Nanometer-scale thin film of Ni supported on glassy carbon (nm-Ni/GC) was prepared by electrochemical deposition through cyclic voltammetry (CV). The properties of nm-Ni/GC were studied by electrochemical in situ FTIR...Nanometer-scale thin film of Ni supported on glassy carbon (nm-Ni/GC) was prepared by electrochemical deposition through cyclic voltammetry (CV). The properties of nm-Ni/GC were studied by electrochemical in situ FTIR reflection spectroscopy using CO adsorption as probe reaction. It has revealed that the nm-Ni/GC exhibits almormal infrared effects (AIREs). The study has extended the inves-tigation of the AIREs that we have discovered initially on nanostructured film materials of platinum group metals and alloys to nanostructured film materials of iron group metals.展开更多
文摘Nanometer-scale thin film of Ni supported on glassy carbon (nm-Ni/GC) was prepared by electrochemical deposition through cyclic voltammetry (CV). The properties of nm-Ni/GC were studied by electrochemical in situ FTIR reflection spectroscopy using CO adsorption as probe reaction. It has revealed that the nm-Ni/GC exhibits almormal infrared effects (AIREs). The study has extended the inves-tigation of the AIREs that we have discovered initially on nanostructured film materials of platinum group metals and alloys to nanostructured film materials of iron group metals.
