The technology of He ion implantation for improving the catastrophic optical damage (COD) level of 980nm semiconductor lasers is introduced.After He ion implantation,p-GaAs obtain higher resistivity than before.About...The technology of He ion implantation for improving the catastrophic optical damage (COD) level of 980nm semiconductor lasers is introduced.After He ion implantation,p-GaAs obtain higher resistivity than before.About 25μm-long current non-injection regions are introduced near both facets,where the injection current is blocked by high resistivity area.The current non-injection regions can reduce carriers inject to facets,and the rate of the non-radiative recombination are reduced.So the COD level is higher than before.The He ion implantation LDs exhibit no COD failure until the rollover occure at a mean maximum power of 440.5mW.Mean COD level of conventional LDs is given as 407.5mW.Compared to conventional LDs,the mean maximum output power level of He ion implantation LDs is improved by 8%.展开更多
Some factors influencing the intelligibility of the enhanced whisper in the joint time-frequency domain are evaluated. Specifically, both the spectrum density and different regions of the enhanced spectrum are analyze...Some factors influencing the intelligibility of the enhanced whisper in the joint time-frequency domain are evaluated. Specifically, both the spectrum density and different regions of the enhanced spectrum are analyzed. Experimental results show that for a spectrum of some density, the joint time-frequency gain-modification based speech enhancement algorithm achieves significant improvement in intelligibility. Additionally, the spectrum region where the estimated spectrum is smaller than the clean spectrum, is the most important region contributing to intelligibility improvement for the enhanced whisper. The spectrum region where the estimated spectrum is larger than twice the size of the clean spectrum is detrimental to speech intelligibility perception within the whisper context.展开更多
High power and high-slope efficiency 650nm band real-refractive-index ridge w aveguide AlGaInP laser diodes with compressive strained MQW active layer are for med by pure Ar ion beam etching process.Symmetric laser me...High power and high-slope efficiency 650nm band real-refractive-index ridge w aveguide AlGaInP laser diodes with compressive strained MQW active layer are for med by pure Ar ion beam etching process.Symmetric laser mesas with high perpendi cularity,which are impossible to obtain by traditional wet etching method due to the use of a 15°-misoriented substrate,are obtained by this dry etching metho d.Laser diodes with 4μm wide,600μm long and 10%/90% coat are fabricated.Th e typical threshold current of these devices is 46mA at room temperature,and a s table fundamental-mode operation over 40mW is obtained.Very high slope efficien cy of 1.4W/A at 10mW and 1.1W/A at 40mW are realized.展开更多
A hybrid central-upwind scheme is proposed. Two sub-schemes, the central difference scheme and the Roets flux difference splitting scheme, are hybridized by means of a binary sensor function. In order to examine the c...A hybrid central-upwind scheme is proposed. Two sub-schemes, the central difference scheme and the Roets flux difference splitting scheme, are hybridized by means of a binary sensor function. In order to examine the capability of the proposed hybrid scheme in computing compressible turbulent flow around a curved surface body, especially the flow involving shock wave, three typical eases are investigated by using detached-eddy simulation technique. Numerical results show good agreements with the experimental measurements. The present hybrid scheme can be applied to simulating the compressible flow around a curved surface body involving shock wave and turbulence.展开更多
In this paper, some properties of the monotone set function defined by theChoquet integral are discussed. It is shown that several important structural characteristics of theoriginal set function, such as weak null-ad...In this paper, some properties of the monotone set function defined by theChoquet integral are discussed. It is shown that several important structural characteristics of theoriginal set function, such as weak null-additivity, strong order continuity, property (s) andpseudomelric generating property, etc., are preserved by the new set function. It is also shown thatC-integrability assumption is inevitable for the preservations of strong order continuous andpseudometric generating property.展开更多
We give the generalized definitions of variable separable solutions to nonlinear evolution equations, and characterize the relation between the functional separable solution and the derivative-dependent functional sep...We give the generalized definitions of variable separable solutions to nonlinear evolution equations, and characterize the relation between the functional separable solution and the derivative-dependent functional separable solution. The new definitions can unify various kinds of variable separable solutions appearing in references. As application, we classify the generalized nonlinear diffusion equations that admit special functional separable solutions and obtain some exact solutions to the resulting equations.展开更多
The influence of various water soluble cations(K^+,Na^+,Ca^2+,Mg^2+)on the hydration of calcined flue gas desulphurization gypsum was investigated.The results show that all cations but Ca^2+can accelerate the hydratio...The influence of various water soluble cations(K^+,Na^+,Ca^2+,Mg^2+)on the hydration of calcined flue gas desulphurization gypsum was investigated.The results show that all cations but Ca^2+can accelerate the hydration of bassanite.The final crystal size is not largely influenced by different salts,except for Na^+,where the giant crystal with length of>130μm is observed.Current study clarifies the influence of different ions on the hydration of bassanite,which could provide sufficient guide for the pre-treatment of original flue gas desulphurization gypsum before actual application.展开更多
Ionic liquid 1-methyl-3-(3-sulfopropyl) -imidazolium hydrogen sulfate([C3SO3HMIM][HSO4]) was synthesized and characterized by infrared spectroscopy(IR) ,nuclear magnetic resonance(1H and 13C NMR) and ultraviolet-visib...Ionic liquid 1-methyl-3-(3-sulfopropyl) -imidazolium hydrogen sulfate([C3SO3HMIM][HSO4]) was synthesized and characterized by infrared spectroscopy(IR) ,nuclear magnetic resonance(1H and 13C NMR) and ultraviolet-visible(UV-Vis) spectra. Its thermal stability was also examined by thermogravimetric analysis(TGA) and a differential scanning calorimeter(DSC) . The mole fraction solubilities of [C3SO3HMIM][HSO4]) in 12 selected solvents(n-pentane,n-hexane,n-heptane,benzene,toluene,ethylbenzene,acetone,2-butanone,3-methyl-2-butanone,tetrahydrofuran,ethyl acetate and dichloromethane) in the temperature range from 289.15 to 363.15 K were meas-ured using a static analytical method and correlated with an empirical equation.展开更多
The cardiac and vascular effect of ethanolamine nitrate ester ferulate (ENF) wasinvestigated on isolated working guinea pig heart (IWH) and rat aortic ring. The coronary blood flowwas remarkably increased while the c...The cardiac and vascular effect of ethanolamine nitrate ester ferulate (ENF) wasinvestigated on isolated working guinea pig heart (IWH) and rat aortic ring. The coronary blood flowwas remarkably increased while the cardiac functions of IWH were not significantly altered by ENFranging from 10-8 to 10-4 mol/L. The percentages of vasorelaxation of ENF t 10 μmol/L) and nicoran-dil (NIC, 10 μmol/L) on K+ (80 mmol/L)-induced contraction in aortic rings were 72 ± 8% and17±8%, respectively. The relaxation effects of ENF and NIC on phenylephrine (PE, 5 μmol/L) in-duced contraction were in a dose-dependent manner. When vessel segments were exposed to PE withmethylene blue (MB, 10 μmol/L) or with glibenclamide (GLI, 10 pmol/L), the percentages of relaxa-tion of ENF (10 μmol/L) and NIC ( 1 0 μmol/L) were 4 1 ±11 % and 49±7% or 76± 14% and the 33±9%,respectively. The results suggested that ENF improved coronary circulation and the vasodilation of ENF was mediated bv nitrate-like action.展开更多
The relations among three kinds of structural characteristics of fuzzy measure: (1) pseudometric generating property; (2) pseudometric generating property of type p; (3) null null additivity, and the convergence for ...The relations among three kinds of structural characteristics of fuzzy measure: (1) pseudometric generating property; (2) pseudometric generating property of type p; (3) null null additivity, and the convergence for sequence of measurable function on semi continuous fuzzy measure space are discussed. A set of equivalent conditions for each of these structural characteristics are presented, respectively. It is proved that null null additivity is equivalent to pseudometric generating property for a finite fuzzy measure on S compact space.展开更多
A possible mechanism for boosting the visible-light photoactivities of graphitic carbon nitride(g-C3N4)nanosheets for CO2 reduction via coupling with the electron donor Co-metal-organic framework(MOF)is proposed in th...A possible mechanism for boosting the visible-light photoactivities of graphitic carbon nitride(g-C3N4)nanosheets for CO2 reduction via coupling with the electron donor Co-metal-organic framework(MOF)is proposed in this study.Specifically,Co-MOF as an electron donor is capable of transferring the photogenerated electrons in the lowest unoccupied molecular orbital(LUMO)to the conduction band of g-C3N4 to facilitate charge separation.As expected,the prepared Co-MOF/g-C3N4 nanocomposites display excellent visible-light-driven photocatalytic CO2 reduction activities.The CO production rate of 6.75μmol g–1 h–1 and CH4 evolution rate of 5.47μmol g–1 h–1 are obtained,which are approximately 2 times those obtained with the original g-C3N4 under the same conditions.Based on a series of analyses,it is shown that the introduction of Co-MOF not only broadens the range of visible-light absorption but also enhances the charge separation,which improves the photocatalytic activity of g-C3N4 to a higher level.In particular,the hydroxyl radical(·OH)experiment was operated under 590 nm(single-wavelength)irradiation,which further proved that the photogenerated electrons in the LUMO of Co-MOF can successfully migrate to g-C3N4.This work may provide an important strategy for the design of highly efficient g-C3N4-based photocatalysts for CO2 reduction.展开更多
To further improve the charge separation and photocatalytic activities of g-C3N4 and CdMoO4 under visible light irradiation,CdMoO4/g-C3N4 composites were rationally synthesized by a facile precipitation-calcination pr...To further improve the charge separation and photocatalytic activities of g-C3N4 and CdMoO4 under visible light irradiation,CdMoO4/g-C3N4 composites were rationally synthesized by a facile precipitation-calcination procedure.The crystal phases,morphologies,chemical compositions,textural structures,and optical properties of the as-prepared composites were characterized by the corresponding analytical techniques.The photocatalytic activities toward degradation of rhodamine B solution were evaluated under visible light irradiation.The results revealed that integrating CdMoO4 with g-C3N4 could remarkably improve the charge separation and photocatalytic activity,compared with those of pristine g-C3N4 and CdMoO4.This would be because the CdMoO4/g-C3N4 composites could facilitate the transfer and separation of the photoexcited electron-hole pairs,which was confirmed by electrochemical impedance spectroscopy,transient photocurrent responses,and photoluminescence measurements.Moreover,active species trapping experiments demonstrated that holes(h+)and superoxide radicals(?O2?)were the main active species during the photocatalytic reaction.A possible photocatalytic mechanism was proposed on the basis of the energy band structures determined by Mott-Schottky tests.This work would provide further insights into the rational fabrication of composites for organic contaminant removal.展开更多
We report a facile approach to water-dispersible polydiacetylene/rare earth ions nanocomposites with reversible thermochromism. The nanocomposites were prepared by doping rare earth ions Dy^3+ or Sin^3+ into layer-s...We report a facile approach to water-dispersible polydiacetylene/rare earth ions nanocomposites with reversible thermochromism. The nanocomposites were prepared by doping rare earth ions Dy^3+ or Sin^3+ into layer-structured 10,12-pentacosadiynoic acid (PCDA) nanopar- ticles to obtain PCDA/rare earth ions nanocomposites (PCDA-RE) and subsequently annealing PCDA-RE at the temperature slightly higher than the melting point of pure PCDA crystals, followed by topochemically polymerizing the annealed PCDA-RE. The polymerized PCDA-RE, i.e. poly(10,12-pentacosadiynoic acid)/rare earth ions nanocomposites (PDARE: PDA-Dy or PDA-Sm), are largely reversible (PDA-Sm) or even completely reversible (PDA-Dy) in the thermochromism, while, without the doping, pure PDA is completely irreversible. It is confirmed that, PDA-RE are also layer-structured with a d-spacing of 5.4 nm, higher than the d-spacing of pure PDA (4.7 nm). In PDA-RE, the rare earth ions form a layer in-between and interact strongly with the PDA bilayers, being responsible for the high degree or even the complete reversibility. This is the first example to make PDA completely reversible through the doping of rare earth ions; the annealing process is essential for the complete reversibility since it removes any defects in the structure.展开更多
According to the description effect range, the method of scaling system in cartography is with the precision of four grades: nominal scaling, ordinal scaling, interval scaling and ratio scaling. The authors have rese...According to the description effect range, the method of scaling system in cartography is with the precision of four grades: nominal scaling, ordinal scaling, interval scaling and ratio scaling. The authors have researched their innate character and inherent relations. The essence of evaluation partialordering set (A ,≤) is the mapping of evaluation object (X, ≤) under fixed condition. The collection and classification of xi ∈ X corresponds how to express Aj ∈ A, i.e. , V xi ∈ X→f(xi ) = Aj → A, Aj is the image of xi under mapping f. The function relation between evaluation partial-ordering set (A, ≤) and evaluation object (X, ≤) is decided by the space character and the way of collection and classification. The different space character and way of collection and classification will produce the different express method and evaluation result, accordingly the authors give out the mathematical definitions for nominal scaling, ordinal scaling, interval scaling and ratio scaling respectively. These results have been proved through the examples.展开更多
In this paper, we discuss a discrete time repairable queuing system with Markovian arrival process, where lifetime of server, service time and repair time of server are all discrete phase type random variables. Using...In this paper, we discuss a discrete time repairable queuing system with Markovian arrival process, where lifetime of server, service time and repair time of server are all discrete phase type random variables. Using the theory of matrix geometric solution, we give the steady state distribution of queue length and waiting time. In addition, the stable availability of the system is also provided.展开更多
Information on the distribution patterns of soil water content (SWC), soil organic matter (SOM), and soil exchangeable cations (SEC) is important for managing forest ecosystems in a sustainable manner. This stud...Information on the distribution patterns of soil water content (SWC), soil organic matter (SOM), and soil exchangeable cations (SEC) is important for managing forest ecosystems in a sustainable manner. This study investigated how SWC, SOM, and SEC were influenced in forests along a successional gradient, including a regional climax (monsoon evergreen broad-leaved forest, or MEBF), a transitional forest (coniferous and broad-leaved mixed forest, or MF), and a pioneer forest (coniferous Masson pine (Pinus rnassoniana) forest, or MPF) of the Dinghushan Biosphere Reserve in the subtropical region of southern China. SWC, SOM, and SEC excluding Ca^2+ were found to increase in the soil during forest succession, being highest in the top soil layer (0 to 15 cm depth) except for Na^+. The differences between soil layers were largest in MF. This finding also suggested that the nutrients were enriched in the topsoil when they became increasingly scarce in the soil. There were no significant differences (P = 0.05) among SWC, SOM, and SEC. A linear, positive correlation was found between SWC and SOM. The correlation between SOM and cation exchange capacity (CEC) was statistically significant, which agreed with the theory that the most important factor determining SEC is SOM. The ratio of K^+ to Na^+ in the topsoil was about a half of that in the plants of each forest. MF had the lowest exchangeable Ca^2+ concentration among the three forests and Ca^2+:K^+ in MPF was two times higher than that in MF. Understanding the changes of SWC, SOM, and CEC during forest succession would be of great help in protecting all three forests in southern China.展开更多
Polydiacetylene(PDA)is one kind of the conjugated polymer with layered structure,which can serve as a host to accommodate the guest components through intercalation.In these intercalated PDAs,some of them were reporte...Polydiacetylene(PDA)is one kind of the conjugated polymer with layered structure,which can serve as a host to accommodate the guest components through intercalation.In these intercalated PDAs,some of them were reported to have a nearly perfect organized structure and perform completely reversible thermochromism.Till now,these reported intercalated PDAs were made by only introducing a single component for intercalation.Here,we chose 10,12-pentacosadiynoic acid(PCDA)as the monomer,of which the carboxyl-terminal groups can interact with either Tb^3+ ions or melamines(MAs).When the feeding molar ratio of PCDA,MA,and Tb^3+ ion was 3:267:1,only Tb^3+ ions were intercalated though excess MAs existed.Such Tb^3+- intercalated poly-PCDA exhibited completely reversible thermochromism,where almost all the carboxyl groups interacted with Tb^3+ ions to form the nearly perfect structure.When the feeding molar ratio of PCDA,MA,and Tb^3+ ion was 3:267:0.6,both Tb^3+ ions and MAs were intercalated.There existed some defects in the imperfect MA-intercalated domains and at the domain boundaries.The MA/Tb^3+- intercalated poly-PCDA exhibits partially reversible thermochromism,where the backbones near the defects are hard to return the initial conformation,while the rest,those at nearly perfect organized domains,are still able to restore the initial conformation.展开更多
A novel plasmonic photo‐Fenton catalyst of Ag/AgCl/Fe‐S was synthesized by ion exchange and photoreduction methods.The obtained catalyst was characterized by X‐ray diffraction,X‐ray photoelectron spectroscopy,scan...A novel plasmonic photo‐Fenton catalyst of Ag/AgCl/Fe‐S was synthesized by ion exchange and photoreduction methods.The obtained catalyst was characterized by X‐ray diffraction,X‐ray photoelectron spectroscopy,scanning electron microscope imaging,and Brunauer‐Emmett‐Teller measurements.Moreover,the photocatalytic activity of Ag/AgCl/Fe‐S was investigated for its degradation activity towards bisphenol A(BPA)as target pollutant under visible light irradiation.The effects of H2O2concentration,pH value,illumination intensity,and catalyst dosage on BPA degradation were examined.Our results indicated that the Ag/AgCl material was successfully loaded onto Fe‐sepiolite and showed a high photocatalytic activity under illumination by visible light.Furthermore,active species capture experiments were performed to explore the photocatalytic mechanism of the Ag/AgCl/Fe‐S in this heterogeneous photo‐Fenton process,where the major active species included hydroxyl radicals(?OH)and holes(h+).展开更多
The early diagnosis of gastric cancer allows patients and physicians to pursue the option of endoscopic resection,which is significantly less invasive than conventional surgical resection.In Korea,the use of endoscopi...The early diagnosis of gastric cancer allows patients and physicians to pursue the option of endoscopic resection,which is significantly less invasive than conventional surgical resection.In Korea,the use of endoscopic submucosal dissection(ESD) has been increasing,and many reports on ESD have been published.In addition,Korean gastroenterologists from several hospitals performing ESD have conducted formal meetings to discuss useful information regarding ESD.Here,we discuss the Korean experience with ESD,including outcomes and prospects of endoscopic treatments.展开更多
Discrete-rate adaptive modulation (AM) scheme for distributed antenna system (DAS) with imperfect channel state information (CSI) is developed, and the corresponding performance is investigated in composite Rayl...Discrete-rate adaptive modulation (AM) scheme for distributed antenna system (DAS) with imperfect channel state information (CSI) is developed, and the corresponding performance is investigated in composite Rayleigh channel. Subject to target bit error rate (BER) constraint, an improved fixed switching threshold (FST) for the AM scheme is presented by means of tightly-approximate BER expression, and it can avoid the performance loss fxom conventional FST. Based on the imperfect CSI, the variable switching threshold (VST) is derived by utilizing the maximum a posteriori method. This VST includes the improved FST as a special case, and may lower the impact of estimation error on the performance. By the switching thresholds, the spectrum efficiency (SE) and average BER of the system are respectively derived, and resulting closed- form expressions are attained. With these expressions, the system performance can be effectively evaluated. Simulation results show that the derived theoretical SE and BER can match the simulations well. Moreover, the AM with the presented FST has higher SE than that with the conventional one, and the AM with VST can tolerate the large estimation error while maintaining the target BER.展开更多
文摘The technology of He ion implantation for improving the catastrophic optical damage (COD) level of 980nm semiconductor lasers is introduced.After He ion implantation,p-GaAs obtain higher resistivity than before.About 25μm-long current non-injection regions are introduced near both facets,where the injection current is blocked by high resistivity area.The current non-injection regions can reduce carriers inject to facets,and the rate of the non-radiative recombination are reduced.So the COD level is higher than before.The He ion implantation LDs exhibit no COD failure until the rollover occure at a mean maximum power of 440.5mW.Mean COD level of conventional LDs is given as 407.5mW.Compared to conventional LDs,the mean maximum output power level of He ion implantation LDs is improved by 8%.
基金The National Natural Science Foundation of China(No.61301295,61273266,61301219,61201326,61003131)the Natural Science Foundation of Anhui Province(No.1308085QF100,1408085MF113)+2 种基金the Natural Science Foundation of Jiangsu Province(No.BK20130241)the Natural Science Foundation of Higher Education Institutions of Jiangsu Province(No.12KJB510021)the Doctoral Fund of Anhui University
文摘Some factors influencing the intelligibility of the enhanced whisper in the joint time-frequency domain are evaluated. Specifically, both the spectrum density and different regions of the enhanced spectrum are analyzed. Experimental results show that for a spectrum of some density, the joint time-frequency gain-modification based speech enhancement algorithm achieves significant improvement in intelligibility. Additionally, the spectrum region where the estimated spectrum is smaller than the clean spectrum, is the most important region contributing to intelligibility improvement for the enhanced whisper. The spectrum region where the estimated spectrum is larger than twice the size of the clean spectrum is detrimental to speech intelligibility perception within the whisper context.
文摘High power and high-slope efficiency 650nm band real-refractive-index ridge w aveguide AlGaInP laser diodes with compressive strained MQW active layer are for med by pure Ar ion beam etching process.Symmetric laser mesas with high perpendi cularity,which are impossible to obtain by traditional wet etching method due to the use of a 15°-misoriented substrate,are obtained by this dry etching metho d.Laser diodes with 4μm wide,600μm long and 10%/90% coat are fabricated.Th e typical threshold current of these devices is 46mA at room temperature,and a s table fundamental-mode operation over 40mW is obtained.Very high slope efficien cy of 1.4W/A at 10mW and 1.1W/A at 40mW are realized.
基金Supported by the National Science Foundation for Post-doctoral Scientists of China(20100481141,201104567)the Natural Science Foundation of Jiangsu Province(BK2011723)the Planned Projects for Postdoctoral Research Foundation of Jiangsu Province(0902001C)~~
文摘A hybrid central-upwind scheme is proposed. Two sub-schemes, the central difference scheme and the Roets flux difference splitting scheme, are hybridized by means of a binary sensor function. In order to examine the capability of the proposed hybrid scheme in computing compressible turbulent flow around a curved surface body, especially the flow involving shock wave, three typical eases are investigated by using detached-eddy simulation technique. Numerical results show good agreements with the experimental measurements. The present hybrid scheme can be applied to simulating the compressible flow around a curved surface body involving shock wave and turbulence.
文摘In this paper, some properties of the monotone set function defined by theChoquet integral are discussed. It is shown that several important structural characteristics of theoriginal set function, such as weak null-additivity, strong order continuity, property (s) andpseudomelric generating property, etc., are preserved by the new set function. It is also shown thatC-integrability assumption is inevitable for the preservations of strong order continuous andpseudometric generating property.
基金The project supported by National Natural Science Foundation of China under Grant Nos.10447007 and 10671156the Natural Science Foundation of Shaanxi Province of China under Grant No.2005A13
文摘We give the generalized definitions of variable separable solutions to nonlinear evolution equations, and characterize the relation between the functional separable solution and the derivative-dependent functional separable solution. The new definitions can unify various kinds of variable separable solutions appearing in references. As application, we classify the generalized nonlinear diffusion equations that admit special functional separable solutions and obtain some exact solutions to the resulting equations.
基金supported by the National Natural Science Foundation of China(No.51473152)Scientific research foundation for Young Talents from Fujian Provincial Department of Education(No.JT180494)+2 种基金Start-up Foundation for Advanced Talents in Sanming University(No.18YG07)Industry-University-Research Cooperation Fund from Sanming Institute of Fluorine Chemical Industry Technology(FCIT20180105)Scientific research Platform Construction Pproject from Fujian Provincial Department of Science and Technology(No.2018H2002).
文摘The influence of various water soluble cations(K^+,Na^+,Ca^2+,Mg^2+)on the hydration of calcined flue gas desulphurization gypsum was investigated.The results show that all cations but Ca^2+can accelerate the hydration of bassanite.The final crystal size is not largely influenced by different salts,except for Na^+,where the giant crystal with length of>130μm is observed.Current study clarifies the influence of different ions on the hydration of bassanite,which could provide sufficient guide for the pre-treatment of original flue gas desulphurization gypsum before actual application.
文摘Ionic liquid 1-methyl-3-(3-sulfopropyl) -imidazolium hydrogen sulfate([C3SO3HMIM][HSO4]) was synthesized and characterized by infrared spectroscopy(IR) ,nuclear magnetic resonance(1H and 13C NMR) and ultraviolet-visible(UV-Vis) spectra. Its thermal stability was also examined by thermogravimetric analysis(TGA) and a differential scanning calorimeter(DSC) . The mole fraction solubilities of [C3SO3HMIM][HSO4]) in 12 selected solvents(n-pentane,n-hexane,n-heptane,benzene,toluene,ethylbenzene,acetone,2-butanone,3-methyl-2-butanone,tetrahydrofuran,ethyl acetate and dichloromethane) in the temperature range from 289.15 to 363.15 K were meas-ured using a static analytical method and correlated with an empirical equation.
文摘The cardiac and vascular effect of ethanolamine nitrate ester ferulate (ENF) wasinvestigated on isolated working guinea pig heart (IWH) and rat aortic ring. The coronary blood flowwas remarkably increased while the cardiac functions of IWH were not significantly altered by ENFranging from 10-8 to 10-4 mol/L. The percentages of vasorelaxation of ENF t 10 μmol/L) and nicoran-dil (NIC, 10 μmol/L) on K+ (80 mmol/L)-induced contraction in aortic rings were 72 ± 8% and17±8%, respectively. The relaxation effects of ENF and NIC on phenylephrine (PE, 5 μmol/L) in-duced contraction were in a dose-dependent manner. When vessel segments were exposed to PE withmethylene blue (MB, 10 μmol/L) or with glibenclamide (GLI, 10 pmol/L), the percentages of relaxa-tion of ENF (10 μmol/L) and NIC ( 1 0 μmol/L) were 4 1 ±11 % and 49±7% or 76± 14% and the 33±9%,respectively. The results suggested that ENF improved coronary circulation and the vasodilation of ENF was mediated bv nitrate-like action.
文摘The relations among three kinds of structural characteristics of fuzzy measure: (1) pseudometric generating property; (2) pseudometric generating property of type p; (3) null null additivity, and the convergence for sequence of measurable function on semi continuous fuzzy measure space are discussed. A set of equivalent conditions for each of these structural characteristics are presented, respectively. It is proved that null null additivity is equivalent to pseudometric generating property for a finite fuzzy measure on S compact space.
基金supported by the National Natural Science Foundation of China(21871079,21501052)the Outstanding Youth Project of Natural Science Foundation of Heilongjiang Province(YQ2019B006)~~
文摘A possible mechanism for boosting the visible-light photoactivities of graphitic carbon nitride(g-C3N4)nanosheets for CO2 reduction via coupling with the electron donor Co-metal-organic framework(MOF)is proposed in this study.Specifically,Co-MOF as an electron donor is capable of transferring the photogenerated electrons in the lowest unoccupied molecular orbital(LUMO)to the conduction band of g-C3N4 to facilitate charge separation.As expected,the prepared Co-MOF/g-C3N4 nanocomposites display excellent visible-light-driven photocatalytic CO2 reduction activities.The CO production rate of 6.75μmol g–1 h–1 and CH4 evolution rate of 5.47μmol g–1 h–1 are obtained,which are approximately 2 times those obtained with the original g-C3N4 under the same conditions.Based on a series of analyses,it is shown that the introduction of Co-MOF not only broadens the range of visible-light absorption but also enhances the charge separation,which improves the photocatalytic activity of g-C3N4 to a higher level.In particular,the hydroxyl radical(·OH)experiment was operated under 590 nm(single-wavelength)irradiation,which further proved that the photogenerated electrons in the LUMO of Co-MOF can successfully migrate to g-C3N4.This work may provide an important strategy for the design of highly efficient g-C3N4-based photocatalysts for CO2 reduction.
基金supported by the Open Project Program of Hubei Key Laboratory of Animal Nutrition and Feed Science,Wuhan Polytechnic University(No.201808)Hubei Important Project of Technological Innovation(2018ABA094)~~
文摘To further improve the charge separation and photocatalytic activities of g-C3N4 and CdMoO4 under visible light irradiation,CdMoO4/g-C3N4 composites were rationally synthesized by a facile precipitation-calcination procedure.The crystal phases,morphologies,chemical compositions,textural structures,and optical properties of the as-prepared composites were characterized by the corresponding analytical techniques.The photocatalytic activities toward degradation of rhodamine B solution were evaluated under visible light irradiation.The results revealed that integrating CdMoO4 with g-C3N4 could remarkably improve the charge separation and photocatalytic activity,compared with those of pristine g-C3N4 and CdMoO4.This would be because the CdMoO4/g-C3N4 composites could facilitate the transfer and separation of the photoexcited electron-hole pairs,which was confirmed by electrochemical impedance spectroscopy,transient photocurrent responses,and photoluminescence measurements.Moreover,active species trapping experiments demonstrated that holes(h+)and superoxide radicals(?O2?)were the main active species during the photocatalytic reaction.A possible photocatalytic mechanism was proposed on the basis of the energy band structures determined by Mott-Schottky tests.This work would provide further insights into the rational fabrication of composites for organic contaminant removal.
基金V.ACKNOWLEDGEMENTSThisworkwassupportedbytheNationalNatu-ralScienceFoundationofChina(No.21334001andNo.91127030).V. ACKNOWLEDGEMENTS This work was supported by the National Natu- ral Science Foundation of China (No.21334001 and No.91127030).
文摘We report a facile approach to water-dispersible polydiacetylene/rare earth ions nanocomposites with reversible thermochromism. The nanocomposites were prepared by doping rare earth ions Dy^3+ or Sin^3+ into layer-structured 10,12-pentacosadiynoic acid (PCDA) nanopar- ticles to obtain PCDA/rare earth ions nanocomposites (PCDA-RE) and subsequently annealing PCDA-RE at the temperature slightly higher than the melting point of pure PCDA crystals, followed by topochemically polymerizing the annealed PCDA-RE. The polymerized PCDA-RE, i.e. poly(10,12-pentacosadiynoic acid)/rare earth ions nanocomposites (PDARE: PDA-Dy or PDA-Sm), are largely reversible (PDA-Sm) or even completely reversible (PDA-Dy) in the thermochromism, while, without the doping, pure PDA is completely irreversible. It is confirmed that, PDA-RE are also layer-structured with a d-spacing of 5.4 nm, higher than the d-spacing of pure PDA (4.7 nm). In PDA-RE, the rare earth ions form a layer in-between and interact strongly with the PDA bilayers, being responsible for the high degree or even the complete reversibility. This is the first example to make PDA completely reversible through the doping of rare earth ions; the annealing process is essential for the complete reversibility since it removes any defects in the structure.
文摘According to the description effect range, the method of scaling system in cartography is with the precision of four grades: nominal scaling, ordinal scaling, interval scaling and ratio scaling. The authors have researched their innate character and inherent relations. The essence of evaluation partialordering set (A ,≤) is the mapping of evaluation object (X, ≤) under fixed condition. The collection and classification of xi ∈ X corresponds how to express Aj ∈ A, i.e. , V xi ∈ X→f(xi ) = Aj → A, Aj is the image of xi under mapping f. The function relation between evaluation partial-ordering set (A, ≤) and evaluation object (X, ≤) is decided by the space character and the way of collection and classification. The different space character and way of collection and classification will produce the different express method and evaluation result, accordingly the authors give out the mathematical definitions for nominal scaling, ordinal scaling, interval scaling and ratio scaling respectively. These results have been proved through the examples.
文摘In this paper, we discuss a discrete time repairable queuing system with Markovian arrival process, where lifetime of server, service time and repair time of server are all discrete phase type random variables. Using the theory of matrix geometric solution, we give the steady state distribution of queue length and waiting time. In addition, the stable availability of the system is also provided.
基金Project supported by the National Natural Science Foundation of China (Nos. 30590381-03 and 30570350).
文摘Information on the distribution patterns of soil water content (SWC), soil organic matter (SOM), and soil exchangeable cations (SEC) is important for managing forest ecosystems in a sustainable manner. This study investigated how SWC, SOM, and SEC were influenced in forests along a successional gradient, including a regional climax (monsoon evergreen broad-leaved forest, or MEBF), a transitional forest (coniferous and broad-leaved mixed forest, or MF), and a pioneer forest (coniferous Masson pine (Pinus rnassoniana) forest, or MPF) of the Dinghushan Biosphere Reserve in the subtropical region of southern China. SWC, SOM, and SEC excluding Ca^2+ were found to increase in the soil during forest succession, being highest in the top soil layer (0 to 15 cm depth) except for Na^+. The differences between soil layers were largest in MF. This finding also suggested that the nutrients were enriched in the topsoil when they became increasingly scarce in the soil. There were no significant differences (P = 0.05) among SWC, SOM, and SEC. A linear, positive correlation was found between SWC and SOM. The correlation between SOM and cation exchange capacity (CEC) was statistically significant, which agreed with the theory that the most important factor determining SEC is SOM. The ratio of K^+ to Na^+ in the topsoil was about a half of that in the plants of each forest. MF had the lowest exchangeable Ca^2+ concentration among the three forests and Ca^2+:K^+ in MPF was two times higher than that in MF. Understanding the changes of SWC, SOM, and CEC during forest succession would be of great help in protecting all three forests in southern China.
基金supported by the Programs of the Shanghai Pujiang Program(No.18PJ1401500)the National Natural Science Foundation of China(No.21801046,No.51721002,No.21574025 and No.21871057)the Ministry of Science and Technology(2016YFA0203302)。
文摘Polydiacetylene(PDA)is one kind of the conjugated polymer with layered structure,which can serve as a host to accommodate the guest components through intercalation.In these intercalated PDAs,some of them were reported to have a nearly perfect organized structure and perform completely reversible thermochromism.Till now,these reported intercalated PDAs were made by only introducing a single component for intercalation.Here,we chose 10,12-pentacosadiynoic acid(PCDA)as the monomer,of which the carboxyl-terminal groups can interact with either Tb^3+ ions or melamines(MAs).When the feeding molar ratio of PCDA,MA,and Tb^3+ ion was 3:267:1,only Tb^3+ ions were intercalated though excess MAs existed.Such Tb^3+- intercalated poly-PCDA exhibited completely reversible thermochromism,where almost all the carboxyl groups interacted with Tb^3+ ions to form the nearly perfect structure.When the feeding molar ratio of PCDA,MA,and Tb^3+ ion was 3:267:0.6,both Tb^3+ ions and MAs were intercalated.There existed some defects in the imperfect MA-intercalated domains and at the domain boundaries.The MA/Tb^3+- intercalated poly-PCDA exhibits partially reversible thermochromism,where the backbones near the defects are hard to return the initial conformation,while the rest,those at nearly perfect organized domains,are still able to restore the initial conformation.
基金supported by the National Natural Science Foundation of China(41573118)Research Foundation of Education Bureau of Hunan Province,China(14B177)Special Project of Xiangtan University~~
文摘A novel plasmonic photo‐Fenton catalyst of Ag/AgCl/Fe‐S was synthesized by ion exchange and photoreduction methods.The obtained catalyst was characterized by X‐ray diffraction,X‐ray photoelectron spectroscopy,scanning electron microscope imaging,and Brunauer‐Emmett‐Teller measurements.Moreover,the photocatalytic activity of Ag/AgCl/Fe‐S was investigated for its degradation activity towards bisphenol A(BPA)as target pollutant under visible light irradiation.The effects of H2O2concentration,pH value,illumination intensity,and catalyst dosage on BPA degradation were examined.Our results indicated that the Ag/AgCl material was successfully loaded onto Fe‐sepiolite and showed a high photocatalytic activity under illumination by visible light.Furthermore,active species capture experiments were performed to explore the photocatalytic mechanism of the Ag/AgCl/Fe‐S in this heterogeneous photo‐Fenton process,where the major active species included hydroxyl radicals(?OH)and holes(h+).
文摘The early diagnosis of gastric cancer allows patients and physicians to pursue the option of endoscopic resection,which is significantly less invasive than conventional surgical resection.In Korea,the use of endoscopic submucosal dissection(ESD) has been increasing,and many reports on ESD have been published.In addition,Korean gastroenterologists from several hospitals performing ESD have conducted formal meetings to discuss useful information regarding ESD.Here,we discuss the Korean experience with ESD,including outcomes and prospects of endoscopic treatments.
基金National Natural Science Foundation of China,Open Research Fund of National Mobile Communications Research Laboratory of Southeast University,Qing Lan Project of Jiangsu Province,the Fundamental Research Funds for the Central Universities,Research Founding of Graduate Innovation Center in NUAA,Innovation Fund of College of Electronic and Information Engineering of NUAA
文摘Discrete-rate adaptive modulation (AM) scheme for distributed antenna system (DAS) with imperfect channel state information (CSI) is developed, and the corresponding performance is investigated in composite Rayleigh channel. Subject to target bit error rate (BER) constraint, an improved fixed switching threshold (FST) for the AM scheme is presented by means of tightly-approximate BER expression, and it can avoid the performance loss fxom conventional FST. Based on the imperfect CSI, the variable switching threshold (VST) is derived by utilizing the maximum a posteriori method. This VST includes the improved FST as a special case, and may lower the impact of estimation error on the performance. By the switching thresholds, the spectrum efficiency (SE) and average BER of the system are respectively derived, and resulting closed- form expressions are attained. With these expressions, the system performance can be effectively evaluated. Simulation results show that the derived theoretical SE and BER can match the simulations well. Moreover, the AM with the presented FST has higher SE than that with the conventional one, and the AM with VST can tolerate the large estimation error while maintaining the target BER.