A novel blue\|light\|emitting functional copolymer containing alternating rigid conjugated PPV and flexible ionic conductivity PEO blocks in the main chain was synthesized by using the Wittig reaction.The copolymer wa...A novel blue\|light\|emitting functional copolymer containing alternating rigid conjugated PPV and flexible ionic conductivity PEO blocks in the main chain was synthesized by using the Wittig reaction.The copolymer was characterized by FT\|IR, 1H\|NMR, UV\|Vis, DSC, GPC, etc.The results show that the copolymer can be soluble in chloroform and tetrahydrofuran,with T g=50 5℃, T d=205℃, a maximum absorption peak in UV\|Vis spectrum at 354nm and an emission peak in the photoluminescent spectrum at 438nm for solution in chloroform and at 475nm for film. It is a good blue emitter for fabricating LED or LEC.展开更多
Two soluble copolymers of fluorenone and dioctoxylbenzene （PFN） or anthracene （PFNAn） were synthesized through Heck polymerization, and were characterized by gel permeation chromatography （GPC）, FT-IR, IH-NMR, e...Two soluble copolymers of fluorenone and dioctoxylbenzene （PFN） or anthracene （PFNAn） were synthesized through Heck polymerization, and were characterized by gel permeation chromatography （GPC）, FT-IR, IH-NMR, elemental analysis and thermogravimetric analysis. The polymers possess good solubility in common organic solvents and high thermal stability with the Onset decomposition temperature at higher than 410 ℃. The photophysical properties of the polymers were investigated in both solutions and spin-coated films. Cyclic voltammetry results revealed that the copolymers possess higher electron affinity and reversible reduction/re-oxidation processes. Their electroluminescent properties were further investigated. PFN and PFNAn show stable and saturated red light emission with high thermal stability and high electron injection ability. This type of conjugated polymers may be promising for the applications as electron acceptors in polymer photovoltaic cells and electron transporting materials.展开更多
Tetraphenylethene (TPE) is a popular luminogen characterized by aggregation-induced emission and has been widely used to construct solid-state emissive materials. In this work, two thermally stable polymers (P1 and P2...Tetraphenylethene (TPE) is a popular luminogen characterized by aggregation-induced emission and has been widely used to construct solid-state emissive materials. In this work, two thermally stable polymers (P1 and P2) consisting of TPE conjugated to the 2,7-positions of fluorene and carbazole, respectively, are synthesized and characterized. Both polymers are weakly fluorescent in solutions but show greatly enhanced emission as the aggregate formation, presenting an aggregation-enhanced emission feature. Two kinds of polymer light-emitting diodes are fabricated utilizing P1 and P2 as emitters (EML) (device I: ITO/PEDOT:PSS (45 nm)/PVK:EML (1:1 wt%, 55 nm)/TPBI (38 nm)/Ca:Ag; device II: ITO/PEDOT:PSS (45 nm)/ PVK:OXD-7:EML (3:1:3 wt%, 55 nm)/TPBI (38 nm)/Ca:Ag). The device II of P2 shows the best performances, affording a maximum luminance of 6500 cd/m 2 and a high peak efficiency of 2.11 cd/A.展开更多
A series of alkali metal salts doped pluronic block copolymer F127 were used as electron injection/transport layers (ETLs) for polymer light-emitting diodes with poly[2-(4-(3′,7′-dimethyloctyloxy)-phenyl)-p-phenylen...A series of alkali metal salts doped pluronic block copolymer F127 were used as electron injection/transport layers (ETLs) for polymer light-emitting diodes with poly[2-(4-(3′,7′-dimethyloctyloxy)-phenyl)-p-phenylenevinylene] (P-PPV) as the emission layer. It was found that the electron transport capability of F127 can be effectively enhanced by doping with alkali metal salts. By using Li2CO3 (15%) doped F127 as ETL, the resulting device exhibited improved performance with a maximum luminous efficiency (LE) of 13.59 cd/A and a maximum brightness of 5529 cd/m2, while the device with undoped F127 as ETL only showed a maximum LE of 8.78 cd/A and a maximum brightness of 2952 cd/m2. The effects of the doping concentration, cations and anions of the alkali metal salts on the performance of the resulting devices were investigated. It was found that most of the alkali metal salt dopants can dramatically enhance the electron transport capability of F127 ETL and the performance of the resulting devices was greatly improved.展开更多
文摘A novel blue\|light\|emitting functional copolymer containing alternating rigid conjugated PPV and flexible ionic conductivity PEO blocks in the main chain was synthesized by using the Wittig reaction.The copolymer was characterized by FT\|IR, 1H\|NMR, UV\|Vis, DSC, GPC, etc.The results show that the copolymer can be soluble in chloroform and tetrahydrofuran,with T g=50 5℃, T d=205℃, a maximum absorption peak in UV\|Vis spectrum at 354nm and an emission peak in the photoluminescent spectrum at 438nm for solution in chloroform and at 475nm for film. It is a good blue emitter for fabricating LED or LEC.
基金Projects(50803074, 50633050) supported by the National Natural Science Foundation of ChinaProject supported by the Opening Fund of State Key Laboratory of Powder MetallurgyStart-up Fund of Central South University, China
文摘Two soluble copolymers of fluorenone and dioctoxylbenzene （PFN） or anthracene （PFNAn） were synthesized through Heck polymerization, and were characterized by gel permeation chromatography （GPC）, FT-IR, IH-NMR, elemental analysis and thermogravimetric analysis. The polymers possess good solubility in common organic solvents and high thermal stability with the Onset decomposition temperature at higher than 410 ℃. The photophysical properties of the polymers were investigated in both solutions and spin-coated films. Cyclic voltammetry results revealed that the copolymers possess higher electron affinity and reversible reduction/re-oxidation processes. Their electroluminescent properties were further investigated. PFN and PFNAn show stable and saturated red light emission with high thermal stability and high electron injection ability. This type of conjugated polymers may be promising for the applications as electron acceptors in polymer photovoltaic cells and electron transporting materials.
基金the National Natural Science Foundation of China (51273053, 21104012, 21284034 and 61106017)the Natural Science Foundation of Zhejiang Province (Y4110331)+1 种基金the Program for Changjiang Scholars and Innovative Research Teams in Chinese Universities (IRT 1231)the Project of Zhejiang Key Scientific and Technological Innovation Team (2010R50017)
文摘Tetraphenylethene (TPE) is a popular luminogen characterized by aggregation-induced emission and has been widely used to construct solid-state emissive materials. In this work, two thermally stable polymers (P1 and P2) consisting of TPE conjugated to the 2,7-positions of fluorene and carbazole, respectively, are synthesized and characterized. Both polymers are weakly fluorescent in solutions but show greatly enhanced emission as the aggregate formation, presenting an aggregation-enhanced emission feature. Two kinds of polymer light-emitting diodes are fabricated utilizing P1 and P2 as emitters (EML) (device I: ITO/PEDOT:PSS (45 nm)/PVK:EML (1:1 wt%, 55 nm)/TPBI (38 nm)/Ca:Ag; device II: ITO/PEDOT:PSS (45 nm)/ PVK:OXD-7:EML (3:1:3 wt%, 55 nm)/TPBI (38 nm)/Ca:Ag). The device II of P2 shows the best performances, affording a maximum luminance of 6500 cd/m 2 and a high peak efficiency of 2.11 cd/A.
基金supported by the National Natural Science Foundation of China (21125419, 50990065, 51010003, 51073058, and 20904011)National Research Project (2009CB623601 and 2009CB930604)
文摘A series of alkali metal salts doped pluronic block copolymer F127 were used as electron injection/transport layers (ETLs) for polymer light-emitting diodes with poly[2-(4-(3′,7′-dimethyloctyloxy)-phenyl)-p-phenylenevinylene] (P-PPV) as the emission layer. It was found that the electron transport capability of F127 can be effectively enhanced by doping with alkali metal salts. By using Li2CO3 (15%) doped F127 as ETL, the resulting device exhibited improved performance with a maximum luminous efficiency (LE) of 13.59 cd/A and a maximum brightness of 5529 cd/m2, while the device with undoped F127 as ETL only showed a maximum LE of 8.78 cd/A and a maximum brightness of 2952 cd/m2. The effects of the doping concentration, cations and anions of the alkali metal salts on the performance of the resulting devices were investigated. It was found that most of the alkali metal salt dopants can dramatically enhance the electron transport capability of F127 ETL and the performance of the resulting devices was greatly improved.
