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含硼分子筛的^(11)B VAS NMR和~1H MAS NMR研究
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作者 陈铁红 孙平川 +2 位作者 邓风 王敬中 丁大同 《波谱学杂志》 CAS CSCD 北大核心 2000年第2期109-113,共5页
以变角旋转 (VAS)NMR方法考察了三配位硼的存在状态 ,得到其四极作用常数Cq为 2 .4MHz,电场梯度不对称系数 η为 0 .0 .硼引入骨架形成的酸性羟基质子的信号位于2 .3ppm ,1 H{1 1 B}双共振实验证实其与硼原子的关联很弱 .与 6.5ppm分子... 以变角旋转 (VAS)NMR方法考察了三配位硼的存在状态 ,得到其四极作用常数Cq为 2 .4MHz,电场梯度不对称系数 η为 0 .0 .硼引入骨架形成的酸性羟基质子的信号位于2 .3ppm ,1 H{1 1 B}双共振实验证实其与硼原子的关联很弱 .与 6.5ppm分子筛吸水峰同时出现的2 .7ppm的信号也被认为是吸水的信号 ,与非骨架铝羟基质子的信号在同一位置 ,但可通过1 H{2 7Al}双共振实验加以判别 . 展开更多
关键词 变角旋转 含硼分子筛 NMR 硼硅羟基 双共振
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A novel algorithm for a rotation invariant template matching 被引量:1
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作者 LEI Ming ZHANG Guang-jun 《Optoelectronics Letters》 EI 2008年第5期379-383,共5页
A novel algorithm for a rotation invariant template matching is proposed when the fluctuating scope of the rotation angle is limited within the region of [-20°,20°]. The matching candidates are selected usin... A novel algorithm for a rotation invariant template matching is proposed when the fluctuating scope of the rotation angle is limited within the region of [-20°,20°]. The matching candidates are selected using a computationally low cost improved correlation algorithm. "AND" operation is adopted to reduce the computational cost. Therefore the algorithm improves the matching speed consumedly. The simulation results verify the efficiency of the proposed method. Moreover,when the size of reference image is fixed,the advantage of this time-saving algorithm is more obvious as the increase of the size of the real time image. The matching speed of the proposed method is over 20 times faster than the speed of the two-level pyramid decomposing accelerating method. 展开更多
关键词 运算法则 旋转 模板匹配
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Entropy evolution of field with a time-varying frequency in the Jaynes-Cummings model
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作者 Qiu Changdong 《Engineering Sciences》 EI 2012年第2期78-83,共6页
Following Jaynes-Cummings model,the evolution of the field entropy in the system of a two-level atom interacting with the single mode coherent field is investigated under rotating-wave approximation.The typical case &... Following Jaynes-Cummings model,the evolution of the field entropy in the system of a two-level atom interacting with the single mode coherent field is investigated under rotating-wave approximation.The typical case "the field frequency variance with time in the form of sine ω=ω0+usin(wt) has been considered.The influences of the amplitude and angle frequency of the field frequency variance on entropy evolution of the field are discussed by numerical calculations.Calculation results indicate that the field frequency variance influences violently the behavior of field entropy evolution;the larger the amplitude of the field frequency variance is,the stronger the influence of the field frequency variance on the time evolution of field entropy is. 展开更多
关键词 two-level atom Jaynes-Cummings model frequency of field varying with time the evolution of the field entropy
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Spatial distribution, seasonal variation and regionalization of PM_(2.5) concentrations in China 被引量:14
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作者 Shuai Wang Guogang Li +5 位作者 Zhengyu Gong Li Du Qingtao Zhou Xiaoyan Meng Shuyan Xie Lei Zhou 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第9期1435-1443,共9页
In order to provide scientific support to policy makers in the regulation of PM2.5 pollution in China, it is important to accurately assess the current status, spatiotemporal characteristics and regionalization data f... In order to provide scientific support to policy makers in the regulation of PM2.5 pollution in China, it is important to accurately assess the current status, spatiotemporal characteristics and regionalization data for this air pollutant. An analysis of the pollution status of PM2.5 was conducted using daily averaged mass concentration data recorded in 74 cities in 2013 and 161 cities in 2014. The rotated empirical orthogonal function(REOF) method was applied to analyze this data. Results showed that the average annual PM2.5 concentration in urban areas of China is 62.2±21.5 ?g/m3, and that the distribution is spatially heterogeneous. The North China Plain, middle and lower Yangtze River Plain, Sichuan Basin and Guanzhong Plain had relatively high annual PM2.5 concentrations compared with the southeast coastal region, the Tibetan Plateau and the Yungui Plateau. PM2.5 mass concentrations tended to be higher in winter than in summer, however, the data for many cities showed a small peak in concentrations from May to July. An analysis of the spatial correlation of PM2.5 indicated a significant influence of topographic conditions. A lower correlation was observed where terrain features varied greatly. Based on the results of the REOF analysis and topographic characteristics, ten regions were identified in mid-eastern China, which could be considered as basic pollution prevention divisions for PM2.5; these include the North China Plain region, Pearl River Delta region, Jianghuai Plain region, middle Yangtze River Plain region, Northeast Plain region, Jiangnan coastal region, Sichuan Basin region, Qiantao Plain region, Guanzhong-Central Plain region and Yungui Plateau region. Seasonal variations in the regionalization data were observed, especially for the North China Plain and Pearl River Delta regions. Among the ten regions identified in this study, the North China Plain, Guanzhong-Central Plain, middle Yangtze River Plain and Jianghuai Plain had relatively high PM2.5 mass concentrations in comparison with the others. Therefore, these regions should be considered as the key regions to target in developing PM2.5 pollution prevention strategies. This study improves the present understanding of the spatial distribution, seasonal changes and regional status of PM2.5 pollution in China and helps establish possible control strategies for the reduction of this air pollutant. 展开更多
关键词 PM2.5 spatiotemporal variability REOF spatial regionalization
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