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基于喷动床技术的超临界CO2聚氨酯珠粒发泡工艺
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作者 夏成志 陈弋翀 +3 位作者 许志美 宗原 刘涛 赵玲 《工程塑料应用》 CAS CSCD 北大核心 2020年第5期63-68,共6页
以热塑性聚氨酯为原料,超临界CO2为发泡剂,通过喷动床发泡技术制备了热塑性聚氨酯发泡珠粒,考察了CO2流速、饱和温度、饱和压力、泄压速率对珠粒发泡行为的影响。结果表明,珠粒发泡均匀性先随着CO2流速上升而上升,之后基本不变,表明形... 以热塑性聚氨酯为原料,超临界CO2为发泡剂,通过喷动床发泡技术制备了热塑性聚氨酯发泡珠粒,考察了CO2流速、饱和温度、饱和压力、泄压速率对珠粒发泡行为的影响。结果表明,珠粒发泡均匀性先随着CO2流速上升而上升,之后基本不变,表明形成稳定喷动后流速的提升对珠粒发泡均匀性无改善作用。珠粒发泡倍率随着饱和温度和饱和压力的提高先上升后下降,随着泄压速率的提高而提高。饱和温度的提高使泡孔密度下降,泡孔直径增大,饱和压力和泄压速率的提高使泡孔密度上升,泡孔直径下降。当CO2流速为0.012 m/s、饱和温度为150℃、饱和压力为10 MPa、泄压速率为20 MPa/s时,珠粒发泡倍率最大,达到9倍,泡孔密度为1.13×107个/cm3,平均泡孔直径为82.3μm。 展开更多
关键词 喷动床 超临界CO2 珠粒 热塑聚氨酯 发泡均匀性
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Study on properties of tetrapod-like zinc oxide whisker/silicone rubber foam composites
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作者 DING Guo-fang CHEN Qing-min LUO Shi-kai SHI Yao-gang HE Chuan-lan 《Journal of Chemistry and Chemical Engineering》 2009年第4期32-38,共7页
In this paper, the microcellular silicone rubber foams, strengthened with tetrapod-like Zinc Oxide whisker(T-ZnOw) are prepared. Through further characterization, it can be seen that the average cell diameter size o... In this paper, the microcellular silicone rubber foams, strengthened with tetrapod-like Zinc Oxide whisker(T-ZnOw) are prepared. Through further characterization, it can be seen that the average cell diameter size of the filled with T-ZnOw is reduced. The distribution uniformity of microcellulars is improved obviously with increasing T-ZnOw filler. The reason that introduction of T-ZnOw can greatly enhance mechanical properties of the microcellular silicone rubber foams is its good interfacial adhesion with the matrix contributes. It is also found that the reducing effects of T-ZnOw on the compressive stress relaxation ratio of microcellular silicone rubber foams, and the improvement is obvious with increasing T-ZnOw filler. 展开更多
关键词 T-ZNOW silicone rubber foams MICROSTRUCTURE PROPERTIES
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