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阴离子主导的手性Cu(Ⅱ)配位聚合物:可逆的结构转换,圆二色谱和二次谐波响应(英文) 被引量:1
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作者 程林 刘琪 +1 位作者 杨晶华 章清松 《无机化学学报》 SCIE CAS CSCD 北大核心 2018年第6期1018-1027,共10页
用手性的V形双齿配体N,N′-((1R,2R)-1,2-二取代环己二胺)双(N-苯甲酸(3-吡啶亚甲基)酰胺(1R,2R)-3-bcpb)和不同的Cu(Ⅱ)盐反应,组装成2个新的手性Cu(Ⅱ)配位聚合物{[Cu((1R,2R)-3-bcpb)]Cl_2}_n(1)和{[Cu((1R,2R)-3-bcpb)_2](ClO_4)2&#... 用手性的V形双齿配体N,N′-((1R,2R)-1,2-二取代环己二胺)双(N-苯甲酸(3-吡啶亚甲基)酰胺(1R,2R)-3-bcpb)和不同的Cu(Ⅱ)盐反应,组装成2个新的手性Cu(Ⅱ)配位聚合物{[Cu((1R,2R)-3-bcpb)]Cl_2}_n(1)和{[Cu((1R,2R)-3-bcpb)_2](ClO_4)2·2H_2O·2CH_3OH}_n(2)。其中1是一维链状结构,2具有二维(4,4)网络拓扑。溶剂热条件下,在甲醇溶剂体系中,通过引入AgClO_4,1能转换成2,同时通过加入NaCl,2也能转换成1。圆二色谱和二次谐波响应测试验证了它们具有结构上的手性。 展开更多
关键词 手性配位聚合物 可逆结构转换 手性-1 2-环己二胺 阴离子主导
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Study on the Reversible DC-DC Converter as Interface between Low and Medium Voltage DC Networks
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作者 Stephan Kenzelmann Carlo Arrioja Alfred Rufer 《Journal of Energy and Power Engineering》 2012年第8期1284-1291,共8页
This paper introduces an isolated reversible DC-DC converter with a particular topology, which benefits from both the NPC (neutral point clamped) structure and the series-parallel connection of converters. The key p... This paper introduces an isolated reversible DC-DC converter with a particular topology, which benefits from both the NPC (neutral point clamped) structure and the series-parallel connection of converters. The key property of the proposed topology is the output voltage elevation above the blocking capabilities of each switch, without taking to a delicate synchronization of series-connected semiconductors. The converter is composed by two identical cells, each containing a full bridge, a medium frequency transformer and an NPC converter, connected in parallel at the input and in series at the output. The operation principle of each cell, into which a trapezoidal modulation was implemented, is similar to a DAB (dual active bridge). A new model improves the dynamic performance of the controller. Simulation and experimental results verify the proposed topology, its control and start-up strategy. 展开更多
关键词 DC-DC converter multilevel converter DC transformer medium voltage medium frequency transformer.
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