The theoretical formulations of Coulomb and Rankine still remain as the fundamental approaches to the analysis of most gravity-type retaining wall,with the assumption that sufficient lateral yield will occur to mobili...The theoretical formulations of Coulomb and Rankine still remain as the fundamental approaches to the analysis of most gravity-type retaining wall,with the assumption that sufficient lateral yield will occur to mobilize fully limited conditions behind the wall.The effects of the magnitude of wall movements and different wall-movement modes are not taken into consideration.The disturbance of backfill is considered to be related to the wall movement under translation mode.On the basis of disturbed state concept(DSC),a general disturbance function was proposed which ranged from-1 to 1.The disturbance variables could be determined from the measured wall movements.A novel approach that related to disturbed degree and the mobilized internal frictional angle of the backfill was also derived.A calculation method benefited from Rankine's theory and the proposed approach was established to predict the magnitude and distribution of earth pressure from the cohesionless backfill under translation mode.The predicted results,including the magnitude and distribution of earth pressure,show good agreement with those of the model test and the finite element method.In addition,the disturbance parameter b was also discussed.展开更多
The mineralogy and trace element contents in coals from the West Bokaro coalfield, which is the one of the biggest Gondwana coalfields of India, were studied to delineate enrichment of trace elements and their modes o...The mineralogy and trace element contents in coals from the West Bokaro coalfield, which is the one of the biggest Gondwana coalfields of India, were studied to delineate enrichment of trace elements and their modes of occur- rence. Elemental concentrations with reference to their crustal abundances indicated that coals are relatively enriched in As （4.4-15.5 mg/kg）, Cd （0.3-3.0 mg/kg）, Cu （28.0-68.1 mg/kg） and V （46.6-178.0 mg/kg）; depleted in Co （10.8-28.4 mg/ kg）, Mn （7.6-483.4 mg/kg）, Ni （13.0-31.6 mg/kg）, Cr （14.2-85.5 mg/kg） and Zn （5.25-70.4 mg/kg）. The concentration of As, Cd, Co, Cu and V were higher than the average values of world and Indian coals. Mineralogical study carried out by X-ray diffraction shows that quartz and kaolinite occur as dominant mineral phases in this coal. Fourier transform infrared spectroscopy pattern suggests organic structures primarily containing aromatic nuclei, aliphatic side chain and some oxygen containing groups. The modes of occurrence of trace elements present in these coals have been determined through statistical approach. Both Cu and Cr are more closely associated with mineral matter, whereas Co is dominantly present with its organic form. The concentrations of Cd, Mn, Ni, Zn, As and V have apparently occur in both organic and inorganic constituents. This study would be helpful to assess the potential environmental impacts during mining and combustion of this coal.展开更多
In the deep Earth, hydrogen mainly occurs as structural hydroxyl and molecular water in minerals and melts, constituting mobile and immobile aqueous components. Hydrous minerals contain hydrogen which occupies a speci...In the deep Earth, hydrogen mainly occurs as structural hydroxyl and molecular water in minerals and melts, constituting mobile and immobile aqueous components. Hydrous minerals contain hydrogen which occupies a specific structural position and constitutes an indispensable component of chemical formulae. On the other hand, nominally anhydrous minerals do not contain hydrogen in their chemical formulae, but can host trace amounts of water in structural position and lattice defect. The molecular water may occur in the lattice defect as fluid/melt inclusions in minerals. Even though the water content of nominally anhydrous minerals is very limited generally in the order of ppm(parts per million), they may play a significant role in influencing the physicochemical properties of mineral and rock systems. With the continuous improvement of modern instrumentations, the analytical methodology exhibits trends for higher spatial resolution, lower detection limit and integral multiple methods on the water amount and its isotopic ratio. Among these methods, Fourier transform infrared spectrometry remains the most widely used, while secondary ion mass spectrometry, continuous flow mass spectrometry, elastic recoil detection analysis and Raman spectrometry are promising. This paper provides a brief review on the methodological progress and their applications to the analysis of structural water in nominally anhydrous minerals.展开更多
基金Project(50678158) supported by the National Natural Science Foundation of China
文摘The theoretical formulations of Coulomb and Rankine still remain as the fundamental approaches to the analysis of most gravity-type retaining wall,with the assumption that sufficient lateral yield will occur to mobilize fully limited conditions behind the wall.The effects of the magnitude of wall movements and different wall-movement modes are not taken into consideration.The disturbance of backfill is considered to be related to the wall movement under translation mode.On the basis of disturbed state concept(DSC),a general disturbance function was proposed which ranged from-1 to 1.The disturbance variables could be determined from the measured wall movements.A novel approach that related to disturbed degree and the mobilized internal frictional angle of the backfill was also derived.A calculation method benefited from Rankine's theory and the proposed approach was established to predict the magnitude and distribution of earth pressure from the cohesionless backfill under translation mode.The predicted results,including the magnitude and distribution of earth pressure,show good agreement with those of the model test and the finite element method.In addition,the disturbance parameter b was also discussed.
文摘The mineralogy and trace element contents in coals from the West Bokaro coalfield, which is the one of the biggest Gondwana coalfields of India, were studied to delineate enrichment of trace elements and their modes of occur- rence. Elemental concentrations with reference to their crustal abundances indicated that coals are relatively enriched in As （4.4-15.5 mg/kg）, Cd （0.3-3.0 mg/kg）, Cu （28.0-68.1 mg/kg） and V （46.6-178.0 mg/kg）; depleted in Co （10.8-28.4 mg/ kg）, Mn （7.6-483.4 mg/kg）, Ni （13.0-31.6 mg/kg）, Cr （14.2-85.5 mg/kg） and Zn （5.25-70.4 mg/kg）. The concentration of As, Cd, Co, Cu and V were higher than the average values of world and Indian coals. Mineralogical study carried out by X-ray diffraction shows that quartz and kaolinite occur as dominant mineral phases in this coal. Fourier transform infrared spectroscopy pattern suggests organic structures primarily containing aromatic nuclei, aliphatic side chain and some oxygen containing groups. The modes of occurrence of trace elements present in these coals have been determined through statistical approach. Both Cu and Cr are more closely associated with mineral matter, whereas Co is dominantly present with its organic form. The concentrations of Cd, Mn, Ni, Zn, As and V have apparently occur in both organic and inorganic constituents. This study would be helpful to assess the potential environmental impacts during mining and combustion of this coal.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41373010 & 41590624)
文摘In the deep Earth, hydrogen mainly occurs as structural hydroxyl and molecular water in minerals and melts, constituting mobile and immobile aqueous components. Hydrous minerals contain hydrogen which occupies a specific structural position and constitutes an indispensable component of chemical formulae. On the other hand, nominally anhydrous minerals do not contain hydrogen in their chemical formulae, but can host trace amounts of water in structural position and lattice defect. The molecular water may occur in the lattice defect as fluid/melt inclusions in minerals. Even though the water content of nominally anhydrous minerals is very limited generally in the order of ppm(parts per million), they may play a significant role in influencing the physicochemical properties of mineral and rock systems. With the continuous improvement of modern instrumentations, the analytical methodology exhibits trends for higher spatial resolution, lower detection limit and integral multiple methods on the water amount and its isotopic ratio. Among these methods, Fourier transform infrared spectrometry remains the most widely used, while secondary ion mass spectrometry, continuous flow mass spectrometry, elastic recoil detection analysis and Raman spectrometry are promising. This paper provides a brief review on the methodological progress and their applications to the analysis of structural water in nominally anhydrous minerals.
