在MTS815 Flex Test GT岩石力学试验系统上,对砂岩进行单轴压缩和三轴循环加卸载试验。结果表明,砂岩的侧向变形和体积变形都与岩石破坏有密不可分的关系;岩石微裂纹的压缩和释放并不一致,内凹现象和推进效应是岩石内部微裂纹压密、闭...在MTS815 Flex Test GT岩石力学试验系统上,对砂岩进行单轴压缩和三轴循环加卸载试验。结果表明,砂岩的侧向变形和体积变形都与岩石破坏有密不可分的关系;岩石微裂纹的压缩和释放并不一致,内凹现象和推进效应是岩石内部微裂纹压密、闭合、扩展等引起的;在循环加卸载持续作用下,岩石的破坏是一个累积的过程;滞回环面积受到围压、荷载大小和加载次数的影响;轴向和侧向累计不可逆应变在循环荷载作用下的增长趋势呈线性关系,围压的增大可有效限制岩石侧向累计不可逆应变。展开更多
Unique MoS_(2)‐SnS_(2)heterogeneous nanoplates have successfully in‐situ grown on poly(3‐(1‐vinylimidazolium‐3‐yl)propane‐1‐sulfonate)functionalized polypyrrole/graphene oxide(PVIPS/PPy/GO).PVIPS can attract h...Unique MoS_(2)‐SnS_(2)heterogeneous nanoplates have successfully in‐situ grown on poly(3‐(1‐vinylimidazolium‐3‐yl)propane‐1‐sulfonate)functionalized polypyrrole/graphene oxide(PVIPS/PPy/GO).PVIPS can attract heptamolybdate ion(Mo7O246−)and Sn^(4+)as the precursors by the ion‐exchange,resulting in the simultaneous growth of 1T’‐MoS2 and the berndtite‐2T‐type hexagonal SnS_(2)by the interfacial induced effect of PVIPS.The obtained MoS_(2)‐SnS_(2)/PVIPS/PPy/GO can serve as electrocatalysts,exhibiting good NRR performance by the synergistic effect.The semi‐conducting SnS_(2)would limit the surface electron accessibility for suppressing HER process of 1T’‐MoS_(2),while metallic 1T’‐MoS_(2)might efficiently improve the NRR electroactivity of SnS_(2)by the creation of Mo‐Sn‐Sn trimer catalytic sites.Otherwise,the irreversible crystal phase transition has taken place during the NRR process.Partial 1T’‐MoS_(2)and SnS_(2)have electrochemically reacted with N_(2),and irreversibly converted into Mo^(2)N and SnxNz due to the formation of Mo−N and Sn−N bonding,meanwhile,partial SnS_(2) has been irreversibly evolved into SnS due to the reduction by the power source in the electrochemical system.It would put forward a new design idea for optimizing the preparation method and electrocatalytic activity of transition metal dichalcogenides.展开更多
A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions： a spin-reorientation-like transition followed by a ferromagnetic-paramagneti...A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions： a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg^-1, with a maximum magnetic entropy change -ASmax of 17 J kg^-1K^-1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg^-1 and 7.4 J kg-lK^-1, respectively.展开更多
Monitoring subtle changes in ionic current flow through a nanopore could be applied to observe single molecule reaction. Here,we introduced cysteine to substitute for lysine at position 238 constructing a mutant aerol...Monitoring subtle changes in ionic current flow through a nanopore could be applied to observe single molecule reaction. Here,we introduced cysteine to substitute for lysine at position 238 constructing a mutant aerolysin K238 C. It could be regarded as a nanoreactor to efficiently visualize chemical bonds making and breaking. The compound 5,5′-dithiobis-(2-nitrobenzoic acid)(DTNB) was selected as a reactant coming into collisions on the interface of the pore to occur a reversible reaction. Our results showed that the mutant aerolysin could respond to three molecules of DTNB simultaneously and reflect corresponding levels with distinguishable current signals. Therefore, this method constitutes a simple, generic tool for monitoring single molecule reaction, which evokes a guidance for the mutant aerolysin towards the application of tracking other more reactions at single molecule level.展开更多
文摘在MTS815 Flex Test GT岩石力学试验系统上,对砂岩进行单轴压缩和三轴循环加卸载试验。结果表明,砂岩的侧向变形和体积变形都与岩石破坏有密不可分的关系;岩石微裂纹的压缩和释放并不一致,内凹现象和推进效应是岩石内部微裂纹压密、闭合、扩展等引起的;在循环加卸载持续作用下,岩石的破坏是一个累积的过程;滞回环面积受到围压、荷载大小和加载次数的影响;轴向和侧向累计不可逆应变在循环荷载作用下的增长趋势呈线性关系,围压的增大可有效限制岩石侧向累计不可逆应变。
文摘Unique MoS_(2)‐SnS_(2)heterogeneous nanoplates have successfully in‐situ grown on poly(3‐(1‐vinylimidazolium‐3‐yl)propane‐1‐sulfonate)functionalized polypyrrole/graphene oxide(PVIPS/PPy/GO).PVIPS can attract heptamolybdate ion(Mo7O246−)and Sn^(4+)as the precursors by the ion‐exchange,resulting in the simultaneous growth of 1T’‐MoS2 and the berndtite‐2T‐type hexagonal SnS_(2)by the interfacial induced effect of PVIPS.The obtained MoS_(2)‐SnS_(2)/PVIPS/PPy/GO can serve as electrocatalysts,exhibiting good NRR performance by the synergistic effect.The semi‐conducting SnS_(2)would limit the surface electron accessibility for suppressing HER process of 1T’‐MoS_(2),while metallic 1T’‐MoS_(2)might efficiently improve the NRR electroactivity of SnS_(2)by the creation of Mo‐Sn‐Sn trimer catalytic sites.Otherwise,the irreversible crystal phase transition has taken place during the NRR process.Partial 1T’‐MoS_(2)and SnS_(2)have electrochemically reacted with N_(2),and irreversibly converted into Mo^(2)N and SnxNz due to the formation of Mo−N and Sn−N bonding,meanwhile,partial SnS_(2) has been irreversibly evolved into SnS due to the reduction by the power source in the electrochemical system.It would put forward a new design idea for optimizing the preparation method and electrocatalytic activity of transition metal dichalcogenides.
基金supported by the National Natural Science Foundation of China (Grant No. 50831006)the National Basic Research Program of China ("973" Project) (Grant No. 2010CB934603)
文摘A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions： a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg^-1, with a maximum magnetic entropy change -ASmax of 17 J kg^-1K^-1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg^-1 and 7.4 J kg-lK^-1, respectively.
基金supported by the National Natural Science Foundation of China (21421004, 21777041, 21327807)the Program of Introducing Talents of Discipline to Universities (B16017)+1 种基金Innovation Program of Shanghai Municipal Education Commission (2017-0107-00-02-E00023)the Fundamental Research Funds for the Central Universities (222201718001, 222201717003)
文摘Monitoring subtle changes in ionic current flow through a nanopore could be applied to observe single molecule reaction. Here,we introduced cysteine to substitute for lysine at position 238 constructing a mutant aerolysin K238 C. It could be regarded as a nanoreactor to efficiently visualize chemical bonds making and breaking. The compound 5,5′-dithiobis-(2-nitrobenzoic acid)(DTNB) was selected as a reactant coming into collisions on the interface of the pore to occur a reversible reaction. Our results showed that the mutant aerolysin could respond to three molecules of DTNB simultaneously and reflect corresponding levels with distinguishable current signals. Therefore, this method constitutes a simple, generic tool for monitoring single molecule reaction, which evokes a guidance for the mutant aerolysin towards the application of tracking other more reactions at single molecule level.
