Eu2+ -activated reddish-orange-emitting Ca3Si2O7 phosphors were synthesized with the addition of NH4Cl flux.When the phosphors were synthesized in a nominal composition of (Ca0.99Eu0.01)3Si2O7 without flux addition,a ...Eu2+ -activated reddish-orange-emitting Ca3Si2O7 phosphors were synthesized with the addition of NH4Cl flux.When the phosphors were synthesized in a nominal composition of (Ca0.99Eu0.01)3Si2O7 without flux addition,a Ca3Si2O7 phase responsible for reddish-orange emission was identified to coexist with an intermediate phase of a-Ca2SiO4 for green emission.With the addition of NH4Cl flux,a-Ca2SiO4 was suppressed while the pure phase Ca3Si2O7 was obtained as the flux content was 3 wt%.Through varying the amount of flux,the emission color of samples can be tuned from green to reddish-orange,corresponding to the phase transformation from a-Ca2SiO4 to Ca3Si2O7.Through optimizing the doping concentration of Eu2+ ,the optimized photoluminescence (PL) properties for reddish-orange emission can be achieved,which makes this kind of phosphor prospective in the applications of the phosphor-converted white light emitting diodes (PC-WLEDs).展开更多
Y99-61799-365 0007491场发射阵列的技术与材料=Field emitter arrays tech-nologies and materials[会,英]/Kleps,I.& Banoiu,G.//Proceedings of 1998 International SemiconductorConference,Vol.2.—365~368(UG)利用不同的微...Y99-61799-365 0007491场发射阵列的技术与材料=Field emitter arrays tech-nologies and materials[会,英]/Kleps,I.& Banoiu,G.//Proceedings of 1998 International SemiconductorConference,Vol.2.—365~368(UG)利用不同的微加工技术已加工出具有各种图形特点的硅发射阵列。其发射极的几何形状能利用变化其技术参数(腐蚀率,选择性和表面形貌)进行修正。为改进其场发射特性,还能用各种材料对硅发射极进行包敷。展开更多
基金supported by the National Natural Science Foundation of China (Nos.50872091,21076161 and 50802062)the Tianjin Municipal Science/Technology Commission (Nos.10SYSYJC28100 and 2006ZD30)the Tianjin Municipal Higher Education Commission (No.20110304)
文摘Eu2+ -activated reddish-orange-emitting Ca3Si2O7 phosphors were synthesized with the addition of NH4Cl flux.When the phosphors were synthesized in a nominal composition of (Ca0.99Eu0.01)3Si2O7 without flux addition,a Ca3Si2O7 phase responsible for reddish-orange emission was identified to coexist with an intermediate phase of a-Ca2SiO4 for green emission.With the addition of NH4Cl flux,a-Ca2SiO4 was suppressed while the pure phase Ca3Si2O7 was obtained as the flux content was 3 wt%.Through varying the amount of flux,the emission color of samples can be tuned from green to reddish-orange,corresponding to the phase transformation from a-Ca2SiO4 to Ca3Si2O7.Through optimizing the doping concentration of Eu2+ ,the optimized photoluminescence (PL) properties for reddish-orange emission can be achieved,which makes this kind of phosphor prospective in the applications of the phosphor-converted white light emitting diodes (PC-WLEDs).
文摘Y99-61799-365 0007491场发射阵列的技术与材料=Field emitter arrays tech-nologies and materials[会,英]/Kleps,I.& Banoiu,G.//Proceedings of 1998 International SemiconductorConference,Vol.2.—365~368(UG)利用不同的微加工技术已加工出具有各种图形特点的硅发射阵列。其发射极的几何形状能利用变化其技术参数(腐蚀率,选择性和表面形貌)进行修正。为改进其场发射特性,还能用各种材料对硅发射极进行包敷。