Conversion of methanol(MeOH) to 2,2,3-trimethylbutane(triptane) over zinc iodide(ZnI_2)catalyst was investigated in a closed batch reactor.Optimum operating parameters were searched and catalyst deactivation and regen...Conversion of methanol(MeOH) to 2,2,3-trimethylbutane(triptane) over zinc iodide(ZnI_2)catalyst was investigated in a closed batch reactor.Optimum operating parameters were searched and catalyst deactivation and regeneration behaviors were discussed.The fresh,spent and regenerated catalysts were characterized by XRD,TG and XRF measurements to elucidate the related mechanism.The experimental results showed that the triptane yield reached up to 12.2% under the process conditions,including a reaction temperature of 200℃,an initial pressure of 0.35 MPa,a reaction time of 2 h,and a Me OH to ZnI_2 molar ratio of 2.The catalyst was gradually deactivated after several run cycles.A small amount of iodine was lost and a certain amount of ZnO was formed on the deactivated ZnI_2 catalyst.Deactivation of the catalyst could be attributed to the reduction of ZnI_2 amount,resulted from iodine loss and formation of Zn O.It was firstly pointed out from our work that the deactivated catalyst could be well regenerated by the hydrogen iodide(HI) and the tert-butanol compensation method,wherein the latter was added as an initiator into the reaction system.The activity recovery of the deactivated(spent) catalyst might be related to the reformation of ZnI_2 and acceleration of the initiation step of this reaction.展开更多
An accurate one-dimensional, heterogeneous model taking account of axial dispersion and heat transfer to the reactor wall, and heat conduction through the reactor wall for methanol synthesis in a bench scale reactor u...An accurate one-dimensional, heterogeneous model taking account of axial dispersion and heat transfer to the reactor wall, and heat conduction through the reactor wall for methanol synthesis in a bench scale reactor under periodic reversal of flow direction is presented. Adjustable parameters in this model are the effectiveness factors for each of the three reactions occurring in the synthesis and a factor for the bed to wall heat transfer coefficient correlation. Experimental data were used to evaluate these parameters and reasonable values of these parameters were obtained. The model was found to closely predict the reactor performance under a wide range of operating conditions, such as carbon oxide concentrations, volumetric flow rate, and cyclic period.展开更多
A new digital transmitter based on delta sigma modulator( DSM) with bus-splitting is presented in this paper. The second order low pass error-feedback delta sigma modulator( EF-DSM) is focused. The signal to noise rat...A new digital transmitter based on delta sigma modulator( DSM) with bus-splitting is presented in this paper. The second order low pass error-feedback delta sigma modulator( EF-DSM) is focused. The signal to noise ratio( SNR) of the EF-DSM is derived for different bus-splitting bits.Following the EF-DSM,a multi-bit digital up mixer is used for carrier frequency transform. In order to validate the theory of bus-splitting,two types of transmitters are implemented on FPGA for comparison,in which one is with non-bus-splitting and the other is with bus-splitting. The FPGA implemented transmitter with bus-splitting promotes the maximum operation speed by 39%,and reduces hardware consumptions more than 16%. Both single tone and orthogonal frequency division multiplexing( OFDM) signal source are used to evaluate the proposed transmitter.展开更多
文摘Conversion of methanol(MeOH) to 2,2,3-trimethylbutane(triptane) over zinc iodide(ZnI_2)catalyst was investigated in a closed batch reactor.Optimum operating parameters were searched and catalyst deactivation and regeneration behaviors were discussed.The fresh,spent and regenerated catalysts were characterized by XRD,TG and XRF measurements to elucidate the related mechanism.The experimental results showed that the triptane yield reached up to 12.2% under the process conditions,including a reaction temperature of 200℃,an initial pressure of 0.35 MPa,a reaction time of 2 h,and a Me OH to ZnI_2 molar ratio of 2.The catalyst was gradually deactivated after several run cycles.A small amount of iodine was lost and a certain amount of ZnO was formed on the deactivated ZnI_2 catalyst.Deactivation of the catalyst could be attributed to the reduction of ZnI_2 amount,resulted from iodine loss and formation of Zn O.It was firstly pointed out from our work that the deactivated catalyst could be well regenerated by the hydrogen iodide(HI) and the tert-butanol compensation method,wherein the latter was added as an initiator into the reaction system.The activity recovery of the deactivated(spent) catalyst might be related to the reformation of ZnI_2 and acceleration of the initiation step of this reaction.
基金The authors are grateful for financial support from the National Natural Science Foundation of China (No. 29476223) and the Ministry of Chemical Industry of China (No. 95-23-01).
文摘An accurate one-dimensional, heterogeneous model taking account of axial dispersion and heat transfer to the reactor wall, and heat conduction through the reactor wall for methanol synthesis in a bench scale reactor under periodic reversal of flow direction is presented. Adjustable parameters in this model are the effectiveness factors for each of the three reactions occurring in the synthesis and a factor for the bed to wall heat transfer coefficient correlation. Experimental data were used to evaluate these parameters and reasonable values of these parameters were obtained. The model was found to closely predict the reactor performance under a wide range of operating conditions, such as carbon oxide concentrations, volumetric flow rate, and cyclic period.
基金Supported by the National Natural Science Foundation of China(No.61674037)National Key Research and Development Program of China(No.2016YFC0800400)+1 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe National Power Grid Corp Science and Technology Project(No.SGTYHT/16-JS-198)
文摘A new digital transmitter based on delta sigma modulator( DSM) with bus-splitting is presented in this paper. The second order low pass error-feedback delta sigma modulator( EF-DSM) is focused. The signal to noise ratio( SNR) of the EF-DSM is derived for different bus-splitting bits.Following the EF-DSM,a multi-bit digital up mixer is used for carrier frequency transform. In order to validate the theory of bus-splitting,two types of transmitters are implemented on FPGA for comparison,in which one is with non-bus-splitting and the other is with bus-splitting. The FPGA implemented transmitter with bus-splitting promotes the maximum operation speed by 39%,and reduces hardware consumptions more than 16%. Both single tone and orthogonal frequency division multiplexing( OFDM) signal source are used to evaluate the proposed transmitter.
