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变比热容对喷管流场和性能影响的计算 被引量:9
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作者 王占学 王建峰 唐狄毅 《推进技术》 EI CAS CSCD 北大核心 2000年第4期60-62,共3页
从变比热容角度出发 ,采用CFD方法计算了发动机加力工作时高温状态下喷管内部流场分布和性能 ,并和定比热容计算结果进行了比较。结果表明 ,采用CFD方法计算加力工作时喷管内部流场和性能 ,应该考虑变比热容的影响。
关键词 航空发动机 喷管流场 变化热容 CFD方法
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部分聚合物结构与热容变化关系研究 被引量:8
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作者 李建凤 谢永红 雷光东 《计算机与应用化学》 CAS 2016年第7期833-837,共5页
以非氢原子及非氢原子间的关系为结构描述符,对部分聚合物结构单元进行了结构表征。采用多元线性回归和偏最小二乘回归的方法建立了该类聚合物结构与聚合物在玻璃化转变温度的热容变化(C_(p,change))之间的关系模型,两模型的复相关系数... 以非氢原子及非氢原子间的关系为结构描述符,对部分聚合物结构单元进行了结构表征。采用多元线性回归和偏最小二乘回归的方法建立了该类聚合物结构与聚合物在玻璃化转变温度的热容变化(C_(p,change))之间的关系模型,两模型的复相关系数(R)分别为0.919和0.900。采用"留一法"交互检验对模型的稳健性和预测能力进行了评价,交互检验的复相关系数(Q^2)分别为0.658和0.693。结果表明结构描述符能够恰当表现该类聚合物结构特征,所建模型的稳健性和预测能力好,热容变化(C_(p,change))的模型预测值具有一定的参考价值。 展开更多
关键词 热容变化(Cp.change) 结构描述符 聚合物 结构与性质
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用量子化学参数预测烯烃聚合物热容变化(英文) 被引量:2
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作者 谢治民 易平贵 《计算机与应用化学》 CAS CSCD 北大核心 2008年第6期679-681,共3页
在B3LYP/6-31G(d)水平上对烯烃聚合物单体进行密度泛函理论计算,得到2个量子化学参数,即分子的等容摩尔热容(C_v)和偶极矩(μ),并用来预测烯烃聚合物在玻璃化转变温度的热容变化(C_(p,change)).从训练集用逐步线性回归方法得到的、物理... 在B3LYP/6-31G(d)水平上对烯烃聚合物单体进行密度泛函理论计算,得到2个量子化学参数,即分子的等容摩尔热容(C_v)和偶极矩(μ),并用来预测烯烃聚合物在玻璃化转变温度的热容变化(C_(p,change)).从训练集用逐步线性回归方法得到的、物理意义非常明确的结构与性能定量关系模型由测试集进行检验.预测值与实验值的相关系数为0.937.这结果表明由这些量子化学参数所建立的关于性能C_(p,change)的定量关系模型能用于聚合物C_(p,change)值的预测,这也证明了量子化学参数能在聚合物结构与性能定量关系研究中能起重要作用. 展开更多
关键词 结构一性能定量关系 量子化学参数 聚合物 热容变化
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Influence of Zeotropic Mixtures' Temperature Gliding on the Performance of Heat Transfer in Condenser or Evaporator 被引量:4
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作者 赵力 高攀 《Transactions of Tianjin University》 EI CAS 2005年第6期400-406,共7页
Many zeotropic refrigerant mixtures are proposed as alternatives to some chlorofluorocar-bons (CFCs) and hydrochlorofluorocarbons ( HCFCs). An advantage of zeotropic mixtures is the possibility of reduction in entropy... Many zeotropic refrigerant mixtures are proposed as alternatives to some chlorofluorocar-bons (CFCs) and hydrochlorofluorocarbons ( HCFCs). An advantage of zeotropic mixtures is the possibility of reduction in entropy generation by matching the temperature glidings of refrigerant and heat-transfer fluid in both condenser and evaporator. Zeotropic mixtures are compared with pure re-frigerants to evaluate their exergetic losses. On the other hand, the special phenomena which result from temperature gliding are proved by experiments. A simple equation is obtained, to evaluate dif-ferent zeotropic mixtures' exergetic losses. The maximum flow rate of heat-transfer fluids is found in order that refrigerants phase change can be completed. Lastly, some examples of zeotropic mix-tures ( R407C, R405A and R414B) are given, and their exergetic losses and maximum flow rate of heat-transfer fluids in condenser are forecasted. 展开更多
关键词 zeotropic mixtures temperature gliding exergetic loss maximum flow rate
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A New Method for Analyzing Heat Exchangers- Matching of Temperature Field 被引量:2
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作者 WANG HuanGuang HUAI XiuLan 《Journal of Thermal Science》 SCIE EI CAS CSCD 2012年第5期452-458,共7页
In heat exchangers, the magnitude of Nu of each duct is influenced by the temperature field, since the ratio of heat capacity rate will influence the matching status of the temperature field between contacting ducts, ... In heat exchangers, the magnitude of Nu of each duct is influenced by the temperature field, since the ratio of heat capacity rate will influence the matching status of the temperature field between contacting ducts, the total heat transfer coefficient is related with the ratio of heat capacity rate. Considering this relationship, a new method for analyzing heat exchanger is proposed - matching of temperature field. First, for a single duct with the temperature field varying exponentially along the flow direction, its Nu is calculated. Then under the hypothesis that the thermal resistance of the wall is negligible, the matching condition was set like this: both the temperature and heat flux are equal for the hot and cold fluids at the wall, so the matching relationship of parameter that describes the temperature field of the hot and cold fluids, was obtained. Finally the relationship between the total Nu and the ratio of heat capacity rate along with the ratio of inherent thermal resistance is obtained. Compared with traditional analyzing methods, the temperature matching method can be used to get the total heat transfer coefficient directly, and also be used for optimization of heat exchanger design. For a parallel flow, the optimal ratio of heat capacity rate is reciprocal to the ratio of inherent thermal resistance, and for a counter flow, the optimal ratio of heat capacity rate is zero or infinity. 展开更多
关键词 matching method heat exchanger ratio of heat capacity rate ratio of inherent thermal resistance
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