[Objective] The aim was to build spectral diagnosis model for nitrogen nutrition in rice leaf.[Method] Through determination of transmission,absorption spectra and nitrogen content on rice leaves of different rice var...[Objective] The aim was to build spectral diagnosis model for nitrogen nutrition in rice leaf.[Method] Through determination of transmission,absorption spectra and nitrogen content on rice leaves of different rice varieties(Xiangyou 109 and Shanyou 98),different growth periods and different nitrogen levels,we analyzed the correlation between leaf spectra and their nitrogen contents,and built prediction model of spectral index for nitrogen content in rice leaf.[Result] The detection precision of this model was above 80% that can be used on diagnosing of rice nitrogen nutrition.[Conclusion] The study provided evidence for monitoring nitrogen nutrition status of rice.展开更多
This paper presents an overview of experimental investigations conducted at China University of Mining and Technology Beijing(CUMTB) on roadway excavation using large-scale geomechanical model tests.The simulated sedi...This paper presents an overview of experimental investigations conducted at China University of Mining and Technology Beijing(CUMTB) on roadway excavation using large-scale geomechanical model tests.The simulated sedimentary rocks are composed by alternating layers of sandstone, mudstone and coal seam inclined at varied angles with respect to the horizontal including 0°, 45°, 60°, and 90°. During the excavation, infrared thermography was employed to detect the thermal response of the surrounding rocks under excavation. The obtained raw thermograms were processed using denoising algorithm, data reduction procedure and Fourier analysis. The infrared temperature(IRT) characterizes the overall rock response; the processed thermal images represent the structural behavior, and the Fourier spectrum describes damage development in the frequency domain. Deeper understanding was achieved by the comparative analyses of excavation in differently inclined rock masses using the image features of IRTs, thermal images and Fourier spectra.展开更多
Four types of common seaweeds(Laminaria japonica,Undaria pinnatifida,Porphyra haitanensis,and Gracilaria lemaneiformis) were examined to remove Cr(Ⅵ) ions from aqueous solution.The experimental parameters that affect...Four types of common seaweeds(Laminaria japonica,Undaria pinnatifida,Porphyra haitanensis,and Gracilaria lemaneiformis) were examined to remove Cr(Ⅵ) ions from aqueous solution.The experimental parameters that affected the biosorption process including pH,biomass dosage,contact time and temperature were investigated via batch experiments.The surface characteristics of seaweeds before and after Cr(Ⅵ) adsorption were studied with scanning electron microscopy and Fourier transform infrared spectroscopy.The results show that an initial solution with the pH of 1.0 is most favorable for Cr(Ⅵ) adsorption.Rapid adsorption is observed in the initial stage and adsorption equilibrium state is reached within 1 h.The adsorption efficiency by Porphyra haitanensis is the maximum among four types of seaweed powders,followed by Laminaria japonica and Undaria pinnatifida with biosorption efficiency up to 90%.The removal rate of Gracilaria lemaneiformis is less than 60%.The kinetic data obtained using the seaweeds are found to follow pseudo-second order kinetic model.Experimental sorption data adequately correlate with the Langmuir model.FTIR indicates that amino and carboxyl groups play an important role in the process of Cr(Ⅵ) adsorption and a large percentage of Cr(Ⅵ) ions are reduced by reductive groups on the surface of seaweeds.展开更多
A series of tungsten-substituted molybdophosphoric acids(H3PMo12-nWnO40·xH2O) were synthesized and characterized by inductive coupled plasma atomic emission spectroscopy(ICPAES),thermal gravimetry and differentia...A series of tungsten-substituted molybdophosphoric acids(H3PMo12-nWnO40·xH2O) were synthesized and characterized by inductive coupled plasma atomic emission spectroscopy(ICPAES),thermal gravimetry and differential scanning calorimetry(TG-DSC),Fourier transform infrared spectroscopy(FTIR),X-ray diffraction(XRD),and FTIR pyridine adsorption.The as-prepared heteropoly acids have a Keggin type structure.The synthesis of tetrahydrofuran by reactive distillation and cyclodehydration of 1,4-butanediol was studied using the tungsten-substituted molybdophosphoric acids as catalysts.The results of catalytic test indicated that the catalytic activity increased with the increase in the substitution number(n) of tungsten atom in H3PMo12-nWnO40·xH2O and was constant as the substitution number(n) was more than 8.The catalytic activity increased with the increase in the catalyst loading and the selectivity of tetrahydrofuran was nearly 100%.展开更多
The family of Cr(Ⅲ) and Fe(Ⅲ)-doped rutile pigments of nominal composition (M^ⅢM^V)xTi1-2xO2, with M^Ⅲ = Cr(Ⅲ) or Fe(Ⅲ) and M'(V) = Sb, Nb, Ta, with x = 0.03, 0.15 and 0.25 were investigated as cera...The family of Cr(Ⅲ) and Fe(Ⅲ)-doped rutile pigments of nominal composition (M^ⅢM^V)xTi1-2xO2, with M^Ⅲ = Cr(Ⅲ) or Fe(Ⅲ) and M'(V) = Sb, Nb, Ta, with x = 0.03, 0.15 and 0.25 were investigated as ceramic pigments covering the yellow-ochre-brown palette. The formulations containing Fe(Ⅲ) are novel compositions not included in the commercial rutile pigments. The materials were characterized by XRD (X-ray diffraction) analysis and FTIR (Fourier transformed infrared spectroscopy). The transition temperature from anatase-to-rutile was estimated by the evolution of the spectral patterns. This crystal phase transition is responsible of the color formation. A higher distortion of TiO6 octahedra is observed in the case of (FeSb) containing cells which contribute to the enhancement of the light absorption. The coloring performance of all the formulations were evaluated by enameling the mixtures containing 5% pigments and commercial frits representative of single and double firing industrial processes. The chromatic values obtained are in the yellow to brown domain of the chromatic plot, depending on the composition of the pigment-frit batch. In the case of the Fe-glazes, and particularly the combination (FeNb), the chromatic values are close to the best yellow tinting. This new FeNb-rutile pigment could be a more benign substitute of Cr-yellow pigments. The homogeneity of the enamels was confirmed by SEM (scanning electron microscopy)-EDAX (energy dispersive X-ray analysis) microscopy.展开更多
A novel metal-free photocatalyst--sulfur/graphene (S/GR) composite--has been synthesized using a facile one-pot, two-step hydrothermal method with thiosulfate and graphene oxide (GO) as precursors. A green reducta...A novel metal-free photocatalyst--sulfur/graphene (S/GR) composite--has been synthesized using a facile one-pot, two-step hydrothermal method with thiosulfate and graphene oxide (GO) as precursors. A green reductant--L-ascorbic add--was used to transform GO to GR under mild conditions. The photocatalyst powders were characterized by Fourier transform infrared spectroscop, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy. Experimental tests were conducted on the photocatalytic decomposition of methyl orange (MO) by different catalysts. Compared to pure oL-S, the as-prepared S/GR composite showed much enhanced photocatalytic activity for the degradation of MO under both UV and solar light. The presence of GR also greatly increased the hydrophilicity and adsorption capacity of the catalyst material. The results indicate that the incorporation of GR with a-S results in a synergistic effect for the S-based photocatalysts offering more effective environmental applications.展开更多
Hyperspectral reflectance (350-2500 nm) measurements were made over two experimental rice fields containing two cultivars treated with three levels of nitrogen application.Four different transformations of the reflect...Hyperspectral reflectance (350-2500 nm) measurements were made over two experimental rice fields containing two cultivars treated with three levels of nitrogen application.Four different transformations of the reflectance data were analyzed for their capability to predict rice biophysical parameters,comprising leaf area index (LAI;m-2 green leaf area m-2 soil) and green leaf chlorophyll density (GLCD;mg chlorophyll m 2 soil),using stepwise multiple regression (SMR) models and support vector machines (SVMs).Four transformations of the rice canopy data were made,comprising reflectances (R),first-order derivative reflectances (D1),second-order derivative reflectances (D2),and logarithm transformation of reflectances (LOG).The polynomial kernel (POLY) of the SVM using R was the best model to predict rice LAI,with a root mean square error (RMSE) of 1.0496 LAI units.The analysis of variance kernel of SVM using LOG was the best model to predict rice GLCD,with an RMSE of 523.0741 mg m-2.The SVM approach was not only superior to SMR models for predicting the rice biophysical parameters,but also provided a useful exploratory and predictive tool for analyzing different transformations of reflectance data.展开更多
The microstructure, wettability and chemical composition of the butterfly wing surfaces were investigated by a scanning electron microscope, a contact angle meter and a Fourier transform infrared spectrometer. The mic...The microstructure, wettability and chemical composition of the butterfly wing surfaces were investigated by a scanning electron microscope, a contact angle meter and a Fourier transform infrared spectrometer. The micro/nano structural models for hydrophobicity of the butterfly wing surfaces were established on the basis of the Cassie equation. The hydrophobicity mechanisms were discussed from the perspective of biological coupling. The butterfly wing surfaces are composed of naturally hydrophobic material and possess micro/nano hierarchical structures, including primary structure (micrometric scales), secondary structure (nano longitudinal ridges and lateral bridges) and tertiary structure (nano stripes). The wing surfaces exhibit high hydrophobicity (contact angle 138°-157°) and low adhesion (sliding angle 1°-3°). The micromorphology and self-cleaning performance of the wing surfaces demonstrate remarkable anisotropism. The special complex wettability ascribes to a coupling effect of the material element and the structure element. In microdimension, the smaller the width and the bigger the spacing of the scale, the stronger the hydrophobicity of the wing surfaces. In nano-dimension, the smaller the height and the smaller the width and the bigger the spacing of the longitudinal ridge, the stronger the hydrophobicity of the wing surfaces. This work promotes our understanding of the hydrophobicity mechanism of bio-surfaces and may bring inspiration for biomimetic design and preparation of smart interfacial materials.展开更多
基金Supported by National Natural Science Foundation(10664001,41061039)National 863 Project(2007AA10Z205)+1 种基金Project for Excellent Young Scientists and Technicians of GuizhouNational Project for Innovative Experiments of College Students(Guizhou University200820)~~
文摘[Objective] The aim was to build spectral diagnosis model for nitrogen nutrition in rice leaf.[Method] Through determination of transmission,absorption spectra and nitrogen content on rice leaves of different rice varieties(Xiangyou 109 and Shanyou 98),different growth periods and different nitrogen levels,we analyzed the correlation between leaf spectra and their nitrogen contents,and built prediction model of spectral index for nitrogen content in rice leaf.[Result] The detection precision of this model was above 80% that can be used on diagnosing of rice nitrogen nutrition.[Conclusion] The study provided evidence for monitoring nitrogen nutrition status of rice.
基金provided by the Special Funds for the Major State Basic Research Project(No.2006CB202200)the Innovative Team Development Project of the state Educational Ministry of China(No.IRT0656)
文摘This paper presents an overview of experimental investigations conducted at China University of Mining and Technology Beijing(CUMTB) on roadway excavation using large-scale geomechanical model tests.The simulated sedimentary rocks are composed by alternating layers of sandstone, mudstone and coal seam inclined at varied angles with respect to the horizontal including 0°, 45°, 60°, and 90°. During the excavation, infrared thermography was employed to detect the thermal response of the surrounding rocks under excavation. The obtained raw thermograms were processed using denoising algorithm, data reduction procedure and Fourier analysis. The infrared temperature(IRT) characterizes the overall rock response; the processed thermal images represent the structural behavior, and the Fourier spectrum describes damage development in the frequency domain. Deeper understanding was achieved by the comparative analyses of excavation in differently inclined rock masses using the image features of IRTs, thermal images and Fourier spectra.
基金Project(KLUEH201302) supported by Funded by the Key Laboratory of Urban Environment and Health,Institute of Urban Environment,Chinese Academy of SciencesProject(51004053) supported by the National Natural Science Foundation of China+2 种基金Project(3502Z20116008) supported by the Science and Technology Research Project of Xiamen City,ChinaProject(JA11146) supported by the Program for Fostering Distinguished Young Scholars in University of Fujian Province,ChinaProject(2011B003) supported by the Foundation for Young Professors of Jimei University,China
文摘Four types of common seaweeds(Laminaria japonica,Undaria pinnatifida,Porphyra haitanensis,and Gracilaria lemaneiformis) were examined to remove Cr(Ⅵ) ions from aqueous solution.The experimental parameters that affected the biosorption process including pH,biomass dosage,contact time and temperature were investigated via batch experiments.The surface characteristics of seaweeds before and after Cr(Ⅵ) adsorption were studied with scanning electron microscopy and Fourier transform infrared spectroscopy.The results show that an initial solution with the pH of 1.0 is most favorable for Cr(Ⅵ) adsorption.Rapid adsorption is observed in the initial stage and adsorption equilibrium state is reached within 1 h.The adsorption efficiency by Porphyra haitanensis is the maximum among four types of seaweed powders,followed by Laminaria japonica and Undaria pinnatifida with biosorption efficiency up to 90%.The removal rate of Gracilaria lemaneiformis is less than 60%.The kinetic data obtained using the seaweeds are found to follow pseudo-second order kinetic model.Experimental sorption data adequately correlate with the Langmuir model.FTIR indicates that amino and carboxyl groups play an important role in the process of Cr(Ⅵ) adsorption and a large percentage of Cr(Ⅵ) ions are reduced by reductive groups on the surface of seaweeds.
基金Supported by Research Funds from Chinese Education Department (2003406)Bureau of Science and Technology of Jiangsu Province (BG2006025)
文摘A series of tungsten-substituted molybdophosphoric acids(H3PMo12-nWnO40·xH2O) were synthesized and characterized by inductive coupled plasma atomic emission spectroscopy(ICPAES),thermal gravimetry and differential scanning calorimetry(TG-DSC),Fourier transform infrared spectroscopy(FTIR),X-ray diffraction(XRD),and FTIR pyridine adsorption.The as-prepared heteropoly acids have a Keggin type structure.The synthesis of tetrahydrofuran by reactive distillation and cyclodehydration of 1,4-butanediol was studied using the tungsten-substituted molybdophosphoric acids as catalysts.The results of catalytic test indicated that the catalytic activity increased with the increase in the substitution number(n) of tungsten atom in H3PMo12-nWnO40·xH2O and was constant as the substitution number(n) was more than 8.The catalytic activity increased with the increase in the catalyst loading and the selectivity of tetrahydrofuran was nearly 100%.
文摘The family of Cr(Ⅲ) and Fe(Ⅲ)-doped rutile pigments of nominal composition (M^ⅢM^V)xTi1-2xO2, with M^Ⅲ = Cr(Ⅲ) or Fe(Ⅲ) and M'(V) = Sb, Nb, Ta, with x = 0.03, 0.15 and 0.25 were investigated as ceramic pigments covering the yellow-ochre-brown palette. The formulations containing Fe(Ⅲ) are novel compositions not included in the commercial rutile pigments. The materials were characterized by XRD (X-ray diffraction) analysis and FTIR (Fourier transformed infrared spectroscopy). The transition temperature from anatase-to-rutile was estimated by the evolution of the spectral patterns. This crystal phase transition is responsible of the color formation. A higher distortion of TiO6 octahedra is observed in the case of (FeSb) containing cells which contribute to the enhancement of the light absorption. The coloring performance of all the formulations were evaluated by enameling the mixtures containing 5% pigments and commercial frits representative of single and double firing industrial processes. The chromatic values obtained are in the yellow to brown domain of the chromatic plot, depending on the composition of the pigment-frit batch. In the case of the Fe-glazes, and particularly the combination (FeNb), the chromatic values are close to the best yellow tinting. This new FeNb-rutile pigment could be a more benign substitute of Cr-yellow pigments. The homogeneity of the enamels was confirmed by SEM (scanning electron microscopy)-EDAX (energy dispersive X-ray analysis) microscopy.
文摘A novel metal-free photocatalyst--sulfur/graphene (S/GR) composite--has been synthesized using a facile one-pot, two-step hydrothermal method with thiosulfate and graphene oxide (GO) as precursors. A green reductant--L-ascorbic add--was used to transform GO to GR under mild conditions. The photocatalyst powders were characterized by Fourier transform infrared spectroscop, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy. Experimental tests were conducted on the photocatalytic decomposition of methyl orange (MO) by different catalysts. Compared to pure oL-S, the as-prepared S/GR composite showed much enhanced photocatalytic activity for the degradation of MO under both UV and solar light. The presence of GR also greatly increased the hydrophilicity and adsorption capacity of the catalyst material. The results indicate that the incorporation of GR with a-S results in a synergistic effect for the S-based photocatalysts offering more effective environmental applications.
基金supported by the National Natural Science Foundation of China(Grant Nos. 40571115 and 40271078)the National Hi-Tech Research and Development Program of China(Grant No. 2006AA10Z203)
文摘Hyperspectral reflectance (350-2500 nm) measurements were made over two experimental rice fields containing two cultivars treated with three levels of nitrogen application.Four different transformations of the reflectance data were analyzed for their capability to predict rice biophysical parameters,comprising leaf area index (LAI;m-2 green leaf area m-2 soil) and green leaf chlorophyll density (GLCD;mg chlorophyll m 2 soil),using stepwise multiple regression (SMR) models and support vector machines (SVMs).Four transformations of the rice canopy data were made,comprising reflectances (R),first-order derivative reflectances (D1),second-order derivative reflectances (D2),and logarithm transformation of reflectances (LOG).The polynomial kernel (POLY) of the SVM using R was the best model to predict rice LAI,with a root mean square error (RMSE) of 1.0496 LAI units.The analysis of variance kernel of SVM using LOG was the best model to predict rice GLCD,with an RMSE of 523.0741 mg m-2.The SVM approach was not only superior to SMR models for predicting the rice biophysical parameters,but also provided a useful exploratory and predictive tool for analyzing different transformations of reflectance data.
基金supported by the National Natural Science Foundation of China(50875108)the Natural Science Foundation of Jilin Province,China(201115162)the Open Fundof Key Laboratory of Bionic Engineering of Ministry of Education,Jilin University(K201004)
文摘The microstructure, wettability and chemical composition of the butterfly wing surfaces were investigated by a scanning electron microscope, a contact angle meter and a Fourier transform infrared spectrometer. The micro/nano structural models for hydrophobicity of the butterfly wing surfaces were established on the basis of the Cassie equation. The hydrophobicity mechanisms were discussed from the perspective of biological coupling. The butterfly wing surfaces are composed of naturally hydrophobic material and possess micro/nano hierarchical structures, including primary structure (micrometric scales), secondary structure (nano longitudinal ridges and lateral bridges) and tertiary structure (nano stripes). The wing surfaces exhibit high hydrophobicity (contact angle 138°-157°) and low adhesion (sliding angle 1°-3°). The micromorphology and self-cleaning performance of the wing surfaces demonstrate remarkable anisotropism. The special complex wettability ascribes to a coupling effect of the material element and the structure element. In microdimension, the smaller the width and the bigger the spacing of the scale, the stronger the hydrophobicity of the wing surfaces. In nano-dimension, the smaller the height and the smaller the width and the bigger the spacing of the longitudinal ridge, the stronger the hydrophobicity of the wing surfaces. This work promotes our understanding of the hydrophobicity mechanism of bio-surfaces and may bring inspiration for biomimetic design and preparation of smart interfacial materials.