新媒体支持下反转教学研究

在新媒体大力发展的今天,教师可以制作更加丰富的课件让学生预习,这些课件对不同年龄段、不同性格的学生作用会有所不同。教师要掌握好学生之间的差异,在做课件时候要有针对性,了解大多数学生的理解力和兴趣点,在课堂交流时才能合理引导学生。掌握反转教学的"度",找到反转教学与新媒体的最佳契合点,才能使教学效率达到最大化。

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide(O_3/H_2O_2 process) to degrade o-phenylenediamine(o-PDA) in a simulated wastewater. A rotor–stator reactor(RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA(η) as well as the overall gas-phase volumetric mass transfer coefficient(KGa) were determined under different operating conditions of H_2O_2 concentration, initial o-PDA concentration, temperature of reaction, initial p H and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate(rCOD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer(GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone(O_3 process), and it was noted that η, KGa and rCODachieved by O_3/H_2O_2 process was 24.4%,31.6% and 25.2% respectively higher than those of O_3 process, indicating that H_2O_2 can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.

Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate

Special proton-gradient-transfer acid complexes （PGTACs） in which the bonded protons are not equivalent and have gradients in transfer ability, acidity, and reactivity were reported. The acidity gradient of the protons gave the PGTACs excellent catalytic activity and selectivity in the esterifica- tion of terpenols. These PGTACs are ＂reaction-induced self-separation catalysts＂ and can be easily reused. The kinetics with PGTACs as catalyst in the esterification of geraniol were also studied for use in engineering design.

Extraction of potassium from K-feldspar via the CaCl_2 calcination route

The extraction of potassium from K-feldspar via a calcium chloride calcination route was studied with a focus on the effects of the calcination atmosphere, calcination temperature and time, mass ratio of CaCl2 to K-feldspar ore and particle size of the K-feldspar ore. The results demonstrated that a competing high-temperature hydrolysis reaction of calcium chloride with moisture in a damp atmosphere occurred concurrently with the conversion reaction of K-feldspar with CaCl2, thus reducing the amount of potassium extracted. The conversion reaction started at approximately 600 °C and accelerated with increasing temperature. When the temperature rose above 900 °C, the extraction of potassium gradually decreased due to the volatilization of the product, KCl.As much as approximately 41% of the potassium was volatilized in 40 min at 1100 °C. The mass ratio of CaCl2/K-feldspar ore significantly affected the extraction. At a mass ratio of 1.15 and 900 °C, the potassium extraction reached 91% in 40 min, while the extraction was reduced to only 22% at the theoretical mass ratio of 0.2. Optimal process conditions are as follows: ore particle size of 50–75 μm, tablet forming pressure of 3 MPa, dry nitrogen atmosphere, mass ratio of CaCl2/ore 1.15:1, calcination temperature of 900 °C, and calcination time of 40 min.The XRD analysis revealed that a complex phase transition of the product SiO2 was also accompanied by the conversion reaction of K-feldspar/CaCl2. The SiO2 product formed at the initial stage was in the quartz phase at 900 °C and was gradually transformed into cristobalite after 30 min.

Effect of Air Velocity on Thermal Comfort under Thermal Environment Ramp Changing

Set points of the indoor air temperature and relative humidity in short-term staying location were studied. In this condition, the thermal reaction of human body varied with the ramp changes of the environmental thermal parameters.The change rules of about 60 subjects′ thermal reaction to the ramp change of environment were surveyed, and the effect of air movement on the thermal reaction during transient condition was considered by using a questionnaire. With the experimental results and research findings under stable condition, a way to set environmental parameters of short-time staying location was recommended.

Temperature dependence of magnetization reversal mechanism in CoNi/CoO bilayers

Exchange coupling and magfietization reversal mechanism in two series of CoxNil-x/CoO （30 nm） （x=0.2 and 0.4） bilayers are studied by vector magnetometer. Two components of magnetization are measured parallel and perpendicular to the applied field. At low temperatures, coercivity Hc oc （tFM）^-n, n = 1.5 and 1.38 for x = 0.2 and 0.4, respectively, in agreement with the random field model. At room temperature, the coercivity is nearly proportional to the inverse FM layer thickness. In addition to the exchange field and the coercivity, the characteristic of the magnetization reversal mechanism was found to change with temperature. At temperatures below 180 K, magnetization reversal process along the unidirectional axis is accompanied only by nucleation and pinning of domain wall while magnetization rotation is also involved at high temperatures.

Investigation of Propene Oligomerization Catalyzed by Phosphotungstic Acid Catalysts

In this paper, the propene oligomerization reaction catalyzed by phosphotungstic acid supported on two kinds of silica gel was studied, it had been found out that the conversion of propene catalyzed by the type A silica gel-phosphotung- stic acid catalyst was 3.38 m%, while the conversion of propene catalyzed by the type B silica gel-phosphotungstic acid catalyst was 90.1 m% with a nonene selectivity of 42.33 m%, and a dodecene selectivity of 31.79 m%. The influence of reaction temperature, pressure and liquid hourly space velocity （LHSV） on the reaction catalyzed by the type B silica gel- phosphotungstic acid catalyst was investigated. It had been verified that when the reaction temperature increased from 170 ~C to 190 ~C, the conversion of propene increased while the selectivity of nonene and dodecene decreased; when the re- action pressure increased from 3.5 MPa to 4.5 MPa, the conversion of propene increased also, and the selectivity of nonene and dodecene changed very little. The conversion of propene at a space velocity of between 0.5 h-1 and 1.0 h-~ was higher than that achieved at 2.0 h-~, but the selectivity of nonene and dodecene did not show regular fluctuations. An optimum conversion of propene （91.05 m%） and an optimum selectivity of nonene and dodecene （89.51 m%） could be achieved at a reaction temperature of 170 ~C, a reaction pressure of 4.5MPa, and a LHSV of 1.0 fit. The experiments on catalyst life showed that the activity of the type B silica gel-phosphotungstic acid catalyst could be only maintained in 25 hours, and the reason was explained also.

Enhanced oxygen reduction reaction performance over Pd catalysts by oxygen-surface-modified SiC

Obtaining a detailed understanding of the surface modification of supports is crucial;however,it is a challenging task for the development and large-scale fabrication of supported electrocatalysts that can be used as alternatives to Pt-based catalysts for the oxygen reduction reaction(ORR).In this study,commercial silicon carbide(SiC)was modified through surface oxidization(O-SiC)to support the use of Pd nanoparticles(Pd NPs)as electrocatalysts for ORR.The obtained Pd/O-SiC catalysts exhibited better ORR activity,stronger durability,and higher resistance to methanol poisoning than that exhibited by commercial Pt/C.The role of the support in enhancing the ORR performance,especially the oxidization of SiC surfaces,was discussed in detail based on the experimental characterizations and density functional theory calculations.The underlying mechanism of the superior ORR performance of Pd/O-SiC catalysts was attributed to the charge transfer from SiC_(x)O_(y)to Pd NPs on the surfaces of SiC and the strong metal–support interactions(SMSIs)between Pd and SiC_(x)O_(y).The charge transfer enhanced the ORR activity by inducing electron-rich Pd,increased the adsorption of the key intermediate OOH,and decreased the Gibbs free energy of the critical ORR step.Furthermore,SMSIs enhanced the ORR stability of the Pd/O-SiC catalyst.This study provided a facile route for designing and developing highly active Pd-based ORR electrocatalysts.

Application of waterborne acrylic emulsions in coated controlled release fertilizer using reacted layer technology

Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tgof coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection.

Residue Upgrading in Slurry Phase over Ultra-fine NiMo/γ-Al_2O_3 Catalyst

In this article, residual oil hydroconversion was studied in slurry phase in the presence of fine solid Ni Mo/γ-Al2O3 catalyst and the effects of operating conditions were carefully studied. The results showed that residue conversion was only affected by the reaction temperature and reaction time. The coke yield increased with a higher reaction temperature, a bigger catalyst particle size, a longer reaction time, a lower initial hydrogen pressure and a lower catalyst concentration. Heteroatoms removal rate increased with a higher reaction temperature, a longer reaction time, a higher initial hydrogen pressure, a higher catalyst concentration, and a smaller catalyst particle size. The role of catalyst in the slurry bed technology was discussed and its function could be stated as follows: the metal was applied to activate the hydrogen atoms for removing heteroatoms and saturating aromatics, while the support of the catalyst was used to prevent the mesophase coalescence for reducing coke formation.

Propagation of Smooth Pulses in Anomalously Dispersive Media

In the present letters we study the propagation of smooth pulses in anomalously dispersive media. We prove that non-analytical but smooth points in a pulse still propagate with the vacuum speed of light, c. It gives an upper limit for signal velocity as well as the non-continuous points of the envelop of a pulse or its derivatives of arbitrary order do.

A Study on the Levitation Control of the Multi-degrees-of-Freedom Rotational Machine Supported by Magnetic Bearings Using Flux Feedback

This paper deals with an open-loop characteristic of a magnetically levitated system including flux feedback. In order to design a controller to obtain a good disturbance rejection and to be insensitive to parameter variations, it might be useful to employ a flux feedback loop. The air gap flux which can be sensed by a proper sensor has linear relationship with respect to the change of the current and the air gap. This linear property decreases the inherent nonlinearity of the magnetic suspension system that is caused by the coupling between the electrical actuator and the mechanical plant. Simulation results achieved from a multi-degree-of-freedom numerical model show that the flux feedback loop makes an improvement of the performance of the magnetic suspension system against the load variations.

Raman+EDFA混合宽带放大器增益谱优化的高效算法

采用遗传算法对Raman +EDFA混合放大器的增益谱进行了优化 ,根据二能级近似的EDFA模型及Raman功率耦合方程获得了简洁的适应度函数形式 ,可以在短时间内获得最优的放大器参数。计算表明 ,通过选择合适的拉曼抽运波长和抽运功率以及EDFA的平均反转度 ,仅用三个抽运源反向抽运的分布拉曼放大器加C波段EDFA就可以获得在 15 4 2～ 16 0 2nm共 6 0nm带宽上最大增益波动小于 1dB的平坦增益谱而无需额外的平坦滤波器。

An improved diagnostic stratocumulus scheme based on estimated inversion strength and its performance in GAMIL2

Based on satellite data and the estimated inversion strength(EIS) derived by Wood et al.(2006), a feasible and uncomplicated stratocumulus scheme is proposed, referred to as EIS scheme. It improves simulation of cloud radiative forcing(CRF) in the Grid-point Atmospheric Model of IAP/LASG version 2(GAMIL2.0) model. When compared with the original lower troposphere stability(LTS) scheme, the EIS scheme reproduces more reasonable climatology distributions of clouds and CRF. The parameterization partly corrects CRF underestimation at mid and high latitudes and overestimation in the convective region. Such improvements are achieved by neglecting the effect of free-tropospheric stratification changes that follow a cooler moist adiabat at middle and high latitude, thereby improving simulated cloudiness. The EIS scheme also improves simulation of the CRF interannual variability. The positive net CRF and negative stratiform anomaly in the East Asian and western North Pacific monsoon regions(EAWNPMR) are well simulated. The EIS scheme is more sensitive to sea surface temperature anomalies(SSTA) than the LTS. Therefore, under the effect of a warmer SSTA in the EAWNPMR, the EIS generates a stronger negative stratiform response, which reduces radiative heating in the low and mid troposphere, in turn producing strong subsidence and negative anomalies of both moisture and cloudiness. Consequent decreases in cloud reflection and shading effects ultimately improve simulation of incoming surface shortwave radiative fluxes and CRF. Because of the stronger subsidence, a stronger anomalous anticyclone over the Philippines Sea is simulated by the EIS run, which leads to a better positive precipitation anomaly in eastern China during ENSO winter.

Inverse Piston Problem for the System of One-Dimensional Isentropic Flow

In this paper, the authors consider the inverse piston problem for the system of one-dimensional isentropic flow and obtain that, under suitable conditions, the piston velocity can be uniquely determined by the initial state of the gas on the right side of the piston and the position of the forward shock.

High Temperature Catalytic Hydrogenation of Acetone over Raney Ni for Chemical Heat Pump

Exothermic hydrogenation reaction of acetone is an important part of an IAH-CHP, and the performance of IAH-CHP is affected directly by this reaction. This paper studies the influence of space velocity, temperature, hydrogen flow rate and pressure on conversion and selectivity experimentally. The byproducts are analyzed and classified into three types: hydrogenation product, cracking products and condensation products. Both the conversion and selectivity of this reaction have the same trend with the change of space velocity, temperature and hydrogen flow rate, and has the opposite trend with the change of pressure. As the space velocity increases, the conversion curve is a gradual decline parabola but the selectivity curve is close to a straight line. Hydrogen flow rate has a more obvious influence on conversion than temperature, whereas on selectivity the situation is opposite. High pressure increases the conversion of acetone to all products, but the increment of byproducts is more than that of isopropanol, so the selectivity decreases as pressure increases.

Multi-scale MSDT inversion based on LAI spatial knowledge

Quantitative remote sensing inversion is ill-posed. The Moderate Resolution Imaging Spectroradiometer at 250 m resolution （MODIS_250m） contains two bands. To deal with this ill-posed inversion of MODIS_250m data, we propose a framework, the Multi-scale, Multi-stage, Sample-direction Dependent, Target-decisions （Multi-scale MSDT） inversion method, based on spa- tial knowledge. First, MODIS images （1 km, 500 m, 250 m） are used to extract multi-scale spatial knowledge. The inversion accuracy of MODIS_lkm data is improved by reducing the impact of spatial heterogeneity. Then, coarse-scale inversion is taken as prior knowledge for the fine scale, again by inversion. The prior knowledge is updated after each inversion step. At each scale, MODIS_lkm to MODIS_250m, the inversion is directed by the Uncertainty and Sensitivity Matrix （USM）, and the most uncertain parameters are inversed by the most sensitive data. All remote sensing data are involved in the inversion, during which multi-scale spatial knowledge is introduced, to reduce the impact of spatial heterogeneity. The USM analysis is used to implement a reasonable allocation of limited remote sensing data in the model space. In the entire multi-scale inversion process field data, spatial knowledge and multi-scale remote sensing data are all involved. As the multi-scale, multi-stage inversion is gradually refined, initial expectations of parameters become more reasonable and their uncertainty range is effectively reduced, so that the inversion becomes increasingly targeted. Finally, the method is tested by retrieving the Leaf Area Index （LAI） of the crop canopy in the Heihe River Basin. The results show that the proposed method is reliable.

Time reversal of a discrete system coupled to a continuum based on non-Hermitian flip

Time reversal in quantum or classical systems described by an Hermitian Hamiltonian is a physically allowed process, which requires in principle inverting the sign of the Hamiltonian. Here we consider the problem of time reversal of a subsystem of discrete states coupled to an external environment characterized by a continuum of states, into which they generally decay. It is shown that, by flipping the discrete-continuum coupling from an Hermitian to a non-Hermitian interaction, thus resulting in a non unitary dynamics, time reversal of the subsystem of discrete states can be achieved, while the continuum of states is not reversed. Exact time reversal requires frequency degeneracy of the discrete states,or large frequency mismatch among the discrete states as compared to the strength of indirect coupling mediated by the continuum. Interestingly, periodic and frequent switch of the discrete-continuum coupling results in a frozen dynamics of the subsystem of discrete states.

Realization of population inversion between 7S_(1/2) and 6P_(3/2) levels of cesium for four-level active optical clock

We demonstrate experimentally the population inversion between 7S1/2 and 6P3/2 levels of cesium in thermal cesium cell with a 455.5 nm pumping laser.We calculate the relative population probabilities at each level theoretically with the density matrix method.In a steady state,5.8% atoms are at 7S1/2 level and 2.9% at 6P3/2 level,which builds up the population inversion between the two levels.We obtain the fluorescence spectra produced in thermal cesium cell in our experiment.The measured relative intensity of each available fluorescence spectral line in the experiment agrees very well with the theoretical result.The demonstrated population inversion between 7S1/2 and 6P3/2 levels can be used to construct an active optical clock of four-level system with a wavelength of 1469.9 nm.

An experimental study on the effects of relative rotation direction on the wake interferences among tandem wind turbines

An experimental study was conducted to investigate the effects of relative rotation direction on the wake interferences among two tandemwind turbines models.While the oncoming flow conditions were kept in constant during the experiments,turbine power outputs,wind loads acting on the turbines,and wake characteristics behind the turbines were compared quantitatively with turbine models in either co-rotating or counter-rotating configuration.The measurement results reveal that the turbines in counter-rotating would harvest more wind energy from the same oncoming wind,compared with the co-rotating case.While the recovery of the streamwise velocity deficits in the wake flows was found to be almost identical with the turbines operated in either co-rotating or counter-rotating,the significant azimuthal velocity generated in the wake flow behind the upstream turbine is believed to be the reason why the counter-rotating turbines would have a better power production performance.Since the azimuthal flow velocity in the wake flow was found to decrease monotonically with the increasing downstream distance,the benefits of the counter-rotating configuration were found to decrease gradually as the spacing between the tandem turbines increases.While the counter-rotating downstream turbine was found to produce up to 20%more power compared with that of co-rotating configuration with the turbine spacing being about 0.7D,the advantage was found to become almost negligible when the turbine spacing becomes greater than 6.5D.It suggests that the counter-rotating configuration design would be more beneficial to turbines in onshore wind farms due to the smaller turbine spacing(i.e.,~3 rotor diameters for onshore wind farms vs.~7 rotor diameters for offshore wind farms in the prevailing wind direction),especially for those turbines sited over complex terrains with the turbine spacing only about 1–2 rotor diameters.