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二氧化锰氧化降解五氯酚 被引量:20
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作者 赵玲 彭平安 黄伟林 《环境科学》 EI CAS CSCD 北大核心 2006年第7期1388-1392,共5页
以二氧化锰为氧化剂,研究了pH 4.12的水溶液中五氯酚氧化降解的反应动力学,并讨论了反应溶液的pH对反应动力学的影响.结果表明,五氯酚对二氧化锰的氧化作用具有较强的反应感受性.在pH一定和二氧化锰充分过量的条件下,随着反应的进行,五... 以二氧化锰为氧化剂,研究了pH 4.12的水溶液中五氯酚氧化降解的反应动力学,并讨论了反应溶液的pH对反应动力学的影响.结果表明,五氯酚对二氧化锰的氧化作用具有较强的反应感受性.在pH一定和二氧化锰充分过量的条件下,随着反应的进行,五氯酚的降解速度变慢,遵循的不是简单的准一级反应动力学而是复合的反应动力学.此外,随溶液pH由3.5升高6.6,五氯酚的降解速度发生显著地下降.运用溶剂萃取和气质联用仪的分析方法,检测到2个主产物和1个次产物.其中,次产物是由四氯-1,4-氢醌与四氯儿茶酚组成的混合物;2个主产物是由五氯酚氧自由基偶合而成的二聚体,且是同分异构体.在观测到的表面反应动力学和降解产物的基础上,提出了五氯酚被二氧化锰氧化降解的反应流程图. 展开更多
关键词 氧化降解 五氯酚 二氧化锰 反应动力学 反应流程图
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Simulation of Low-Temperature Coal Tar Hydrocracking in Supercritical Gasoline 被引量:8
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作者 Zhang Lei Liu Zongkuan Gu Zhaolin 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第4期70-76,共7页
The aim of this paper was preliminary design of the process for low-temperature coal tar hydrocrackmg m supercritical gasoline based on Aspen Plus with the concept of energy self-sustainability. In order to ensure the... The aim of this paper was preliminary design of the process for low-temperature coal tar hydrocrackmg m supercritical gasoline based on Aspen Plus with the concept of energy self-sustainability. In order to ensure the correct- ness and accuracy of the simulation, we did the following tasks: selecting reasonable model compounds for low-tem- perature coal tar; describing the nature of products gasoline and diesel accurately; and confirming the proper property study method for each block by means of experience and trial. The purpose of energy self-sustainability could be pos- sibly achieved, on one hand, by using hot stream to preheat cold stream and achieving temperature control of streams, and on the other hand, by utilizing gas (byproduct of the coal tar hydrocracking) combustion reaction to provide energy. Results showed that the whole process could provide a positive net power of about 609 kW-h for processing the low- temperature coal tar with a flowrate of 2 268 kg/h. The total heat recovery amounted to 2 229 kW-h, among which 845 kW'h was obtained from the gas combustion reaction, and 1 116 kW'h was provided by the reactor's outlet stream, with the rest furnished by hot streams of the products gasoline, diesel and residue. In addition, the process flow sheet could achieve products separation well, and specifically the purity of product gasoline and diesel reached 97.2% and 100%, respectively. 展开更多
关键词 coal tar supercritical solvent HYDROCRACKING process design energy self-sustainability Aspen Plus
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