Pyrrolic N or pyridinic N: The active center of N-doped carbon for CO_(2) reduction

Pyridinic N is widely regarded as the active center while pyrrolic N has low‐activity in metal‐free N‐doped carbon for electrocatalytic CO_(2) reduction reaction(CO_(2)RR)to CO,but this viewpoint remains open to question.In this study,through density functional theoretical calculations,we first illustrate that the intrinsic activity of pyrrolic N is high enough for effectively catalyzing CO_(2)RR,however,due to the interplay with the neighboring pyridinic N sites,the activity of pyrrolic N is dramatically suppressed.Then,experimentally,metal‐free N‐doped carbon spheres(NCS)electrocatalysts without significant pyridinic N content are prepared for CO_(2)RR.The pyrrolic N in NCS shows a direct‐positive correlation with the performance for CO_(2)RR,representing the active center with high activity.The optimum NCS could produce syngas with a wide range of CO/H_(2) ratio(0.09 to 12)in CO_(2)RR depending on the applied potential,meanwhile,the best selectivity of 71%for CO can be obtained.Intentionally adding a small amount of pyridinic N to the optimum NCS dramatically decreases the activity for CO_(2)RR,further verifying the suppressed activity of pyrrolic N sites by the neighboring pyridinic N sites.This work reveals the interaction between a variety of N species in N‐doped carbon,and the potential of pyrrolic N as the new type of active site for electrocatalysts,which can improve our understanding of the electrocatalysis mechanism and be helpful for the rational design of high‐efficient electrocatalysts.

Ultrasonic-assisted fabrication of Cs_(2)AgBiBr_(6)/Bi_(2)WO_(6) S-scheme heterojunction for photocatalytic CO_(2) reduction under visible light

In this manuscript,Cs_(2)AgBiBr_(6)/Bi_(2)WO_(6) nanocomposites was fabricated via an ultrasonic-assisted process.The activity of the as-obtained Cs_(2)AgBiBr_(6)/Bi_(2)WO_(6) nanocomposites for photocatalytic CO_(2) reduction was studied under visible light.The as-obtained Cs_(2)AgBiBr_(6)/Bi_(2)WO_(6) nanocomposites show a superior activity for photocatalytic CO_(2) reduction to produce CH4 and CO,with an optimum activity achieved over 0.5 Cs_(2)AgBiBr_(6)/Bi_(2)WO_(6).The obvious superior activity observed over Cs_(2)AgBiBr_(6)/Bi_(2)WO_(6) nanocomposites as compared with bare Cs_(2)AgBiBr_(6) and bare Bi_(2)WO_(6) as well as a mechanical mixture of Cs_(2)AgBiBr_(6) and Bi_(2)WO_(6) can be owe to the fabrication of an efficient S-scheme heterojunction,which accelerates the separation of the photogenerated charge carriers in Cs_(2)AgBiBr_(6) and Bi_(2)WO_(6) without sacrificing the high redox capability of Cs_(2)AgBiBr_(6) and Bi_(2)WO_(6).This work demonstrates that the coupling of two photocatalytic materials with staggered band alignment to form an S-scheme heterojunction is an effective strategy to develop efficient photocatalytic systems and also highlights the promising role of using lead free perovskites in photocatalysis.

GF(2)-modules for Sz (q) wrC_t

In this note the authors investigates the property of the GF(2)-modules for the wreath products Sz(q)wrCt,and establish some sufficient condition for a Sz(q)wrCt, GF(2)-module to be natural.

Visible-light-induced NiCo_(2)O_(4)@Co_(3)O_(4) core/shell heterojunction photocatalysts for efficient removal of organic dyes

Semiconductor photocatalysis has been considered as a potential technology for the removal of organic dyes from wastewater.The development of photocatalysts with high stability and strong catalytic activity is the most important in application.Visible-light-induced NiCo_(2)O_(4)@Co_(3)O_(4) core/shell heterojunctions were synthesized via a sol-gel method in this paper.Compared to bare NiCo_(2)O_(4) and Co_(3)O_(4),NiCo_(2)O_(4)@Co_(3)O_(4) showed a remarkably enhanced removal rate towards congo red(CR)degradation with 98.4%of the removal rate to CR at 120 min under irradiation.The excellent performance of NiCo_(2)O_(4)@Co_(3)O_(4) benefits from the effective separation of photogenerated electron-holes by forming a heterojunction,and the rapid transfer efficiency of photo-generated charge carriers results from the core/shell architectures.A mechanism that NiCo_(2)O_(4)@Co_(3)O_(4) degrades CR to harmless inorganic substances by h^(+),•O-2 and•OH during the photocatalytic process was proposed.

C(sp^2)-H/O-H cross-dehydrogenative coupling of quinoxalin-2(1H)-ones with alcohols under visible-light photoredox catalysis

An efficient and practical route to various 3-alkoxylquinoxalin-2(1 H)-ones through visible-light photocatalytic C(sp^2)-H/O-H cross-dehydrogenation coupling of quinoxalin-2(1 H)-ones and alcohols,employing ambient air as an oxidant at room temperature under metal-free conditions,was developed.

Degradation of phenol in industrial wastewater over the F–Fe/TiO_2 photocatalysts under visible light illumination

F–Fe/TiO_2 composite photocatalyst was synthesized by a facile one-step hydrothermal method and then characterized by XRD, XPS and UV–Vis DRS. The catalyst of F–Fe/TiO_2 exhibited the highest photodegradation rate for phenol as compared with pure TiO_2, F/TiO_2, Fe/TiO_2, F0.38–Fe0.13–TiO_2 and Fe(III)/F-TiO_2 under visible light irradiation. The simulated conditions of industrial phenolic wastewater including initial phenol concentration,visible light intensity, p H and different anions were investigated in the presence of F–Fe/TiO_2 photocatalyst. In addition, as expected, the F–Fe/TiO_2 photocatalyst displayed excellent stability, showing a potential industrial application for the treatment of phenolic wastewater.

Construction of 2D Zn‐MOF/BiVO_(4)S‐scheme heterojunction for efficient photocatalytic CO_(2) conversion under visible light irradiation

The construction of S‐scheme heterojunction photocatalysts has been regarded as an effective avenue to facilitate the conversion of solar energy to fuel.However,there are still considerable challenges with regard to efficient charge transfer,the abundance of catalytic sites,and extended light absorption.Herein,an S‐scheme heterojunction of 2D/2D zinc porphyrin‐based metal‐organic frameworks/BiVO_(4)nanosheets(Zn‐MOF/BVON)was fabricated for efficient photocatalytic CO_(2)conversion.The optimal one shows a 22‐fold photoactivity enhancement when compared to the previously reported BiVO4 nanoflake(ca.15 nm),and even exhibits~2‐time improvement than the traditional g‐C3N4/BiVO4 heterojunction.The excellent photoactivities are ascribed to the strengthened S‐scheme charge transfer and separation,promoted CO_(2)activation by the well‐dispersed metal nodes Zn_(2)(COO)_(4)in the Zn‐MOF,and extended visible light response range based on the results of the electrochemical reduction,electron paramagnetic resonance,and in‐situ diffuse reflectance infrared Fourier transform spectroscopy.The dimension‐matched Zn‐MOF/BVON S‐scheme heterojunction endowed with highly efficient charge separation and abundant catalytic active sites contributed to the superior CO2 conversion.This study offers a facile strategy for constructing S‐scheme heterojunctions involving porphyrin‐based MOFs for solar fuel production.

Flat Currents of Green-Schwarz Superstring in AdS2 × S^2 Background

From the κ symmetric action of IIB string in AdS2 × S^2 background given by Zhou, we derive the equations of motion. By using the twisted dual transformation which was introduced by Hou, we construct the flat currents, conserving non-local charge with one free parameter, for the superstring in AdS2 × S^2.

Visible-light-induced deoxygenative C2-sulfonylation of quinoline N-oxides with sulfinic acids for the synthesis of 2-sulfonylquinoline via radical reactions

A simple and efficient method for the synthesis of 2-sulfonylquinoline from deoxygenative C2-sulfonylation of quinoline N-oxides with sulfinic acid induced by visible light is presented.This protocol shows a broad substrate scope,and desired products with various substituents can be formed in moderate to high yields at room temperature.

Integrable Coupling of (2+1)-Dimensional Multi-component DLW Integrable Hierarchy and Its Hamiltonian Structure

A new multi-component Lie algebra is constructed, and a type of new loop algebra is presented. A （2＋1）-dimensional multi-component DLW integrable hierarchy is obtained by using a （2＋1）-dimensional zero curvature equation. Furthermore, the loop algebra is expanded into a larger one and a type of integrable coupling system and its corresponding Hamiltonian structure are worked out.

Singularity Analysis of 2-DOF Planar Seven-bar MechanismsUsed in Hybrid Actuators

Based on the Jacobian matrices relating the input speeds with the output speeds of linkages, a general method, which is used for solving the singularities of planar multi-loop multi-DOF linkages, is presented. The four kinds of singularities of 2-DOF planar seven-bar linkages used in hybrid actuators are analyzed in detail by this method. Its five kinds of singular positions whose characteristics are discussed respectively are discovered. Three approaches are proposed on how to avoid the singular positions of planar multi-loop multi-DOF linkages. Based on the assemblability of planar single-loop N-bar chains or linkages, the geometry conditions are investigated and discovered to avoid the singular positions of the linkages. In order to versify aforementioned conclusions, a case is given in which the singular curves are plotted and simulated.

A complexity-scalable software-based MPEG-2 video encoder

With the development of general-purpose processors (GPP) and video signal processing algorithms, it is possible to implement a software-based real-time video encoder on GPP, and its low cost and easy upgrade attract developers' interests to transfer video encoding from specialized hardware to more flexible software. In this paper, the encoding structure is set up first to support complexity scalability; then a lot of high performance algorithms are used on the key time-consuming modules in coding process; finally, at programming level, processor characteristics are considered to improve data access efficiency and processing parallelism. Other programming methods such as lookup table are adopted to reduce the computational complexity. Simulation results showed that these ideas could not only improve the global performance of video coding, but also provide great flexibility in complexity regulation.

河北南部方言中的虚词“可”

河北南部方言中新发现的虚成分"可1"是表示其所限定的行为动作符合说话人意愿或看法的副词,与山东方言及近代语料中的助词"可2"用法意义有易混之处,要注意区分。尽管"可1"与"可2"分布地域相邻,但我们认为"可1"与"可2"没有来源关系,"可1"应与普通话"可"同源且是其意义用法进一步引申虚化的结果。

固始方言“可VP”问句考察

固始方言中一类特殊的问句———“可”问句,将其与普通话反复问句、是非问句进行比较,发现其间的差别与对应关系。“可”有体的区别,尝试从表里值的角度揭示“可”的表现形式、句法功能及使用条件,试图探讨“可”的成因。

对国际贸易与自然环境关系的几点思考

环境保护问题已成为当今国际贸易中各国关注的新焦点 ,作者通过分析产品价格剪刀差、“环境倾销”、垃圾贸易等与环境相互影响的几个问题 ,阐明在不合理国际经济秩序和狭隘民族利己主义观念影响下 ,贸易将资源的过度开发和过度消费联系起来 ,加剧地球自然环境的污染 ,必须扭转这种状况才能保障各国平等的发展机会的权利 。

Evaluation of the computational performance of the finite-volume atmospheric model of the IAP/LASG(FAMIL) on a high-performance computer

High computational performance is extremely important for climate system models, especially in ultra-high-resolution model development. In this study, the computational performance of the Finite-volume Atmospheric Model of the IAP/LASG （FAMIL） was comprehensively evaluated on Tianhe-2, which was the world＇s top-ranked supercomputer from June 2013 to May 2016. The standardized Atmospheric Model Inter-comparison Project （AMIP） type of experiment was carried out that focused on the computational performance of each node as well as the simulation year per day （SYPD）, the running cost speedup, and the scalability of the FAMIL. The results indicated that （1） based on five indexes （CPU usage, percentage of CPU kernel mode that occupies CPU time and of message passing waiting time （CPU SW）, code vectorization （VEC）, average of Gflops （Gflops_ AVE）, and peak of Gflops （Gflops_PK））, FAMIL shows excellent computational performance on every Tianhe-2 computing node; （2） considering SYPD and the cost speedup of FAMIL systematically, the optimal Message Passing Interface （MPI） numbers of processors （MNPs） choice appears when FAMIL use 384 and 1536 MNPs for C96 （100 km） and C384 （25 km）, respectively; and （3） FAMIL shows positive scalability with increased threads to drive the model. Considering the fast network speed and acceleration card in the MIC architecture on Tianhe-2, there is still significant room to improve the computational performance of FAMIL.

Visible-Light-Induced Cascade Azidation/Cyclization of Activated Alkenes to Synthesize Azidated Indolo[2,1-a]isoquinolines

An efficient visible-light-induced radical cascade azidation/cyclization of 2-aryl indoles with trimethylsilyl azide(TMSN3)has been developed using organic dye Rose Bengal as the photocatalyst.This method did not require metal catalysts and additives,and used air as the oxidant to obtain diverse indolo[2,1-a]isoquinolin-6(5H)-ones in moderate to good yields.Mechanistic studies demonstrated that the reaction proceeded via a radical pathway.

LONG-TERM ADMINISTRATION OF RADIX TRIPTERYGII GLYCOSIDE IN A VARIETY OF GLOMERULONEPHRITIS

Objective To assess the therapeutic effects and side actions of glycoside of radix Tripterygii wilfordii in long-term treatment of a variety of glomerulonephritis. Methods 65 patients including 21,15,18 and 11 with IgA nephropathy, mesangial proliferative glomerulonephritis (MsPGN), focal segmental glomerular sclerosis (FSGS) and anaphylactoid purpura respectively, were treated with glycoside of radix Tripterygii for 12-18 months. Proteinuria and hematuria and serum soluble interleukin-2R(SIL-2R) in all patients were determined before treatment and at the end of 12-18 months. Results The results showed that 28 patients had remission, 18 improvement and 19 no effects. The total effective rate was 70%. There were signifi- cant decreases in serum SIL-2R after treatment. Conclusion Long-term treatment with glycoside of radix Tripterygii is effective, resulting in less side actions and decreased recurrent rates of IgAN?MsPGN?FSGS and anaphylactoid purpura.

Synthesis of CO_(2)-Based Re-processable Slight Cross-Linked Polyurea Thermosets

The use of CO_(2) as monomer to synthesize polymer materials is an important and potential applications topic from the viewpoint of green and sustainable chemistry.A new kind of CO_(2)-based polyurea(PUa)was synthesized by polycondensation of CO_(2) with 4,7,10-trioxa-1,13-tridecanediamine and tris(2-aminoethyl)amine(TAEA).TAEA was used as cross-link reagent.The mechanical properties of PUa were significantly improved by inserted the crosslink agent of TAEA.The formed slight cross-linked PUa exhibited excellent mechanical properties with tensile strength of 26.8 MPa,elongation at break of 34%and Young’s modulus of 351 MPa.Moreover,it could be remolded for 3 times without obvious change in the mechanical properties,which are ascribed to the hydrogen bonding interaction among the main chains and the slight cross-linked structure.In addition,the synthesized CO_(2)-based PUa is of outstanding thermal performance with an initial decomposition temperature above 300℃,besides it is tolerance for a variety of organic solvents.

Distribution of Exchangeable Calcium，Magnesium and Potassium as Affected by Fertilizer Application to Red Soil

A leaching experiment was carried out with repacked soil columns in laboratory to stndy the leachingprocess of a red soil derived from sandstone as affected by warions fertilization practices. The treatments wereCK (as a control), CaCO_3, CaSO_4, MgCO_3, Ca(H_2PO_4)_2, Urea, KCl, Mnltiple (a mixture of the above-mentioned fertilizers), and KNO_3. The fertilizers were added to the bare surface of the soil columns, andthen the columns were leached with 120 mL deionized water daily through peristaltic pumps over a periodof 92 days. At the end of leaching process, soils were sampled from different depths of the soil profiles, i.e.,0-5 cm, 5-10 cm, 10-20 cm, 20-40 cm, and 40-60 cm. The results showed when applying Ca, Mg, andK to the bare surface of the soil columns, exchangeable Ca￣(2+), Mg￣(2+), and K￣+ in the upper layer of thesoil profile increased correspondingly, with an extent depending mainly on the application rates of Ca, Mg,and K and showing a downward trend. CaCO_3, CaSO_4, MgCO_3, and Ca(H_2PO_4)_2 treatments had scarcelyany effect on movement of exchangeable K￣+, while CaCO_3, and CaSO_4 treatments significantly promotedthe downward movement of exchangeable Mg￣(2+) although these two treatments had no obvious effect onleaching losses of Mg. The fact that under Urea treatment, exchangeable Ca￣(2+) and Mg￣(2+) were higheras compared to CK treatment showed urea could prevent leaching of exchangeable Ca￣(2+) and Mg￣(2+). Theobvious downward movement of exchangeable Ca￣(2+) and Mg￣(2+) was noticed in KCl treatment. In Multipletreatment, the downward movement of exchangeable Ca￣(2+) and Mg￣(2+) was evident, while that of K￣+ was lessevident. Application of KNO_3 strongly promoted the downward movement of exchangeable Ca￣(2+) and Mg￣(2+)in the soil profile.