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氧化铝基催化剂中铂、磷的同时发射光谱法测定 被引量:1
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作者 叶毓琼 杨军 邓耀全 《冶金分析》 CAS CSCD 北大核心 1993年第6期45-47,共3页
难熔氧化铝基催化剂中金属元素的测定已有报道.但同时测定其中的铂和磷,则尚未见到.铂,磷的物理、化学性质相差悬殊,同时测定有一定的难度.
关键词 催化剂 发光光谱分析
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纯氧化钪中十五个稀土杂质的发射光谱测定
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作者 唐秀玲 左家福 《有色金属分析通讯》 1992年第3期22-23,共2页
关键词 氧化钪 稀土杂质 发光光谱分析
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Synthesis and Characterization of Aluminum/Carbon Nanotubes Composites: Study of Interfacial Interaction
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作者 Mananna Barbeno Pasquale Barone +3 位作者 Valentino Pingitore Assunta Bonanno Mariano Davoli FangXu 《Journal of Chemistry and Chemical Engineering》 2013年第4期313-318,共6页
Abstract: In this work, the authors present a study of growth and characterization of composite based on AI and CNT (carbon nanotubes. The composites were prepared by a chemical mixing method and characterized by SE... Abstract: In this work, the authors present a study of growth and characterization of composite based on AI and CNT (carbon nanotubes. The composites were prepared by a chemical mixing method and characterized by SEM analysis, energy dispersed X-ray measurements, X-ray photoelectron spectroscopy and cathodoluminescence spectroscopy. The analysis showed that the composites are formed by macro-cluster of aluminum oxide on a network of CNT without formation of chemical bonds at interface between particles. The results are compared with those obtained for a sample of CNT with AI traces (〈 0.5%). They show that only the presence of metal traces changes the nanotubes optical properties, with a luminescence signal centered at about 380 nm. These luminescence signals are caused by the adhesion between CNT and AI micro-clusters that promote the formation of band gap with some local energy levels. 展开更多
关键词 Carbon nanotubes ALUMINUM interface structure metal-CNT composite.
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Resonance-Enhanced Photon Excitation Spectroscopy of the Even-Parity Autoionizing Rydberg States of Xe
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作者 Chun-yan Li Ting-ting Wang +2 位作者 Jun-feng Zhen Qun Zhang Yang Chen 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第5期401-406,共6页
Xenon atoms were produced in their metastable states 5p^56s[3/2]2 and 5p^56s'[1/2]0 in a pulsed DC discharge in a beam, and subsequently excited to the even-parity autoionizing Rydberg states 5p^5np' [3/2] 1,[1/2] 1... Xenon atoms were produced in their metastable states 5p^56s[3/2]2 and 5p^56s'[1/2]0 in a pulsed DC discharge in a beam, and subsequently excited to the even-parity autoionizing Rydberg states 5p^5np' [3/2] 1,[1/2] 1, and 5p^5nf' [5/2] 3 using single photon excitation. The excitation spectra of the even-parity autoionizing resonance series from the metastable 129Xe were obtained by recording the autoionized Xe+ with time-of-flight ion detection in the photon energy range of 28000-42000 cm-1. A wealth of autoionizing resonances were newly observed, from which more precise and systematic spectroscopic data of the level energies and quantum defects were derived. 展开更多
关键词 XE Pulsed DC discharge Resonance-enhanced photon excitation spectroscopy Autoionizing resonance
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Analysis on porous Si PL from quantum confinement effect
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作者 WANGKaiyuan TANGJieying 《Semiconductor Photonics and Technology》 CAS 1995年第1期84-87,共4页
We have measured the variation of photoluminescence(PL) in porous silicon with anodization(AO) time,HF soak time or natural oxidation time,and found that the peak value of PL spectrum will shift towards shorter value ... We have measured the variation of photoluminescence(PL) in porous silicon with anodization(AO) time,HF soak time or natural oxidation time,and found that the peak value of PL spectrum will shift towards shorter value as above time is increased.The analyses in experiment and theory show that the quantum confined structures produced by the AO process may be responsible for the blue shift. 展开更多
关键词 Porous Materials Anodization Spectral Analysis PHOTOLUMINESCENCE Quantum Confinement Effect
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二胺基二硅烷及二氮杂环硅烷的合成、表征及其性质 被引量:6
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作者 崔孟忠 赵一新 +3 位作者 张斌 席靖宇 王曙光 唐小真 《科学通报》 EI CAS CSCD 北大核心 2005年第8期745-750,共6页
通过二氯硅烷与碱金属的Wurtz偶联反应产物的氨解反应,合成得到了二胺基二硅烷和二氮杂环硅烷化合物,在表征合成化合物的基础上,发现了Si-H键的红外吸收峰裂分.通过红外光谱进一步研究了合成化合物的水解、缩合聚合反应过程,观测到了Si-... 通过二氯硅烷与碱金属的Wurtz偶联反应产物的氨解反应,合成得到了二胺基二硅烷和二氮杂环硅烷化合物,在表征合成化合物的基础上,发现了Si-H键的红外吸收峰裂分.通过红外光谱进一步研究了合成化合物的水解、缩合聚合反应过程,观测到了Si-H键振动吸收峰的裂分转变.通过对两种含硅氢键化合物的几种稳定的几何异构体进行密度泛函理论(DFT)计算,结果表明化合物的红外光谱Si-H键振动峰的裂分,是由不同的几何异构体同时存在所致.合成化合物在空气中的水解、缩合聚合反应,得到了一类新型的有机硅聚合物-聚二硅氧烷,该聚合物的主链结构具有Si-O-Si和Si-Si交替存在的序列单元.通过发光光谱分析,证实了该类聚合物具有类似于聚硅烷的光致发光性质. 展开更多
关键词 氮杂环 二硅烷 二胺基 密度泛函理论(DFT) 表征 合成化合物 几何异构体 有机硅聚合物 发光光谱分析 光致发光性质 红外光谱 氨解反应 反应产物 二氯硅烷 反应过程 缩合聚合 聚合反应 二硅氧烷 主链结构 吸收峰 Si 碱金属
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Implantation induced defects and electrical properties of Sb-implanted ZnO 被引量:1
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作者 XIE Hui LIU Tong +4 位作者 LIU JingMing CAO Ke Wei DONG ZhiYuan YANG Jun ZHAO YouWen 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第8期1333-1338,共6页
Defects in Sb implanted Zn O single crystals have been studied by using photoluminescence(PL) spectroscopy,X-ray diffraction(XRD) and Raman scattering.Electrical properties of the samples were analyzed by Hall effect ... Defects in Sb implanted Zn O single crystals have been studied by using photoluminescence(PL) spectroscopy,X-ray diffraction(XRD) and Raman scattering.Electrical properties of the samples were analyzed by Hall effect measurement.The results indicate that the annealed Sb-implanted sample is n-type with a free electron concentration of the same amplitude as the calculated implantation concentration.The well-known oxygen vacancy related deep level green PL band is suppressed in the as-implanted sample and recovers to the level close to the as-grown Zn O single crystal after annealing.These phenomena suggest that a large portion of as-implanted Sb atoms occupy oxygen lattice site in an unstable state and move to the interstitial site,forming the complex donor defect upon high temperature annealing,resulting in n-type conduction even if the implantation dose is quite high. 展开更多
关键词 ZNO PHOTOLUMINESCENCE Ramam scattering Hall measurement ion implantation DEFECT
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