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和频振动光谱研究多晶金电极/溶液界面乙腈分子取向的flip-flop行为
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作者 黄芝 唐鑫 +3 位作者 邓罡华 周恩财 王鸿飞 郭源 《电化学》 CAS CSCD 北大核心 2011年第2期134-138,共5页
应用和频振动光谱研究乙腈/金电极界面吸附,观测到乙腈的甲基振动峰强度随电极电势而变化.当电极电势越过零电荷电势(pzc)时,甲基振动峰符号发生反转,这意味着该基团取向发生反转(flip-flop).由此而推断乙腈分子在金电极界面的吸附构型... 应用和频振动光谱研究乙腈/金电极界面吸附,观测到乙腈的甲基振动峰强度随电极电势而变化.当电极电势越过零电荷电势(pzc)时,甲基振动峰符号发生反转,这意味着该基团取向发生反转(flip-flop).由此而推断乙腈分子在金电极界面的吸附构型.即在零电荷电势下,电极界面吸附的乙腈分子构型为甲基靠近电极表面而腈基远离电极表面;高于零电荷电势,则变为腈基靠近电极表面而甲基远离电极表面. 展开更多
关键词 和频振动光谱 取向反转 金电极 乙腈
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Molecular Axis Orientation in Charge Transfer Reactions Determined with a Reaction Microscope
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作者 Shao-feng Zhang Xin-wen Ma Xiao-long Zhu 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第6期621-626,J0002,共7页
Based on the reaction microscope at the institute of modern physics, the reaction mechanism in molecular ion-atom collisions is investigated experimentally. The features of this system is illustrated by a kinematicall... Based on the reaction microscope at the institute of modern physics, the reaction mechanism in molecular ion-atom collisions is investigated experimentally. The features of this system is illustrated by a kinematically complete experhnent performed for the collision process. Using the so-called list-mode data recording technique and the coincidence measurement, the momentum vector of each fragment from the molecular ion were recorded event by event. The orientation of the molecular axis for H2^+ dissociation reactions could be determined for each event in the off-line analysis. The measured orientation of the molecular ion is believed the same as the one at the instance of collision under axial recoil approximation. The polar angle resolution of the molecular orientation of ±8° was obtained. 展开更多
关键词 Reaction microscope Imaging technique Molecular orientation Hydrogen molecular ion DISSOCIATION
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