Acetic anhydride is the important organic chemical raw material, and is used widely in chemical industry,pharmaceutical industry, dyes, spices and other fields. In this paper, the process of carbonylation of methyl ac...Acetic anhydride is the important organic chemical raw material, and is used widely in chemical industry,pharmaceutical industry, dyes, spices and other fields. In this paper, the process of carbonylation of methyl acetate in rhodium iodine catalyst system was studied, and the suitable reaction conditions were determined.At the same time, the kinetic model was established. The optimum reaction conditions were as follows: the reaction pressure was 5 MPa, the hydrogen content was 8%, the amount of iodomethane was 15%, the amount of lithium iodide was 3%, the reaction temperature was 150 ℃ and the reaction time is 3 h. Under the above reaction conditions, the selectivity of the reaction is close to 100% and the conversion is as high as 92%. The macroscopic kinetic model of the reaction was established in the temperature range of 120 ℃–150 ℃. The reaction is an irreversible reaction without the formation of by-products and the dynamic equation is also given in the Conclusions section.展开更多
The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of ma...The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of macromixing time and micromixing time are quantitatively discussed. The results show that under a continuous and stable operating condition, as the paddle speed increases, the macromixing time and micromixing time calculated by the two models both decrease, even in a linkage equilibrium state. Simultaneously, as the paddle speed increases, the results figured by the two models tend to be consistent. It indicates that two models both are more suitable for calculation of mixing time in high paddle speed. Compared with the existing experimental results of this type of reactor, the mixing time computed in the speed of 1500 r/min is closer to it. These conclusions can provide an important reference for systematically studying the strengthening mechanism of LISR under continuous mixing conditions.展开更多
Arch dams suffer time-varying external loadings and harsh environment that harm their physical properties. With the aging of such dams, damage accumulates and concrete degradation inevitably appears. In this paper, a ...Arch dams suffer time-varying external loadings and harsh environment that harm their physical properties. With the aging of such dams, damage accumulates and concrete degradation inevitably appears. In this paper, a model is proposed for simulating concrete degradation with aging because of chemo-mechanical damage. The seismic response of an arch dam with aging effects is analyzed using the proposed model. The results show that the damage caused by the aging of arch dams may result in an increase in tensile cantilever stresses during earthquakes. Meanwhile, the dynamic displacement and joint opening also clearly increase in comparison with those without damage. Thus, the seismic safety of arch dams is reduced by aging effects.展开更多
Potassium (K) release characteristics in soil play a significant role in supplying available K. Information on K-release characteristics in soils of central Iran is limited. The objectives of this study were to dete...Potassium (K) release characteristics in soil play a significant role in supplying available K. Information on K-release characteristics in soils of central Iran is limited. The objectives of this study were to determine K release characteristics and correlations of K release rate constants with K extracted by different chemical methods in surface soils of ten calcareous soils of central Iran. The kinetics of K release in the soils was determined by successive extraction with 0.01 mol L-1 CaC12 in a period of 2-2017 h at 25±1℃. Soil K was extracted by distilled water, 0.5 mol L-1 MgNO3, 0.002 mol L-1 SrC12, 0.1 mol L-1 BaC12, 0.01 mol L-1 CaC12, 1 mol L-1 NaC1, 1 mol L-1 boiling HNO3, 1 mol L-1 NH4OAC, Mehlich 1, 0.002 mol L-1 SrC12 + 0.05 mol L-1 citric acid, and ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA). A plot of cumulative amounts of K released showed a discontinuity in slope at 168 h. Thus, two equations were applied to two segments of the total reaction time (2-168 and 168-2 017 h). Cumulative amounts of K released ranged from 55 to 299 mg kg-1 in 2-168 h and from 44 to 119 mg kg-1 in 168-2 017 h. Release kinetics of K in the two time segments conformed fairly well to parabolic diffusion, simplified Elovich, and power function models. There was a wide variation in the K release rate constants. Increasingly higher average concentrations of soil K were extracted by distilled water, Mehlich 1, SrC12, CaC12, SrC12 + citric acid, AB-DTPA, MgNO3, NaCI, NH4OAc, BaCI2, and HNO3. Potassium release rate constants were significantly correlated with K extracted. The results of this study showed that information obtained from mathematical modeling in two reaction time segments can help to estimate the K-supplying power of soils.展开更多
In this paper, regarding the time delay as a bifurcation parameter, the stability and Hopf bifurcation of the model of competition between two species in a turbidostat with Beddington-DeAngelis functional response and...In this paper, regarding the time delay as a bifurcation parameter, the stability and Hopf bifurcation of the model of competition between two species in a turbidostat with Beddington-DeAngelis functional response and discrete delay are studied. The Hopf bifurcations can be shown when the delay crosses the critical value. Furthermore, based on the normal form and the center manifold theorem, the type, stability and other properties of the bifurcating periodic solutions are determined. Finally, some numerical simulations are given to illustrate the results.展开更多
The pattern formation in reaction-diffusion system has long been the subject of interest to the researchers in the domain of mathematical ecology because of its universal exis- tence and importance. The present invest...The pattern formation in reaction-diffusion system has long been the subject of interest to the researchers in the domain of mathematical ecology because of its universal exis- tence and importance. The present investigation deals with a spatial dynamics of the Beddington-DeAngelis predator-prey model in the presence of a constant proportion of prey refuge. The model system representing boundary value problem under study is subjected to homogeneous Neumann boundary conditions. The asymptotic stability including the local and the global stability and the bifurcation as well of the unique pos- itive homogeneous steady state of the corresponding temporal model has been analyzed. The Turing instability region in two-parameter space and the condition of diffusion- driven instability of the spatiotemporal model are investigated. Based on the appro- priate numerical simulations, the present model dynamics in Turing space appears to get influenced by prey refuge while it exhibits diffusion-controlled pattern formation growth to spots, stripe-spot mixtures, labyrinthine, stripe-hole mixtures and holes repli- cation. The results obtained appear to enrich the findings of the model system under consideration.展开更多
文摘Acetic anhydride is the important organic chemical raw material, and is used widely in chemical industry,pharmaceutical industry, dyes, spices and other fields. In this paper, the process of carbonylation of methyl acetate in rhodium iodine catalyst system was studied, and the suitable reaction conditions were determined.At the same time, the kinetic model was established. The optimum reaction conditions were as follows: the reaction pressure was 5 MPa, the hydrogen content was 8%, the amount of iodomethane was 15%, the amount of lithium iodide was 3%, the reaction temperature was 150 ℃ and the reaction time is 3 h. Under the above reaction conditions, the selectivity of the reaction is close to 100% and the conversion is as high as 92%. The macroscopic kinetic model of the reaction was established in the temperature range of 120 ℃–150 ℃. The reaction is an irreversible reaction without the formation of by-products and the dynamic equation is also given in the Conclusions section.
基金Project(51276131)supported by the National Natural Science Foundation of ChinaProject(ZRZ0316)supported by the Natural Science Foundation of Hubei Province,ChinaProject(2013070104010025)supported by the Morning Glory Project of Wuhan Science and Technology Bureau,China
文摘The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of macromixing time and micromixing time are quantitatively discussed. The results show that under a continuous and stable operating condition, as the paddle speed increases, the macromixing time and micromixing time calculated by the two models both decrease, even in a linkage equilibrium state. Simultaneously, as the paddle speed increases, the results figured by the two models tend to be consistent. It indicates that two models both are more suitable for calculation of mixing time in high paddle speed. Compared with the existing experimental results of this type of reactor, the mixing time computed in the speed of 1500 r/min is closer to it. These conclusions can provide an important reference for systematically studying the strengthening mechanism of LISR under continuous mixing conditions.
基金supported by the National Natural Science Foundation of China (Grant No. 50779021)the Beijing Natural Science Foundation (Grant No. 8082014)+1 种基金the Scientific Foundation for Returned Overseas Chinese Scholars, Ministry of Educationthe State Key Laboratory of Hydroscience and Engineering, China (Grant No. 2008-TC-2)
文摘Arch dams suffer time-varying external loadings and harsh environment that harm their physical properties. With the aging of such dams, damage accumulates and concrete degradation inevitably appears. In this paper, a model is proposed for simulating concrete degradation with aging because of chemo-mechanical damage. The seismic response of an arch dam with aging effects is analyzed using the proposed model. The results show that the damage caused by the aging of arch dams may result in an increase in tensile cantilever stresses during earthquakes. Meanwhile, the dynamic displacement and joint opening also clearly increase in comparison with those without damage. Thus, the seismic safety of arch dams is reduced by aging effects.
文摘Potassium (K) release characteristics in soil play a significant role in supplying available K. Information on K-release characteristics in soils of central Iran is limited. The objectives of this study were to determine K release characteristics and correlations of K release rate constants with K extracted by different chemical methods in surface soils of ten calcareous soils of central Iran. The kinetics of K release in the soils was determined by successive extraction with 0.01 mol L-1 CaC12 in a period of 2-2017 h at 25±1℃. Soil K was extracted by distilled water, 0.5 mol L-1 MgNO3, 0.002 mol L-1 SrC12, 0.1 mol L-1 BaC12, 0.01 mol L-1 CaC12, 1 mol L-1 NaC1, 1 mol L-1 boiling HNO3, 1 mol L-1 NH4OAC, Mehlich 1, 0.002 mol L-1 SrC12 + 0.05 mol L-1 citric acid, and ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA). A plot of cumulative amounts of K released showed a discontinuity in slope at 168 h. Thus, two equations were applied to two segments of the total reaction time (2-168 and 168-2 017 h). Cumulative amounts of K released ranged from 55 to 299 mg kg-1 in 2-168 h and from 44 to 119 mg kg-1 in 168-2 017 h. Release kinetics of K in the two time segments conformed fairly well to parabolic diffusion, simplified Elovich, and power function models. There was a wide variation in the K release rate constants. Increasingly higher average concentrations of soil K were extracted by distilled water, Mehlich 1, SrC12, CaC12, SrC12 + citric acid, AB-DTPA, MgNO3, NaCI, NH4OAc, BaCI2, and HNO3. Potassium release rate constants were significantly correlated with K extracted. The results of this study showed that information obtained from mathematical modeling in two reaction time segments can help to estimate the K-supplying power of soils.
基金Acknowledgments The authors would like to thank the editors and the anonymous referees for their helpful suggestions and comments which led to the improvement of our original manuscript. This work is supported by the National Natural Science Foundation of China (Grant Nos. 11561022, 11261017), the China Postdoctoral Science Foundation (Grant No. 2014M562008).
文摘In this paper, regarding the time delay as a bifurcation parameter, the stability and Hopf bifurcation of the model of competition between two species in a turbidostat with Beddington-DeAngelis functional response and discrete delay are studied. The Hopf bifurcations can be shown when the delay crosses the critical value. Furthermore, based on the normal form and the center manifold theorem, the type, stability and other properties of the bifurcating periodic solutions are determined. Finally, some numerical simulations are given to illustrate the results.
文摘The pattern formation in reaction-diffusion system has long been the subject of interest to the researchers in the domain of mathematical ecology because of its universal exis- tence and importance. The present investigation deals with a spatial dynamics of the Beddington-DeAngelis predator-prey model in the presence of a constant proportion of prey refuge. The model system representing boundary value problem under study is subjected to homogeneous Neumann boundary conditions. The asymptotic stability including the local and the global stability and the bifurcation as well of the unique pos- itive homogeneous steady state of the corresponding temporal model has been analyzed. The Turing instability region in two-parameter space and the condition of diffusion- driven instability of the spatiotemporal model are investigated. Based on the appro- priate numerical simulations, the present model dynamics in Turing space appears to get influenced by prey refuge while it exhibits diffusion-controlled pattern formation growth to spots, stripe-spot mixtures, labyrinthine, stripe-hole mixtures and holes repli- cation. The results obtained appear to enrich the findings of the model system under consideration.