Solid-state phase transitions of 4-methylanilinium perchlorate (4-CH3C6H4NH3.C104, 1) and tetrafluoroborate (4-CH3C6H4- NH3-BF4, 2) were investigated with variable-temperature X-ray single-crystal structure analys...Solid-state phase transitions of 4-methylanilinium perchlorate (4-CH3C6H4NH3.C104, 1) and tetrafluoroborate (4-CH3C6H4- NH3-BF4, 2) were investigated with variable-temperature X-ray single-crystal structure analysis and thermal studies. Both 1 and 2 undergo first-order phase transitions and exhibit distinct dielectric anomalies at 385 and 247 K, respectively.展开更多
基金supported by the National Natural Science Foundation of China (21071030)Natural Science Foundation of Jiangsu Province(BK2010425)
文摘Solid-state phase transitions of 4-methylanilinium perchlorate (4-CH3C6H4NH3.C104, 1) and tetrafluoroborate (4-CH3C6H4- NH3-BF4, 2) were investigated with variable-temperature X-ray single-crystal structure analysis and thermal studies. Both 1 and 2 undergo first-order phase transitions and exhibit distinct dielectric anomalies at 385 and 247 K, respectively.