The hot deformation behavior of homogenized zinc alloy was investigated through uniaxial compression test on a Gleeble-1500 thermal-mechanical simulator within a temperature range of 230-380°C and a strain rate r...The hot deformation behavior of homogenized zinc alloy was investigated through uniaxial compression test on a Gleeble-1500 thermal-mechanical simulator within a temperature range of 230-380°C and a strain rate range of 0.01-10 s -1 ,the corresponding flow curves and their characters were determined and analyzed,and microstructures were studied by optical,SEM and TEM microscopy.The results indicated that the microstructure evolution of zinc alloy during hot deformation involves the spheroidization of the phase of TiZn15,coarsening of the precipitated phase and dynamic recrystallization(DRX)of the phase of matrix,leading to the formation of the polyphase(η+ε+TiZn15)structure.The spheroidization of the phase of TiZn15 during hot deformation was beneficial to the particle nucleation stimulated and then promoted to DRX of matrix.The dynamic recrystallization grain size of the matrix phase decreased firstly and then increased with elevating the temperature,and the degree of DRX became more complete when the strain rate and strain became larger.Hot deformation accelerated the diffusion of Cu atom,which resulted in the coarsening of the precipitated phase.Thus,the microstructure was refined owing to the pinning effect of the precipitated phase.展开更多
Microstructural development in hot working of TA15titanium alloy with primary stripαstructure was investigated withthe aim to globularizeαstrips.Results show that the mechanisms of morphology transformation are the ...Microstructural development in hot working of TA15titanium alloy with primary stripαstructure was investigated withthe aim to globularizeαstrips.Results show that the mechanisms of morphology transformation are the same to the spheroidizationmechanisms of lamellar structure.Boundary splitting and termination migration are more important than coarsening due to the largesize of stripα.Theαstrips are stable in annealing due to the unfavorable geometrical orientation of intra-αboundaries,the largethickness of strip and the geometrical stability ofαparticles.Predeformation and low speed deformation accelerate globularization ofαstrips in the following ways:direct changing of particle shape,promotion of boundary splitting and termination migration byincreasing high angle grain boundaries and interfacial area,promotion of coarsening by forming dislocation structures.Largepredeformation combined with high temperature annealing is a feasible way to globularize stripα.展开更多
The effect of heat treatment on the structure of Poly(p-phenylene benzobisoxazole) (PBO) fiber was studied by wide angle X-ray diffraction (WAXD) and differential scanning calorimetry-(DSC), which resuits in c...The effect of heat treatment on the structure of Poly(p-phenylene benzobisoxazole) (PBO) fiber was studied by wide angle X-ray diffraction (WAXD) and differential scanning calorimetry-(DSC), which resuits in confirmation of secondary crystallization in the heat treatment process. The effect of heat treatment on the structure and morphology of PBO fiber' s surface was investigated with X-ray photoelectron spectroscopic analysis (XPS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The results show that heat treatment not only has an effect on the composition of PBO fiber's surface, but also improves the microstmcture of PBO fiber, makes fiber more regular.展开更多
Microencapsulation of phase change materials(Micro PCMs) has been paid special attention because of their extensive applications in saving and releasing energy. Micro PCMs containing paraffin with a melting point of ...Microencapsulation of phase change materials(Micro PCMs) has been paid special attention because of their extensive applications in saving and releasing energy. Micro PCMs containing paraffin with a melting point of 55 ℃ in polystyrene-divinylbenzene(P(St-DVB)) were prepared by suspension-like polymerization. The characterization of microcapsules by FTIR, DSC and TG proved that paraffin had been successfully encapsulated and the proportion of encapsulated paraffin was 49.8%—58.5%. The effects of polyvinylpyrrolidone(PVP) with different molecular weights serving as the suspension stabilizer were investigated in detail. The results illustrated that the type of PVP had a significant influence on the particle size of Micro PCMs. The average diameter of Micro PCMs decreased with an increasing molecular weight of PVP. Moreover, the crosslinker-postaddition method was adopted in this study to improve the morphology of P(St-DVB) Micro PCMs. SEM images showed that when the DVB was added at the 2nd hour of polymerization the morphology of obtained P(St-DVB) Micro PCMs exhibited good sphericity since it could avoid the influence of cross-linker agent during the nucleation period.展开更多
The microstructural evolution of AA6061 and Mn-bearing Al-Mg-Si-Cu alloys was studied by compression tests that were carried out between 300 and 500 °C with a wide range of strain rates. Compared to the AA6061 al...The microstructural evolution of AA6061 and Mn-bearing Al-Mg-Si-Cu alloys was studied by compression tests that were carried out between 300 and 500 °C with a wide range of strain rates. Compared to the AA6061 alloy, the large amount of α-Al(MnFeCr)Si dispersoids in the Mn-bearing alloy yielded a significant increase in the flow stress under all deformation conditions. The effects of the deformation parameters on the evolution of the microstructure were studied using electronic backscatter diffraction measurements. The predominant softening mechanism of both alloys was dynamic recovery. The presence of α dispersoids in Mn-bearing alloys effectively refined the size of substructures with misorientation angles in the range of 2°-5°, which retarded the dynamic recovery. To predict the subgrain size under various deformation conditions, the threshold stresses that were caused by α dispersoids were calculated by the modified Orowan equation and incorporated into a conventional constitutive equation. The subgrain size that was predicted by the modified constitutive equation showed satisfactory agreement with the experimental measurements.展开更多
We introduce a kind of number-conserving coherent state in Rindler space which can describe the quantum state of thermal particles observed in Rindler space. This is based on the Unruh effect that the thermal particle...We introduce a kind of number-conserving coherent state in Rindler space which can describe the quantum state of thermal particles observed in Rindler space. This is based on the Unruh effect that the thermal particles seen by an accelerating observer in fiat space can be seen by an inertial observer in curved space under a conformal transformation.展开更多
Cell mechanics plays an important role in cellular physiological activities. Recent studies have shown that cellular mechanical properties are novel biomarkers for indicating the cell states. In this article, temperat...Cell mechanics plays an important role in cellular physiological activities. Recent studies have shown that cellular mechanical properties are novel biomarkers for indicating the cell states. In this article, temperature-controllable atomic force microscopy(AFM) was applied to quantitatively investigate the effects of temperature and cellular interactions on the mechanics and morphology of human cancer cells. First, AFM indenting experiments were performed on six types of human cells to investigate the changes of cellular Young's modulus at different temperatures and the results showed that the mechanical responses to the changes of temperature were variable for different types of cancer cells. Second, AFM imaging experiments were performed to observe the morphological changes in living cells at different temperatures and the results showed the significant changes of cell morphology caused by the alterations of temperature. Finally, by co-culturing human cancer cells with human immune cells, the mechanical and morphological changes in cancer cells were investigated. The results showed that the co-culture of cancer cells and immune cells could cause the distinct mechanical changes in cancer cells, but no significant morphological differences were observed. The experimental results improved our understanding of the effects of temperature and cellular interactions on the mechanics and morphology of cancer cells.展开更多
基金Project(2009BAE71B03)supported by the National Key Technology Support Program of China During the 11th Five-year Plan Period
文摘The hot deformation behavior of homogenized zinc alloy was investigated through uniaxial compression test on a Gleeble-1500 thermal-mechanical simulator within a temperature range of 230-380°C and a strain rate range of 0.01-10 s -1 ,the corresponding flow curves and their characters were determined and analyzed,and microstructures were studied by optical,SEM and TEM microscopy.The results indicated that the microstructure evolution of zinc alloy during hot deformation involves the spheroidization of the phase of TiZn15,coarsening of the precipitated phase and dynamic recrystallization(DRX)of the phase of matrix,leading to the formation of the polyphase(η+ε+TiZn15)structure.The spheroidization of the phase of TiZn15 during hot deformation was beneficial to the particle nucleation stimulated and then promoted to DRX of matrix.The dynamic recrystallization grain size of the matrix phase decreased firstly and then increased with elevating the temperature,and the degree of DRX became more complete when the strain rate and strain became larger.Hot deformation accelerated the diffusion of Cu atom,which resulted in the coarsening of the precipitated phase.Thus,the microstructure was refined owing to the pinning effect of the precipitated phase.
基金Projects(51205317,51575449) supported by the National Natural Science Foundation of ChinaProject(3102015AX004) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(104-QP-2014) supported by the Research Fund of the State Key Laboratory of Solidification Processing,China
文摘Microstructural development in hot working of TA15titanium alloy with primary stripαstructure was investigated withthe aim to globularizeαstrips.Results show that the mechanisms of morphology transformation are the same to the spheroidizationmechanisms of lamellar structure.Boundary splitting and termination migration are more important than coarsening due to the largesize of stripα.Theαstrips are stable in annealing due to the unfavorable geometrical orientation of intra-αboundaries,the largethickness of strip and the geometrical stability ofαparticles.Predeformation and low speed deformation accelerate globularization ofαstrips in the following ways:direct changing of particle shape,promotion of boundary splitting and termination migration byincreasing high angle grain boundaries and interfacial area,promotion of coarsening by forming dislocation structures.Largepredeformation combined with high temperature annealing is a feasible way to globularize stripα.
文摘The effect of heat treatment on the structure of Poly(p-phenylene benzobisoxazole) (PBO) fiber was studied by wide angle X-ray diffraction (WAXD) and differential scanning calorimetry-(DSC), which resuits in confirmation of secondary crystallization in the heat treatment process. The effect of heat treatment on the structure and morphology of PBO fiber' s surface was investigated with X-ray photoelectron spectroscopic analysis (XPS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The results show that heat treatment not only has an effect on the composition of PBO fiber's surface, but also improves the microstmcture of PBO fiber, makes fiber more regular.
基金financially supported by the National Natural Science Foundation of China (No. 20973022 and 11472048)the State Key Laboratory of Catalytic Materials and Reaction Engineering (RIPP, SINOPEC)
文摘Microencapsulation of phase change materials(Micro PCMs) has been paid special attention because of their extensive applications in saving and releasing energy. Micro PCMs containing paraffin with a melting point of 55 ℃ in polystyrene-divinylbenzene(P(St-DVB)) were prepared by suspension-like polymerization. The characterization of microcapsules by FTIR, DSC and TG proved that paraffin had been successfully encapsulated and the proportion of encapsulated paraffin was 49.8%—58.5%. The effects of polyvinylpyrrolidone(PVP) with different molecular weights serving as the suspension stabilizer were investigated in detail. The results illustrated that the type of PVP had a significant influence on the particle size of Micro PCMs. The average diameter of Micro PCMs decreased with an increasing molecular weight of PVP. Moreover, the crosslinker-postaddition method was adopted in this study to improve the morphology of P(St-DVB) Micro PCMs. SEM images showed that when the DVB was added at the 2nd hour of polymerization the morphology of obtained P(St-DVB) Micro PCMs exhibited good sphericity since it could avoid the influence of cross-linker agent during the nucleation period.
基金the financial supports from the National Natural Science Foundation of China (No. U1864209)Jincheng Science and Technology Plan Project of Shanxi Province, China (No. 201702014)。
文摘The microstructural evolution of AA6061 and Mn-bearing Al-Mg-Si-Cu alloys was studied by compression tests that were carried out between 300 and 500 °C with a wide range of strain rates. Compared to the AA6061 alloy, the large amount of α-Al(MnFeCr)Si dispersoids in the Mn-bearing alloy yielded a significant increase in the flow stress under all deformation conditions. The effects of the deformation parameters on the evolution of the microstructure were studied using electronic backscatter diffraction measurements. The predominant softening mechanism of both alloys was dynamic recovery. The presence of α dispersoids in Mn-bearing alloys effectively refined the size of substructures with misorientation angles in the range of 2°-5°, which retarded the dynamic recovery. To predict the subgrain size under various deformation conditions, the threshold stresses that were caused by α dispersoids were calculated by the modified Orowan equation and incorporated into a conventional constitutive equation. The subgrain size that was predicted by the modified constitutive equation showed satisfactory agreement with the experimental measurements.
基金Supported by the National Natural Science Foundation of China under Grant Nos.10775097 and 10874174by the Specialized Research Fund for the for the Doctorial Progress of Higher Education of China under Grant No.20070358009
文摘We introduce a kind of number-conserving coherent state in Rindler space which can describe the quantum state of thermal particles observed in Rindler space. This is based on the Unruh effect that the thermal particles seen by an accelerating observer in fiat space can be seen by an inertial observer in curved space under a conformal transformation.
基金supported by the National Natural Science Foundation of China(61175103,61375107,61327014,61433017)the Research Fund of the State Key Laboratory of Robotics(2014-Z07)CAS FEA International Partnership Program for Creative Research Teams
文摘Cell mechanics plays an important role in cellular physiological activities. Recent studies have shown that cellular mechanical properties are novel biomarkers for indicating the cell states. In this article, temperature-controllable atomic force microscopy(AFM) was applied to quantitatively investigate the effects of temperature and cellular interactions on the mechanics and morphology of human cancer cells. First, AFM indenting experiments were performed on six types of human cells to investigate the changes of cellular Young's modulus at different temperatures and the results showed that the mechanical responses to the changes of temperature were variable for different types of cancer cells. Second, AFM imaging experiments were performed to observe the morphological changes in living cells at different temperatures and the results showed the significant changes of cell morphology caused by the alterations of temperature. Finally, by co-culturing human cancer cells with human immune cells, the mechanical and morphological changes in cancer cells were investigated. The results showed that the co-culture of cancer cells and immune cells could cause the distinct mechanical changes in cancer cells, but no significant morphological differences were observed. The experimental results improved our understanding of the effects of temperature and cellular interactions on the mechanics and morphology of cancer cells.