Irreversible reaction DIFFUSIVITY
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Global attractors associated with general partly dissipative reaction-diffusion systems in unbounded domains
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作者 袁建军 《Journal of Chongqing University》 CAS 2004年第2期66-68,共3页
The asymptotic behaviour of solutions for general partly dissipative reaction-diffusion systems in Rn is studied. The asymptotic compactness of the solutions and then the existence of the global attractor are proved i... The asymptotic behaviour of solutions for general partly dissipative reaction-diffusion systems in Rn is studied. The asymptotic compactness of the solutions and then the existence of the global attractor are proved in L2(Rn )× L2(Rn ) . 展开更多
关键词 global attractor asymptotic compactness partly dissipative effect reaction diffusion systems
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Diffusion-controlled synthesis of Cu-based catalysts for the Rochow reaction 被引量:2
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作者 刘合之 李晶 +4 位作者 纪永军 张在磊 汪学广 钟子宜 苏发兵 《Science China Materials》 SCIE EI CSCD 2017年第12期1215-1226,共12页
The properties of materials are strongly dependent on their structures. The diffusion effect is a main kinetic factor that can be used to regulate the growth and structure of materials. In this work, we developed a sy... The properties of materials are strongly dependent on their structures. The diffusion effect is a main kinetic factor that can be used to regulate the growth and structure of materials. In this work, we developed a systematic and feasible strategy to synthesize Cu2O solid spheres and hexahedrons by controlling the diffusion coefficients. These Cu2O products can be successively transformed into corresponding Cu hollow spheres and hexahedrons as well as CuO porous spheres and hexahedrons by controlling hydrogen diffusion in hydrazine hydrate solution and controlling oxygen diffusion in air, respectively. The formation of these transformations was also discussed in detail. Tested for Rochow reaction, the as-prepared Cu2O solid and CuO porous spheres exhibit higher dimethyldichlorosilane selectivity and Si conversion than Cu hollow spheres, which is attributed to the active sites for CH3Cl adsorption formed in CuxSi phase after the removal of oxygen atoms in Cn2O and CuO in the formation of dimethylchlorosilane. The present work not only develops a feasible method for preparing well shape-defined Cu2O solid spheres and hexahedrons but also clarifies the respective roles of Cu, Cu2O and CuO in dimethyldichlorosilane synthesis via Rochow reaction. 展开更多
关键词 cuprous oxide hollow spheres porous spheres surface oxygen vacancies Rochow reaction
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ON THE EXISTENCE OF GLOBAL ATTRACTOR FOR A CLASS OF INFINITE DIMENSIONAL DISSIPATIVE NONLINEAR DYNAMICAL SYSTEMS 被引量:10
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作者 ZHONGCHENGKUI SUNCHUNYOU NIUMINGFEI 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2005年第3期393-400,共8页
By means of a nonstandard estimation about the energy functional, the authors prove the existence of a global attractor for an abstract nonlinear evolution equation. As an application, the existence of a global attrac... By means of a nonstandard estimation about the energy functional, the authors prove the existence of a global attractor for an abstract nonlinear evolution equation. As an application, the existence of a global attractor for some nonlinear reaction-diffusion equations with some distribution derivatives in inhomogeneous terms is obtained. 展开更多
关键词 Global attractor Measures of noncompactness Reaction-diffusion equations
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Numerical Approximation of a Reaction-Diffusion System with Fast Reversible Reaction
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作者 Robert EYMARD Danielle HILHORST +1 位作者 Hideki MURAKAWA Michal OLECH 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2010年第5期631-654,共24页
The authors consider the finite volume approximation of a reaction-diffusion system with fast reversible reaction.It is deduced from a priori estimates that the approximate solution converges to the weak solution of t... The authors consider the finite volume approximation of a reaction-diffusion system with fast reversible reaction.It is deduced from a priori estimates that the approximate solution converges to the weak solution of the reaction-diffusion problem and satisfies estimates which do not depend on the kinetic rate.It follows that the solution converges to the solution of a nonlinear diffusion problem,as the size of the volume elements and the time steps converge to zero while the kinetic rate tends to infinity. 展开更多
关键词 Instantaneous reaction limit Mass-action kinetics Finite volume methods Convergence of approximate solutions Discrete a priori estimates Kolmogorov's theorem
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The existence and non-existence of travelling front in high order auto-catalysis chemical reaction
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作者 QI YuanWei LIU GuiRong 《Science China Mathematics》 SCIE 2012年第9期1761-1768,共8页
This article studies propagating wave fronts in an isothermal chemical reaction A + nB →(n + 1)B involving two chemical species,a reactant A and an auto-catalyst B whose diffusion coefficients,DA and DB,are unequal d... This article studies propagating wave fronts in an isothermal chemical reaction A + nB →(n + 1)B involving two chemical species,a reactant A and an auto-catalyst B whose diffusion coefficients,DA and DB,are unequal due to different molecular weights and/or sizes.More accurate bounds v* and v* that depend on DB/DA,when the ratio is less than 1,are derived such that there is a unique travelling wave of every speed v v* and there does not exist any travelling wave of speed v < v*.The refined bounds for DB/DA < 1 case is compatible to what has been shown in earlier work for DB/DA > 1 when n 3. 展开更多
关键词 high order autocatalysis travelling wave minimum speed REACTION-DIFFUSION
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PATTERN FORMATION IN CHEMOTAXIC REACTION-DIFFUSION SYSTEMS
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作者 HIROTO SHOJI KEITARO SAITOH 《International Journal of Biomathematics》 2012年第3期205-213,共9页
In this study, we investigate two-dimensional patterns generated by chemotaxis reaction-diffusion systems. We numerically examine the Keller-Segel models with the volume-filling aggregation term and the receptor aggre... In this study, we investigate two-dimensional patterns generated by chemotaxis reaction-diffusion systems. We numerically examine the Keller-Segel models with the volume-filling aggregation term and the receptor aggregation term in two dimensions. Spotted, striped and reversed spotted patterns are obtained as stable motionless equi- librium patterns. The relative stability of these patterns is studied numerically on the basis of the derived free energy. The intuitive understanding of these generated patterns and the relation with three-dimensional patterns are also discussed. 展开更多
关键词 CHEMOTAXIS Keller Segel model stability analysis.
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