Synthetic macrocyclic host molecules always play an essential role in the establishment and development of supramolecular chemistry. Along with the continuous interests in the study of classical macrocycles, recent de...Synthetic macrocyclic host molecules always play an essential role in the establishment and development of supramolecular chemistry. Along with the continuous interests in the study of classical macrocycles, recent decades have witnessed the emergence and rapid development of the chemistry and supramolecular chemistry of novel and functional macrocycles. Owing to their easy availability, a self-tunable V-shaped cavity resulted from 1,3-alternate conformation, and diversified electronic features steered by the interplay between heteroatom linkages and aromatic rings, heteracalixaromatics act as a type of versatile and powerful macrocyclic hosts in molecular recognition and fabrication of supramolecular systems. Very recently, by means of engineering the bond connectivity or the recombination of chemical bonds within heteracalixaromatics, we have devised coronarenes, a new generation of macrocycles. In this concise review, macrocyclic and supramolecular chemistry of coronarenes are summarized in the order of their syntheses, structural features, molecular recognition and self-assembly properties. In the last part of this article, personal perspectives on the study of macrocyclic and supramolecular chemistry will also be discussed.展开更多
This paper presents an empirical study of the acquisition of English ambiguous verb-locative prepositional phrase constructions （VLPPs） by adult Mandarin and Spanish speakers. This study assumes that the semantic pr...This paper presents an empirical study of the acquisition of English ambiguous verb-locative prepositional phrase constructions （VLPPs） by adult Mandarin and Spanish speakers. This study assumes that the semantic properties of the target VLPPs that relate to change-of-location in sentences such as The boat floated under the bridge arise from an uninterpretable syntactic feature selected by English but unselected by Mandarin Chinese and Spanish. Results obtained from an animated cartoon selection task indicate that neither the Mandarin nor the Spanish speakers at any level of English proficiency possess native-like interpretative knowledge. Tense/ Aspect effects on the interpretation of the target constructions by Spanish speakers were also found. These results are interpreted as consistent with the Representational Deficit Hypothesis view （Hawkins, 2003, 2005） of adult second language acquisition.展开更多
基金supported by the National Natural Science Foundation of China (21732004, 21421064, 91427301, 21132005)Tsinghua University
文摘Synthetic macrocyclic host molecules always play an essential role in the establishment and development of supramolecular chemistry. Along with the continuous interests in the study of classical macrocycles, recent decades have witnessed the emergence and rapid development of the chemistry and supramolecular chemistry of novel and functional macrocycles. Owing to their easy availability, a self-tunable V-shaped cavity resulted from 1,3-alternate conformation, and diversified electronic features steered by the interplay between heteroatom linkages and aromatic rings, heteracalixaromatics act as a type of versatile and powerful macrocyclic hosts in molecular recognition and fabrication of supramolecular systems. Very recently, by means of engineering the bond connectivity or the recombination of chemical bonds within heteracalixaromatics, we have devised coronarenes, a new generation of macrocycles. In this concise review, macrocyclic and supramolecular chemistry of coronarenes are summarized in the order of their syntheses, structural features, molecular recognition and self-assembly properties. In the last part of this article, personal perspectives on the study of macrocyclic and supramolecular chemistry will also be discussed.
文摘This paper presents an empirical study of the acquisition of English ambiguous verb-locative prepositional phrase constructions （VLPPs） by adult Mandarin and Spanish speakers. This study assumes that the semantic properties of the target VLPPs that relate to change-of-location in sentences such as The boat floated under the bridge arise from an uninterpretable syntactic feature selected by English but unselected by Mandarin Chinese and Spanish. Results obtained from an animated cartoon selection task indicate that neither the Mandarin nor the Spanish speakers at any level of English proficiency possess native-like interpretative knowledge. Tense/ Aspect effects on the interpretation of the target constructions by Spanish speakers were also found. These results are interpreted as consistent with the Representational Deficit Hypothesis view （Hawkins, 2003, 2005） of adult second language acquisition.
