Using carbon tetrachloride (CCl4) as extraction agent, the activated sludge from Tianjin Jizhuangzi Sewage Treatment Plant as inoculum, the test study on biodegradability of lubricants was carried out. The test flas...Using carbon tetrachloride (CCl4) as extraction agent, the activated sludge from Tianjin Jizhuangzi Sewage Treatment Plant as inoculum, the test study on biodegradability of lubricants was carried out. The test flasks containing the mineral medium, the test oil and the inoculum were placed in incubation together with flasks containing poisoned blanks for periods of 0 and 21 days, respectively. Flasks containing the reference materials in place of the test oil were run in parallel. At the end of the incubation period, the contents of the flasks were subjected to sonic vibration, and were acidified and extracted by using CCI4. The extracts were then analysed by infra-red (IR) spectrometer to measure the maximum absorption of the C-H stretch of CH2-CH3 band at wavelength of 2 930 cm^-1. The absorption values were used to calculate the residual oil contents of the poisoned and test flasks. Consequently the biodegradability of the test oil was calculated. The test results indicate that the differences in the biodegradability of test materials in different tests are within 5.5%, and consistent with the data described in Coordinating European Council (CEC) L-33- A-93. The biodegradability of lubricants can be evaluated by this method effectively.展开更多
In recent decades, a growing worldwide trend of developing the biodegradable lubricants has been prevailing to form a specific field of green chemistry and green engineering. Enhancement of biodegradability of unreadi...In recent decades, a growing worldwide trend of developing the biodegradable lubricants has been prevailing to form a specific field of green chemistry and green engineering. Enhancement of biodegradability of unreadily biodegradable petroleum-based lubricants has as such become an urgent must. For over a decade the authors have been focusing on the improvement of biodegradability of unreadily biodegradable lubricants such as petroleum-based lubricating oils and greases. A new idea of lubricant biodegradation enhancer was put forward by the authors with the aim to stimulate the biodegradation of unreadily biodegradable lubricants by incorporating the enhancer into the lubricants in order to turn the lubricants into greener biodegradable ones and to help in situ bioremediation of lubricant-contaminated environment. This manuscript summarizes our recent efforts relating to the chemistry and technology of biodegradation enhancers for lubricants. Firstly, the chemistry of lubricant biodegradation enhancers was designed based on the principles of bioremediation for the treatment of hydrocarbon contaminated environment. Secondly, the ability of the designed biodegradation enhancers for increasing the biodegradability of unreadily biodegradable industrial lubricants was investigated through biodegradability evaluation tests, microbial population analysis, and biodegradation kinetics modeling. Finally, the impact of biodegradation enhancers on some crucial performance characteristics of lubricants such as lubricity and oxidation stability was tested via tribological evaluation and oxidation determinations. Our results have shown that the designed chemistry of nitrogenous and/or phosphorous compounds such as lauroyl glutamine, oleoyl glycine, oleic diethanolamide phosphate and lauric diethanolamide borate was outstanding in boosting biodegradation of petroleum-based lubricants which was ascribed to increase the microbial population and decrease the oil-water interfacial tension during the biodegradation process. Lubricants doped with the biodegradation enhancers exhibited much better biodegradability and higher biodegradation rate in the surrounding soils which could be well modeled by the exponential biodegradation kinetics. Furthermore, as lubricant dopants, the biodegradation enhancers also provided excellent capability in reducing friction and wear and in retarding oxidation of lubricants. In the nature of things, lubricant biodegradation enhancers, which are multi-functional not only in the improvement of biodegradability, but also in the fortification of lubricity and in the inhibition of oxidation of lubricants, are expected to be promising as a new category of lubricant additives.展开更多
The modification of Shenfu coals by a microwave treatment carried out under a hydrogen or a methane atmosphere, and the subsequent maceral separation by flotation, are described in this paper. The surface contact angl...The modification of Shenfu coals by a microwave treatment carried out under a hydrogen or a methane atmosphere, and the subsequent maceral separation by flotation, are described in this paper. The surface contact angle and the Zeta potential of the coal macerals were measured both with and without the treat- ment. The results show that the surface wettability of SFF (Shenfu Fusain) and SFV (Shenfu Vitrain) can be changed by the microwave treatment. An increase in the difference in surface wettability of SFF and SFV causes in a subsequent increase in the enrichment of inertinite and vitrinite. The results of the Zeta potential measurements show that the surface potentials of SFF and SFV are also changed by the treatment.展开更多
Pit limit design has,up to date,focused mainly on maximization of economic profit alone,with environmental and social issues largely ignored.This paper focuses on incorporating both environmental and social issues in ...Pit limit design has,up to date,focused mainly on maximization of economic profit alone,with environmental and social issues largely ignored.This paper focuses on incorporating both environmental and social issues in the pit limit design process and provides an approach to pit limit optimization that is in compliance with sustainable development.The case study demonstrates that ecological costs have a substantial down-sizing effect and social benefits have a substantial up-sizing effect on the optimal pit limit.When the ecological costs are factored in,the optimal pit limit is 37.5%smaller than the economically optimal pit limit.However,when the social benefits are factored in,the optimal pit limit is 48.3%larger than the economically optimal one.The overall optimal pit limit,with the economic profit,ecological costs and social benefits simultaneously considered,is a result of balancing conflicting goals of maximizing economic profit,minimizing ecological cost,and maximizing social benefit.展开更多
It is wen-known that patented technology licensing is closely related to technology standards, and whether a technology standard contains a specific patented technology solution or not, there is always a patented tech...It is wen-known that patented technology licensing is closely related to technology standards, and whether a technology standard contains a specific patented technology solution or not, there is always a patented technology hcensing imphed, for patented technology hcensing is a prerequisite for the existence and development of technology standards. Therefore, technology standards create a good many potential chances for hcensing patented technologies concerning them. Superficially speaking, patent holders achieve huge profits mainly by means of hcensing patented technologies through a standard mainly in the form of a patent pool; however, in fact, it is know-how licensing behind the patented technology involved in the standard that really helps patent holders make huge profits.展开更多
基金China Petroleum & Chemical Corporation (No. 104141)
文摘Using carbon tetrachloride (CCl4) as extraction agent, the activated sludge from Tianjin Jizhuangzi Sewage Treatment Plant as inoculum, the test study on biodegradability of lubricants was carried out. The test flasks containing the mineral medium, the test oil and the inoculum were placed in incubation together with flasks containing poisoned blanks for periods of 0 and 21 days, respectively. Flasks containing the reference materials in place of the test oil were run in parallel. At the end of the incubation period, the contents of the flasks were subjected to sonic vibration, and were acidified and extracted by using CCI4. The extracts were then analysed by infra-red (IR) spectrometer to measure the maximum absorption of the C-H stretch of CH2-CH3 band at wavelength of 2 930 cm^-1. The absorption values were used to calculate the residual oil contents of the poisoned and test flasks. Consequently the biodegradability of the test oil was calculated. The test results indicate that the differences in the biodegradability of test materials in different tests are within 5.5%, and consistent with the data described in Coordinating European Council (CEC) L-33- A-93. The biodegradability of lubricants can be evaluated by this method effectively.
基金the financial support provided by the National Natural Science Foundation of China (project Nos.50975282 and 50275147)the Natural Science Foundation of Chongqing, China (project No. CSTC 2008BA4037)
文摘In recent decades, a growing worldwide trend of developing the biodegradable lubricants has been prevailing to form a specific field of green chemistry and green engineering. Enhancement of biodegradability of unreadily biodegradable petroleum-based lubricants has as such become an urgent must. For over a decade the authors have been focusing on the improvement of biodegradability of unreadily biodegradable lubricants such as petroleum-based lubricating oils and greases. A new idea of lubricant biodegradation enhancer was put forward by the authors with the aim to stimulate the biodegradation of unreadily biodegradable lubricants by incorporating the enhancer into the lubricants in order to turn the lubricants into greener biodegradable ones and to help in situ bioremediation of lubricant-contaminated environment. This manuscript summarizes our recent efforts relating to the chemistry and technology of biodegradation enhancers for lubricants. Firstly, the chemistry of lubricant biodegradation enhancers was designed based on the principles of bioremediation for the treatment of hydrocarbon contaminated environment. Secondly, the ability of the designed biodegradation enhancers for increasing the biodegradability of unreadily biodegradable industrial lubricants was investigated through biodegradability evaluation tests, microbial population analysis, and biodegradation kinetics modeling. Finally, the impact of biodegradation enhancers on some crucial performance characteristics of lubricants such as lubricity and oxidation stability was tested via tribological evaluation and oxidation determinations. Our results have shown that the designed chemistry of nitrogenous and/or phosphorous compounds such as lauroyl glutamine, oleoyl glycine, oleic diethanolamide phosphate and lauric diethanolamide borate was outstanding in boosting biodegradation of petroleum-based lubricants which was ascribed to increase the microbial population and decrease the oil-water interfacial tension during the biodegradation process. Lubricants doped with the biodegradation enhancers exhibited much better biodegradability and higher biodegradation rate in the surrounding soils which could be well modeled by the exponential biodegradation kinetics. Furthermore, as lubricant dopants, the biodegradation enhancers also provided excellent capability in reducing friction and wear and in retarding oxidation of lubricants. In the nature of things, lubricant biodegradation enhancers, which are multi-functional not only in the improvement of biodegradability, but also in the fortification of lubricity and in the inhibition of oxidation of lubricants, are expected to be promising as a new category of lubricant additives.
基金support provided by theShanxi Province "13115" Science and Technology Innovation Program (No. 2008ZDKG-53)the Shanxi International Scienceand Technology Cooperation Project of China (No. 2007KW-02)
文摘The modification of Shenfu coals by a microwave treatment carried out under a hydrogen or a methane atmosphere, and the subsequent maceral separation by flotation, are described in this paper. The surface contact angle and the Zeta potential of the coal macerals were measured both with and without the treat- ment. The results show that the surface wettability of SFF (Shenfu Fusain) and SFV (Shenfu Vitrain) can be changed by the microwave treatment. An increase in the difference in surface wettability of SFF and SFV causes in a subsequent increase in the enrichment of inertinite and vitrinite. The results of the Zeta potential measurements show that the surface potentials of SFF and SFV are also changed by the treatment.
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(Nos.52074061,51974060,U1903216)Northeastern University Doctoral Basal Research Fund,China(No.N2001006).
文摘Pit limit design has,up to date,focused mainly on maximization of economic profit alone,with environmental and social issues largely ignored.This paper focuses on incorporating both environmental and social issues in the pit limit design process and provides an approach to pit limit optimization that is in compliance with sustainable development.The case study demonstrates that ecological costs have a substantial down-sizing effect and social benefits have a substantial up-sizing effect on the optimal pit limit.When the ecological costs are factored in,the optimal pit limit is 37.5%smaller than the economically optimal pit limit.However,when the social benefits are factored in,the optimal pit limit is 48.3%larger than the economically optimal one.The overall optimal pit limit,with the economic profit,ecological costs and social benefits simultaneously considered,is a result of balancing conflicting goals of maximizing economic profit,minimizing ecological cost,and maximizing social benefit.
文摘It is wen-known that patented technology licensing is closely related to technology standards, and whether a technology standard contains a specific patented technology solution or not, there is always a patented technology hcensing imphed, for patented technology hcensing is a prerequisite for the existence and development of technology standards. Therefore, technology standards create a good many potential chances for hcensing patented technologies concerning them. Superficially speaking, patent holders achieve huge profits mainly by means of hcensing patented technologies through a standard mainly in the form of a patent pool; however, in fact, it is know-how licensing behind the patented technology involved in the standard that really helps patent holders make huge profits.