Conversion of methanol(MeOH) to 2,2,3-trimethylbutane(triptane) over zinc iodide(ZnI_2)catalyst was investigated in a closed batch reactor.Optimum operating parameters were searched and catalyst deactivation and regen...Conversion of methanol(MeOH) to 2,2,3-trimethylbutane(triptane) over zinc iodide(ZnI_2)catalyst was investigated in a closed batch reactor.Optimum operating parameters were searched and catalyst deactivation and regeneration behaviors were discussed.The fresh,spent and regenerated catalysts were characterized by XRD,TG and XRF measurements to elucidate the related mechanism.The experimental results showed that the triptane yield reached up to 12.2% under the process conditions,including a reaction temperature of 200℃,an initial pressure of 0.35 MPa,a reaction time of 2 h,and a Me OH to ZnI_2 molar ratio of 2.The catalyst was gradually deactivated after several run cycles.A small amount of iodine was lost and a certain amount of ZnO was formed on the deactivated ZnI_2 catalyst.Deactivation of the catalyst could be attributed to the reduction of ZnI_2 amount,resulted from iodine loss and formation of Zn O.It was firstly pointed out from our work that the deactivated catalyst could be well regenerated by the hydrogen iodide(HI) and the tert-butanol compensation method,wherein the latter was added as an initiator into the reaction system.The activity recovery of the deactivated(spent) catalyst might be related to the reformation of ZnI_2 and acceleration of the initiation step of this reaction.展开更多
In this paper, asymmetric Gaussian weighting functions are introduced for the identification of linear parameter varying systems by utilizing an input-output multi-model structure. It is not required to select operati...In this paper, asymmetric Gaussian weighting functions are introduced for the identification of linear parameter varying systems by utilizing an input-output multi-model structure. It is not required to select operating points with uniform spacing and more flexibility is achieved. To verify the effectiveness of the proposed approach, several weighting functions, including linear, Gaussian and asymmetric Gaussian weighting functions, are evaluated and compared. It is demonstrated through simulations with a continuous stirred tank reactor model that the oroposed aonroach nrovides more satisfactory aonroximation.展开更多
Parabolic through concentrators and parabolic dish concentrators followed by a PVR （pressurized volumetric receiver） are proposed, studying the performance behavior of a RCBC （regenerative closed Brayton cycle） op...Parabolic through concentrators and parabolic dish concentrators followed by a PVR （pressurized volumetric receiver） are proposed, studying the performance behavior of a RCBC （regenerative closed Brayton cycle） operating with helium or hydrogen. A pressurized gas such as helium circulates along the volumetric receiver, capturing the concentrated thermal solar energy to be further converted into electric power via a thermal cycle. The overall efficiency of the plant has been computed under variable parameters to determine the operating conditions for which efficiency and specific power are acceptable. As consequence of the proposed analysis, it is concluded that direct coupling between volumetric receivers and thermal engines renders high efficiency while avoiding an intermediate heat transfer medium.展开更多
Separation density is one of the most concerned operating parameters in gravity beneficiation.Although equal-errors cut point or distribution density is usually used as practical separation density in gravity benefici...Separation density is one of the most concerned operating parameters in gravity beneficiation.Although equal-errors cut point or distribution density is usually used as practical separation density in gravity beneficiation, the gravity separating process complexly affected by many kinds of factors is actually carried out at a fluctuant density; namely, the practical separation density is essentially a random variable.The studied results show that the equal-errors cut point is the mathematical expectation of this random variable, and the distribution density corresponds to the highest separation efficiency in the gravity separation process.This shows that the distribution density is the best working point of the gravity separation equipment under a particular operating condition.Therefore,in order to fully develop the function of the gravity separation equipment, the distribution density should be close to the theoretical separation density unlimitedly in the range of minimum fluctuation.展开更多
文摘Conversion of methanol(MeOH) to 2,2,3-trimethylbutane(triptane) over zinc iodide(ZnI_2)catalyst was investigated in a closed batch reactor.Optimum operating parameters were searched and catalyst deactivation and regeneration behaviors were discussed.The fresh,spent and regenerated catalysts were characterized by XRD,TG and XRF measurements to elucidate the related mechanism.The experimental results showed that the triptane yield reached up to 12.2% under the process conditions,including a reaction temperature of 200℃,an initial pressure of 0.35 MPa,a reaction time of 2 h,and a Me OH to ZnI_2 molar ratio of 2.The catalyst was gradually deactivated after several run cycles.A small amount of iodine was lost and a certain amount of ZnO was formed on the deactivated ZnI_2 catalyst.Deactivation of the catalyst could be attributed to the reduction of ZnI_2 amount,resulted from iodine loss and formation of Zn O.It was firstly pointed out from our work that the deactivated catalyst could be well regenerated by the hydrogen iodide(HI) and the tert-butanol compensation method,wherein the latter was added as an initiator into the reaction system.The activity recovery of the deactivated(spent) catalyst might be related to the reformation of ZnI_2 and acceleration of the initiation step of this reaction.
基金Supported by the National Natural Science Foundation of China(21076179,61104008)National Basic Research Program of China(2012CB720500)
文摘In this paper, asymmetric Gaussian weighting functions are introduced for the identification of linear parameter varying systems by utilizing an input-output multi-model structure. It is not required to select operating points with uniform spacing and more flexibility is achieved. To verify the effectiveness of the proposed approach, several weighting functions, including linear, Gaussian and asymmetric Gaussian weighting functions, are evaluated and compared. It is demonstrated through simulations with a continuous stirred tank reactor model that the oroposed aonroach nrovides more satisfactory aonroximation.
文摘Parabolic through concentrators and parabolic dish concentrators followed by a PVR （pressurized volumetric receiver） are proposed, studying the performance behavior of a RCBC （regenerative closed Brayton cycle） operating with helium or hydrogen. A pressurized gas such as helium circulates along the volumetric receiver, capturing the concentrated thermal solar energy to be further converted into electric power via a thermal cycle. The overall efficiency of the plant has been computed under variable parameters to determine the operating conditions for which efficiency and specific power are acceptable. As consequence of the proposed analysis, it is concluded that direct coupling between volumetric receivers and thermal engines renders high efficiency while avoiding an intermediate heat transfer medium.
基金Supported by the Young Science Foundation of China(50025411)the Doctoral Science Research Foundation of University(20030290015)
文摘Separation density is one of the most concerned operating parameters in gravity beneficiation.Although equal-errors cut point or distribution density is usually used as practical separation density in gravity beneficiation, the gravity separating process complexly affected by many kinds of factors is actually carried out at a fluctuant density; namely, the practical separation density is essentially a random variable.The studied results show that the equal-errors cut point is the mathematical expectation of this random variable, and the distribution density corresponds to the highest separation efficiency in the gravity separation process.This shows that the distribution density is the best working point of the gravity separation equipment under a particular operating condition.Therefore,in order to fully develop the function of the gravity separation equipment, the distribution density should be close to the theoretical separation density unlimitedly in the range of minimum fluctuation.
