This research focuses on measuring the mode transformation and energy attenuation of wedge waves for different apex angle wedges by using laser ultrasound techniques.Pulsed laser excitation and optical deflection beam...This research focuses on measuring the mode transformation and energy attenuation of wedge waves for different apex angle wedges by using laser ultrasound techniques.Pulsed laser excitation and optical deflection beam methods for detection were used to measure the wedge waves.In experiment,various wedge waves at different locations were recorded by scanning the excitation laser along the wedge tip,and different orders of wedge waves were observed.By fixing the distance between the excitation and detection positions and scanning the samples along the direction normal to the wedge tip,the modes transformation process was obtained.It was found that the energy of the acoustic waves for 20°,25° and 30° wedges decreased exponentially to a steady energy of Rayleigh wave within the main wavelength range of the acoustic modes,while the energy of acoustic waves of 45° and 60° wedge remained stable as the propagation line was scanned away from the wedge tip.展开更多
Switching on/off single-molecule magnets(SMMs)at room temperature is still a challenge in moleculebased magnets.Herein,two photochromic Ln-based(Ln=Dy,Tb)phosphonate coordinated polymers were synthesized with regulabl...Switching on/off single-molecule magnets(SMMs)at room temperature is still a challenge in moleculebased magnets.Herein,two photochromic Ln-based(Ln=Dy,Tb)phosphonate coordinated polymers were synthesized with regulable SMM behavior.The reversible room-temperature photo-coloration was an electron transfer process with a generation of relatively stable radicals,characterized by structural analyses,ultraviolet-visible,luminescence and electron spin resonance spectra and magnetic measurements.Importantly,owing to the antiferromagnetic coupling interactions between Ln^(3+) ions and photogenerated radicals,the room-temperature light irradiation surprisingly switched off the SMM behavior,showing the first example of radicalquenched SMMs in the molecule-based magnets.Moreover,the silient SMM behavior could be recovered after eliminating photogenerated radicals via heat treatment,showing a reversible off/on switch of SMMs via light and heat.This work constructs a system for switching off/on SMMs through electron transfer photochromism,providing a visual operation way via naked-eye-detectable coloration for the switchable SMMs.展开更多
The phenomenon that different molecular packing modes in aggregates result in different optical properties has attracted intense attention,since it can provide useful information to establish the relationship between ...The phenomenon that different molecular packing modes in aggregates result in different optical properties has attracted intense attention,since it can provide useful information to establish the relationship between the micro-and macro-world.In this paper,DBTDO-DMAC was designed with 9,10-dihydro-9,9-dimethylacridine(DMAC)as electron donor.DBTDO-DPA and DBTDO-Cz were designed for comparison,which adopted diphenylamine(DPA)with twisted structure and carbazole(Cz)with planar structure as donors,respectively.As expected,two polymorphs(Crystal G and Crystal Y)of DBTDO-DMAC were obtained and exhibited distinct properties.Crystal G originating from planar conformation exhibited mechanochromism(MC)phenomenon and the emission color changed from green to yellow with a redshift of 35 nm after grinding.Nevertheless,Crystal Y with folded conformation displayed obvious room-temperature phosphorescence(RTP)with yellow afterglow.Careful single crystal analyses,powder X-ray diffraction and theoretical calculation reveal that the different emissive behaviors are highly related to the molecular conformation and packing modes.The successful adjustment of molecular conformation provides some guidance in the design of other MC and/or RTP luminogens,broadens the molecule family with the tunable molecular conformation and opens up a new avenue for exploring possible adjustment of molecular packing in aggregates.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 60878023 and 61108013)the program for New Century Excellent Talents in University (NCET)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘This research focuses on measuring the mode transformation and energy attenuation of wedge waves for different apex angle wedges by using laser ultrasound techniques.Pulsed laser excitation and optical deflection beam methods for detection were used to measure the wedge waves.In experiment,various wedge waves at different locations were recorded by scanning the excitation laser along the wedge tip,and different orders of wedge waves were observed.By fixing the distance between the excitation and detection positions and scanning the samples along the direction normal to the wedge tip,the modes transformation process was obtained.It was found that the energy of the acoustic waves for 20°,25° and 30° wedges decreased exponentially to a steady energy of Rayleigh wave within the main wavelength range of the acoustic modes,while the energy of acoustic waves of 45° and 60° wedge remained stable as the propagation line was scanned away from the wedge tip.
基金supported by the National Natural Science Foundation of China(21901133,22171155 and 22071126)the State Key Laboratory of Fine Chemicals(KF1905)。
文摘Switching on/off single-molecule magnets(SMMs)at room temperature is still a challenge in moleculebased magnets.Herein,two photochromic Ln-based(Ln=Dy,Tb)phosphonate coordinated polymers were synthesized with regulable SMM behavior.The reversible room-temperature photo-coloration was an electron transfer process with a generation of relatively stable radicals,characterized by structural analyses,ultraviolet-visible,luminescence and electron spin resonance spectra and magnetic measurements.Importantly,owing to the antiferromagnetic coupling interactions between Ln^(3+) ions and photogenerated radicals,the room-temperature light irradiation surprisingly switched off the SMM behavior,showing the first example of radicalquenched SMMs in the molecule-based magnets.Moreover,the silient SMM behavior could be recovered after eliminating photogenerated radicals via heat treatment,showing a reversible off/on switch of SMMs via light and heat.This work constructs a system for switching off/on SMMs through electron transfer photochromism,providing a visual operation way via naked-eye-detectable coloration for the switchable SMMs.
基金the National Natural Science Foundation of China(21875130)the Starting Foundation of Tianjin Universitythe Project of“100 Talents Program”of Shanxi Province。
文摘The phenomenon that different molecular packing modes in aggregates result in different optical properties has attracted intense attention,since it can provide useful information to establish the relationship between the micro-and macro-world.In this paper,DBTDO-DMAC was designed with 9,10-dihydro-9,9-dimethylacridine(DMAC)as electron donor.DBTDO-DPA and DBTDO-Cz were designed for comparison,which adopted diphenylamine(DPA)with twisted structure and carbazole(Cz)with planar structure as donors,respectively.As expected,two polymorphs(Crystal G and Crystal Y)of DBTDO-DMAC were obtained and exhibited distinct properties.Crystal G originating from planar conformation exhibited mechanochromism(MC)phenomenon and the emission color changed from green to yellow with a redshift of 35 nm after grinding.Nevertheless,Crystal Y with folded conformation displayed obvious room-temperature phosphorescence(RTP)with yellow afterglow.Careful single crystal analyses,powder X-ray diffraction and theoretical calculation reveal that the different emissive behaviors are highly related to the molecular conformation and packing modes.The successful adjustment of molecular conformation provides some guidance in the design of other MC and/or RTP luminogens,broadens the molecule family with the tunable molecular conformation and opens up a new avenue for exploring possible adjustment of molecular packing in aggregates.
