对外汉语教学模式的程序化和反程序化

围绕对外汉语教学模式问题,采用归纳分析的方法,分析了对外汉语教学模式特点和存在的不足,提出既要有程序化特征,又要突破过于程序化的观点。研究结果对提高对外汉语教学效果有指导意义。

Ru/FeO_x catalyst performance design: Highly dispersed Ru species for selective carbon dioxide hydrogenation

A series of Ru/FeOx catalysts were synthesized for the selective hydrogenation of CO2to CO.Detailed characterizations of the catalysts through X‐ray diffraction,X‐ray photoelectron spectroscopy,transmission electron microscopy,and temperature‐programmed techniques were performed to directly monitor the surface chemical properties and the catalytic performance to elucidate the reaction mechanism.Highly dispersed Ru species were observed on the surface of FeOx regardless of the initial Ru loading.Varying the Ru loading resulted in changes to the Ru coverage over the FeOx surface,which had a significant impact on the interaction between Ru and adsorbed H,and concomitantly,the H2activation capacity via the ability for H2dissociation.FeOx having0.01%of Ru loading exhibited100%selectivity toward CO resulting from the very strong interaction between Ru and adsorbed H,which limits the desorption of the activated H species and hinders over‐reduction of CO to CH4.Further increasing the Ru loading of the catalysts to above0.01%resulted in the adsorbed H to be easily dissociated,as a result of a weaker interaction with Ru,which allowed excessive CO reduction to produce CH4.Understanding how to selectively design the catalyst by tuning the initial loading of the active phase has broader implications on the design of supported metal catalysts toward preparing liquid fuels from CO2.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences toward preparing liquid fuels from CO2.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.

Solvothermal preparation and characteristics of Sn-doped In_2O_3

Sn-doped In2O3 (ITO) nanopowders were prepared in ethanol solvent by solvothermal process. The effects of the solvothermal temperature, coprecipitation pH value and SnO2 content on the products phase and microwave absorption were investigated by X-ray diffractometry and microwave reflectance. ITO nanopowders with cubic structure can be respectively prepared at 250 and 270 ℃ for 6 h. The prepared product is InOOH or the mixture of InOOH and In3Sn4O12 when the solvothermal temperature is below 250℃. With rising solvothermal temperature and prolonging time, the absorption of the ITO powders gradually decreases. The products are ITO nanopowders by coprecipitating at pH=9 or 11, but ITO powders with Sn3O4 at pH=6. The absorption of powders prepared at pH=6 is better than that at any other pH value. The products are all ITO nanopowders and crystal size reduces with increasing SnO2 content. The microwave absorption of ITO nanopowders with SnO2 content of 8% (mass fraction) is the best among samples with different SnO2 contents.

Long-term nitritation performance of ammonium-rich landfill leachate

This study presents a biological system combined upflow anaerobic sludge bed(UASB) with sequencing batch reactor(SBR) to treat ammonium-rich landfill leachate.The start-up and operation of the nitritation at low temperatures were investigated.The synergetic interaction of free ammonia(FA) inhibition on nitriteoxidizing bacteria(NOB) and process control was used to achieve nitritation in the SBR.It is demonstrated that nitritation was successfully started up in the SBR at low temperatures(14.0 ℃-18.2 ℃) by using FA inhibition coupled with process control,and then was maintained for 482 days at normal/low temperature.Although ammonia-oxidizing bacteria(AOB) and NOB co-existed within bacterial clusters in the SBR sludge,AOB were confirmed to be dominant nitrifying population species by scanning electron microscopic(SEM) observation and fluorescence in situ hybridization(FISH) analysis.This confirmation not only emphasized that cultivating the appropriate bacteria is essential for achieving stable nitritation performance,but it also revealed that NOB activity was strongly inhibited by FA rather than being eliminated altogether from the system.

The applications of hypervalent iodine(Ⅲ) reagents in the constructions of heterocyclic compounds through oxidative coupling reactions

Hypervalent iodine(Ⅲ)reagents have been vastly used in many useful organic transformations.In this review article,we highlight the strategies that used the common hypervalent iodine(Ⅲ)reagents as oxidants to synthesize the heterocyclic compounds,based on the patterns of bond formation during the construction of the heterocyclic backbones.

CONVEXIFICATION AND CONCAVIFICATION METHODS FOR SOME GLOBAL OPTIMIZATION PROBLEMS

In this paper, firstly, we propose several convexification and concavification transformations to convert a strictly monotone function into a convex or concave function, then we propose several convexification and concavification transformations to convert a non-convex and non-concave objective function into a convex or concave function in the programming problems with convex or concave constraint functions, and propose several convexification and concavification transformations to convert a non-monotone objective function into a convex or concave function in some programming problems with strictly monotone constraint functions. Finally, we prove that the original programming problem can be converted into an equivalent concave minimization problem, or reverse convex programming problem or canonical D.C. programming problem. Then the global optimal solution of the original problem can be obtained by solving the converted concave minimization problem, or reverse convex programming problem or canonical D.C. programming problem using the existing algorithms about them.

Silicon-based nanosheets synthesized by a topochemical reaction for use as anodes for lithium ion batteries

Silicon is the most promising anode material for the next generation high- performance lithium ion batteries. However, its commercial application is hindered by its poor performance due to the huge volume change during cycling. Although two-dimensional silicon-based materials show significantly improved performance, flexible synthesis of such materials is still a challenge. In this work, silicon-based nanosheets with a multilayer structure are synthesized for the first time by a topochemical reaction. The morphology and oxidation state of these nanosheets can be controlled by appropriate choice of reaction media and oxidants. Benefiting from the hierarchical structure and ultrathin size, when the silicon-based nanosheets are employed as anodes they exhibit a charge （delithiation） capacity of 800 mAh/g after 50 cycles with a maximum coulombic efficiency of 99.4% and good rate performance （647 mAh/g at 1 A/g）. This work demonstrates a novel method for preparing nanosheets not only for lithium ion batteries but also having various potential applications in other fields, such as catalysts, electronics and photonics.