Phase transitions, morphology changes, and oxidation mechanism of the ilmenite oxidation process were investigated. FeTi03 transforms to hematite and rutile when oxidation at 700-800 ℃, and pseudobrookite is formed w...Phase transitions, morphology changes, and oxidation mechanism of the ilmenite oxidation process were investigated. FeTi03 transforms to hematite and rutile when oxidation at 700-800 ℃, and pseudobrookite is formed when the oxidation temperature reaches 900 ℃. The initial ilmenite powder exhibits paramagnetism; however, after being oxidized at the intermediate temperature (800-850 ℃), the oxidation product exhibits weak ferromagnetism. The oxidation mechanism was discussed. The microstructure observations show that a lot of micro-pores emerge on the surfaces of ilmenite particles at the intermediate temperature, which is deemed to be caoable ofenhancin~ the mass transfer ofoxgen during oxidation.展开更多
Microstructure evolution and dislocation configurations in nanostructured Al–Mg alloys processed by high pressure torsion (HPT) were analyzed by transmission electron microscopy (TEM) and high-resolution TEM (HR...Microstructure evolution and dislocation configurations in nanostructured Al–Mg alloys processed by high pressure torsion (HPT) were analyzed by transmission electron microscopy (TEM) and high-resolution TEM (HRTEM). The results show that the grains less than 100 nm have sharp grain boundaries (GBs) and are completely free of dislocations. In contrast, a high density of dislocation as high as 1017 m^-2 exists within the grains larger than 200 nm and these larger grains are usually separated into subgrains and dislocation cells. The dislocations are 60° full dislocations with Burgers vectors of 1/2〈110〉and most of them appear as dipoles and loops. The microtwins and stacking faults (SFs) formed by the Shockley partials from the dissociation of both the 60° mixed dislocation and 0° screw dislocation in ultrafine grains were simultaneously observed by HRTEM in the HPT Al–Mg alloys. These results suggest that partial dislocation emissions, as well as the activation of partial dislocations could also become a deformation mechanism in ultrafine-grained aluminum during severe plastic deformation. The grain refinement mechanism associated with the very high local dislocation density, the dislocation cells and the non-equilibrium GBs, as well as the SFs and microtwins in the HPT Al-Mg alloys were proposed.展开更多
Laser assisted machining (LAM) has difficulties in estimating temperature after applying a LAM process due to its very small heat input area, large energy and movement. In particular, in the case of laser assisted t...Laser assisted machining (LAM) has difficulties in estimating temperature after applying a LAM process due to its very small heat input area, large energy and movement. In particular, in the case of laser assisted turning (LAT) process, it is more difficult to estimate the temperature after preheating because it has a shape of ellipse when a laser heat source is rotated. A prediction method and thermal analysis method for heat source shapes were proposed as a square shaped member was preheated. The temperature distribution was calculated according to the rotation of the member. Compared with the results of the former study, the maximum temperature of the calculation results, 1 407.1 ℃, is 8.5 ℃ higher than that of the square member, which is 1 398.6 ℃. In a LAT process for a square member, the maximum temperature is 1 850.8 ℃. It is recognized that a laser power control process is required because square members show a maximum temperature that exceeds a melting temperature at around a vertex of the member according to the rotation.展开更多
Using coarse-grained molecular dynamics simulations based on Gay-Berne potential model, we have simulated the cooling process of liquid n-butanol. A new set of GB parameters are obtained by fitting the results of dens...Using coarse-grained molecular dynamics simulations based on Gay-Berne potential model, we have simulated the cooling process of liquid n-butanol. A new set of GB parameters are obtained by fitting the results of density functional theory calculations. The simulations are carried out in the range of 290-50 K with temperature decrements of 10 K. The cooling characteristics are determined on the basis of the variations of the density, the potential energy and orientational order parameter with temperature, whose slopes all show discontinuity. Both the radial distribution function curves and the second-rank orientational correlation function curves exhibit splitting in the second peak. Using the discontinuous change of these thermodynamic and structure properties, we obtain the glass transition at an estimate of temperature Tg=1204.10 K, which is in good agreement with experimental results 1104-1 K.展开更多
Neutron-deficient Z ≈ N nuclei84,86Mo have been investigated using pairing-deformation self-consistent cranked shell modelcalculations up to spin I > 20 . Our calculations are in good agreement with the experiment...Neutron-deficient Z ≈ N nuclei84,86Mo have been investigated using pairing-deformation self-consistent cranked shell modelcalculations up to spin I > 20 . Our calculations are in good agreement with the experimental data, indicating γ-soft triaxial shapesat low rotational frequency and well-deformed triaxial-oblate shapes at high rotational frequency for both nuclei. The shape changeis due to the alignments of the g9/2protons and g9/2neutrons.展开更多
The theoretical light curves of contact binaries are calculated with and without putting in the contact binary evolution model.Firstly,we do not use the contact binary evolution model.A comparison of the light curve i...The theoretical light curves of contact binaries are calculated with and without putting in the contact binary evolution model.Firstly,we do not use the contact binary evolution model.A comparison of the light curve is performed with and without the deformation caused by rotation and tides.It shows that the light curve presents many differences,especially on the bottom and top.Secondly,we adopt the contact binary model [Huang R Q,et al.Chin J Astron Astrophys,2007,7:235-244;Song H F,et al.Chin J Astron Astrophys,2007,7:539-550] and compute the theoretical light curve with and without rotational and tidal effects by studying three binary systems(with low-,intermediate-and high-mass components).The bottom and top of the theoretical light curves are discussed and compared to observations.The results show that taking into account the rotational effect has a better agreement with observations than without it.Therefore,the deformation of the light curve of contact binaries caused by rotation and tides is very important.Meanwhile,the rotational and tidal effect can advance the start of the semi-detached,contact phase and the time of mass-reversal.展开更多
基金Project(51074105) supported by the National Natural Science Foundation of ChinaProject(51225401) supported by the China National Funds for Distinguished Young Scientists
文摘Phase transitions, morphology changes, and oxidation mechanism of the ilmenite oxidation process were investigated. FeTi03 transforms to hematite and rutile when oxidation at 700-800 ℃, and pseudobrookite is formed when the oxidation temperature reaches 900 ℃. The initial ilmenite powder exhibits paramagnetism; however, after being oxidized at the intermediate temperature (800-850 ℃), the oxidation product exhibits weak ferromagnetism. The oxidation mechanism was discussed. The microstructure observations show that a lot of micro-pores emerge on the surfaces of ilmenite particles at the intermediate temperature, which is deemed to be caoable ofenhancin~ the mass transfer ofoxgen during oxidation.
基金Project(BK2012715)supported by the Basic Research Program(Natural Science Foundation)of Jiangsu Province,ChinaProject(14KJA430002)supported by the Key University Science Research Project of Jiangsu Province,China+3 种基金Project(50971087)supported by the National Natural Science Foundation of China,ChinaProjects(11JDG070,11JDG140)supported by the Senior Talent Research Foundation of Jiangsu University,ChinaProject(hsm1301)supported by the Foundation of the Jiangsu Province Key Laboratory of High-end Structural Materials,ChinaProject(Kjsmcx2011004)supported by the Foundation of the Jiangsu Province Key Laboratory of Materials Tribology,China
文摘Microstructure evolution and dislocation configurations in nanostructured Al–Mg alloys processed by high pressure torsion (HPT) were analyzed by transmission electron microscopy (TEM) and high-resolution TEM (HRTEM). The results show that the grains less than 100 nm have sharp grain boundaries (GBs) and are completely free of dislocations. In contrast, a high density of dislocation as high as 1017 m^-2 exists within the grains larger than 200 nm and these larger grains are usually separated into subgrains and dislocation cells. The dislocations are 60° full dislocations with Burgers vectors of 1/2〈110〉and most of them appear as dipoles and loops. The microtwins and stacking faults (SFs) formed by the Shockley partials from the dissociation of both the 60° mixed dislocation and 0° screw dislocation in ultrafine grains were simultaneously observed by HRTEM in the HPT Al–Mg alloys. These results suggest that partial dislocation emissions, as well as the activation of partial dislocations could also become a deformation mechanism in ultrafine-grained aluminum during severe plastic deformation. The grain refinement mechanism associated with the very high local dislocation density, the dislocation cells and the non-equilibrium GBs, as well as the SFs and microtwins in the HPT Al-Mg alloys were proposed.
基金Project(70004782)supported by the Regional Strategic Technology Development Program of the Ministry of Knowledge Economy(MKE),KoreaProject(2011-0017407)supported by National Research Foundation(NRF)of KoreaWork financially supported by the Second Stage of Brain Korea 21 Projects
文摘Laser assisted machining (LAM) has difficulties in estimating temperature after applying a LAM process due to its very small heat input area, large energy and movement. In particular, in the case of laser assisted turning (LAT) process, it is more difficult to estimate the temperature after preheating because it has a shape of ellipse when a laser heat source is rotated. A prediction method and thermal analysis method for heat source shapes were proposed as a square shaped member was preheated. The temperature distribution was calculated according to the rotation of the member. Compared with the results of the former study, the maximum temperature of the calculation results, 1 407.1 ℃, is 8.5 ℃ higher than that of the square member, which is 1 398.6 ℃. In a LAT process for a square member, the maximum temperature is 1 850.8 ℃. It is recognized that a laser power control process is required because square members show a maximum temperature that exceeds a melting temperature at around a vertex of the member according to the rotation.
文摘Using coarse-grained molecular dynamics simulations based on Gay-Berne potential model, we have simulated the cooling process of liquid n-butanol. A new set of GB parameters are obtained by fitting the results of density functional theory calculations. The simulations are carried out in the range of 290-50 K with temperature decrements of 10 K. The cooling characteristics are determined on the basis of the variations of the density, the potential energy and orientational order parameter with temperature, whose slopes all show discontinuity. Both the radial distribution function curves and the second-rank orientational correlation function curves exhibit splitting in the second peak. Using the discontinuous change of these thermodynamic and structure properties, we obtain the glass transition at an estimate of temperature Tg=1204.10 K, which is in good agreement with experimental results 1104-1 K.
基金supported by the YKM Entrepreneurial Education Foundationthe National Natural Science Foundation of China (Grant Nos.10735010 and 10975006)the Chinese Major State Basic Research Development Program (Grant No. 2007CB815000)
文摘Neutron-deficient Z ≈ N nuclei84,86Mo have been investigated using pairing-deformation self-consistent cranked shell modelcalculations up to spin I > 20 . Our calculations are in good agreement with the experimental data, indicating γ-soft triaxial shapesat low rotational frequency and well-deformed triaxial-oblate shapes at high rotational frequency for both nuclei. The shape changeis due to the alignments of the g9/2protons and g9/2neutrons.
基金supported by the National Natural Science Foundation of China (Grant No.10933002)
文摘The theoretical light curves of contact binaries are calculated with and without putting in the contact binary evolution model.Firstly,we do not use the contact binary evolution model.A comparison of the light curve is performed with and without the deformation caused by rotation and tides.It shows that the light curve presents many differences,especially on the bottom and top.Secondly,we adopt the contact binary model [Huang R Q,et al.Chin J Astron Astrophys,2007,7:235-244;Song H F,et al.Chin J Astron Astrophys,2007,7:539-550] and compute the theoretical light curve with and without rotational and tidal effects by studying three binary systems(with low-,intermediate-and high-mass components).The bottom and top of the theoretical light curves are discussed and compared to observations.The results show that taking into account the rotational effect has a better agreement with observations than without it.Therefore,the deformation of the light curve of contact binaries caused by rotation and tides is very important.Meanwhile,the rotational and tidal effect can advance the start of the semi-detached,contact phase and the time of mass-reversal.