bis(azidomethyl) 3,3′ bis(1,2,4 oxadiazole)(Ⅰ) and bis(azidoacetamino) oxazofurazan(Ⅱ) were synthesized. The structures of these two compounds have been identified by IR, 1H NMR, MS and elemental analy...bis(azidomethyl) 3,3′ bis(1,2,4 oxadiazole)(Ⅰ) and bis(azidoacetamino) oxazofurazan(Ⅱ) were synthesized. The structures of these two compounds have been identified by IR, 1H NMR, MS and elemental analysis. Azido groups were introduced into furazan derivatives and energetic materials of high nitrogen content and high enthalpy of formation can be obtained. The densities of compound Ⅰ and Ⅱ are relatively high. Compound Ⅰ is an azide of lower melting point, it is hopeful to be applied as energetic plastic additives.展开更多
The bonding interface of 7B52 Al alloy laminated composite （ALC） fabricated by hot rolling was investigated using optical microscopy （OM）, transmission electron microscopy （TEM）, scanning electron microscopy （...The bonding interface of 7B52 Al alloy laminated composite （ALC） fabricated by hot rolling was investigated using optical microscopy （OM）, transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, ultrasonic flaw detection （UFD）, and bonding strength tests. The results show that metallurgical bonding is achieved at the interface after composite rolling. The TEM analysis and tensile tests indicate that the 7B52 ALC plate combines high strength of the hard individual layer and good toughness of the soft individual layer. However, UFD technology and SEM analysis prove that the defects （thick oxide films, acid washed residues, air, oil and coarse particles） existing in the bonding interface are harmful to the bonding strength. To sum up, the composite roiling process is suitable for 7B52 ALC plate, and the content and size of the defects should be controlled strictly. Advanced surface treatment of each individual layer would be beneficial to further improve the bonding quality.展开更多
QCr0.8 was electron-beam welded to TC4 and the effect of the intermetallic layer （IMC-layer） on the mechanical properties of the joint was investigated. The IMC-layers are joint weaknesses at the Cu fusion line in c...QCr0.8 was electron-beam welded to TC4 and the effect of the intermetallic layer （IMC-layer） on the mechanical properties of the joint was investigated. The IMC-layers are joint weaknesses at the Cu fusion line in centered welding and at the Ti fusion line when the beam is deviated towards Cu. A new method referred to as electron-beam superposition welding was presented, and the optimal welding sequence was considered. The IMC-layer produced by centered welding was fragmented and remelted during Cu-side non-centered welding, giving a finely structured compound layer and improved mechanical properties of the joint. The tensile strength of joint is 276.0 MPa, 76.7% that of the base metal.展开更多
金属飞轮功率密度大,可靠性高,是我国推广飞轮储能技术应用的重要途径。本文综合考虑应力强度、金属疲劳、储能总量、储能密度和加工工艺,依托有限元计算优化金属飞轮设计,以应对不同工况要求。飞轮材料选用35Cr Mo A,设计储能量大于20 ...金属飞轮功率密度大,可靠性高,是我国推广飞轮储能技术应用的重要途径。本文综合考虑应力强度、金属疲劳、储能总量、储能密度和加工工艺,依托有限元计算优化金属飞轮设计,以应对不同工况要求。飞轮材料选用35Cr Mo A,设计储能量大于20 k W·h。频繁充放电飞轮采用4倍安全系数,具备高可靠性;高速待机飞轮以疲劳极限强度作为设计准则,平衡储能量和寿命。计算对比发现,"哑铃"形截面有利于实现轻质量大转动惯量,相同储能量下降低轴承负荷。此外,文章依托模块化设计思想,提出叠层铆合飞轮设计,评估轴孔螺孔应力集中影响。上述讨论为低速大功率金属飞轮进一步设计和量产化提供了有力参考。展开更多
In order to establish the relationship between the measured dynamic response and the health status of long-span bridges, a double-layer model updating method for steel-concrete composite beam cable-stayed bridges is p...In order to establish the relationship between the measured dynamic response and the health status of long-span bridges, a double-layer model updating method for steel-concrete composite beam cable-stayed bridges is proposed. Measured frequencies are selected as the first-layer reference data, and the mass of the bridge deck, the grid density, the modulus of concrete and the ballast on the side span are modified by using a manual tuning technique. Measured global positioning system （GPS） data is selected as the second-layer reference data, and the degradation of the integral structure stiffness EI of the whole bridge is taken into account for the second-layer model updating by using the finite element iteration algorithm. The Nanpu Bridge in Shanghai is taken as a case to verify the applicability of the proposed model updating method. After the first-layer model updating, the standard deviation of modal frequencies is smaller than 7%. After the second-layer model updating, the error of the deflection of the mid-span is smaller than 10%. The integral structure stiffness of the whole bridge decreases about 20%. The research results show a good agreement between the calculated response and the measured response.展开更多
Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering condit...Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques.The results reveal that when the sintering temperature is above the melting point of aluminum,the self-propagating high-temperature synthesis reaction occurs between Ti and Al,and forms various phases of Ti-based solid solutions including α-Ti Ti3Al,TiAl,TiAl2 and α-Ti including TiAl3,etc.When the sintering time increased,Ti-based solid solution,TiAl2 and TiAl3 disappeared gradually,and the sheet containing Ti3Al and TiAl phases in a multilayered structure formed finally.A lot of voids were also observed in the sintered structures,which were caused by the melting Al,Kirkendall effect and the difference of molar volumes between reactants and products.The voids were eliminated and a dense sample was obtained by the following hot press.展开更多
Electrical properties of high quality ultra thin nitride/oxynitride(N/O)stack dielectrics pMOS capacitor with refractory metal gate electrode are investigated,and ultra thin (<2 nm) N/O stack gate dielectrics with ...Electrical properties of high quality ultra thin nitride/oxynitride(N/O)stack dielectrics pMOS capacitor with refractory metal gate electrode are investigated,and ultra thin (<2 nm) N/O stack gate dielectrics with significant low leakage current and high resistance to boron penetration are fabricated.Experiment results show that the stack gate dielectric of nitride/oxynitride combined with improved sputtered tungsten/titanium nitride (W/TiN) gate electrode is one of the candidates for deep sub-micron metal gate CMOS devices.展开更多
Tazobactam,β lactamase inhibitor, was synthesized from 6 aminopenicillanic acid through eleven steps, including diazotization, bromination, oxidation, chlorization, cyclization, deprotection and so on. The designed...Tazobactam,β lactamase inhibitor, was synthesized from 6 aminopenicillanic acid through eleven steps, including diazotization, bromination, oxidation, chlorization, cyclization, deprotection and so on. The designed route was examined, particularly the azide substitution and cyclization. In the latter reaction, vinyl acetic ester was employed in place of acetylene.展开更多
Bottom-simulating reflectors (BSRs) in seismic profile always indicate the bottom of gas hydrate stability zone, but is difficult to determine the distribution and features of gas hydrate sediments (GHS). In this stud...Bottom-simulating reflectors (BSRs) in seismic profile always indicate the bottom of gas hydrate stability zone, but is difficult to determine the distribution and features of gas hydrate sediments (GHS). In this study, based on AVA forward modeling and angle-domain common-image gathers we use prestack AVA parameters consistency inversion in predicting gas hydrate sediments in the Shenhu area at northern slope of South China Sea, and obtain the vertical and lateral features and saturation of GHS.展开更多
文摘bis(azidomethyl) 3,3′ bis(1,2,4 oxadiazole)(Ⅰ) and bis(azidoacetamino) oxazofurazan(Ⅱ) were synthesized. The structures of these two compounds have been identified by IR, 1H NMR, MS and elemental analysis. Azido groups were introduced into furazan derivatives and energetic materials of high nitrogen content and high enthalpy of formation can be obtained. The densities of compound Ⅰ and Ⅱ are relatively high. Compound Ⅰ is an azide of lower melting point, it is hopeful to be applied as energetic plastic additives.
基金Project(51312JQ08)supported by the Pre-Research Foundation of China General Equipment DepartmentProject(NBPJ2013-4)supported by the Postdoctoral Science Foundation of Ningbo Branch of China Academy of Ordnance Science+1 种基金Project(bsh1402073)supported by the Postdoctoral Science Foundation of Zhejiang Province,ChinaProject(2014A610051)supported by the Ningbo Natural Science Foundation of China
文摘The bonding interface of 7B52 Al alloy laminated composite （ALC） fabricated by hot rolling was investigated using optical microscopy （OM）, transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, ultrasonic flaw detection （UFD）, and bonding strength tests. The results show that metallurgical bonding is achieved at the interface after composite rolling. The TEM analysis and tensile tests indicate that the 7B52 ALC plate combines high strength of the hard individual layer and good toughness of the soft individual layer. However, UFD technology and SEM analysis prove that the defects （thick oxide films, acid washed residues, air, oil and coarse particles） existing in the bonding interface are harmful to the bonding strength. To sum up, the composite roiling process is suitable for 7B52 ALC plate, and the content and size of the defects should be controlled strictly. Advanced surface treatment of each individual layer would be beneficial to further improve the bonding quality.
基金Project (2010CB731704) supported by the National Basic Research Program of China
文摘QCr0.8 was electron-beam welded to TC4 and the effect of the intermetallic layer （IMC-layer） on the mechanical properties of the joint was investigated. The IMC-layers are joint weaknesses at the Cu fusion line in centered welding and at the Ti fusion line when the beam is deviated towards Cu. A new method referred to as electron-beam superposition welding was presented, and the optimal welding sequence was considered. The IMC-layer produced by centered welding was fragmented and remelted during Cu-side non-centered welding, giving a finely structured compound layer and improved mechanical properties of the joint. The tensile strength of joint is 276.0 MPa, 76.7% that of the base metal.
文摘金属飞轮功率密度大,可靠性高,是我国推广飞轮储能技术应用的重要途径。本文综合考虑应力强度、金属疲劳、储能总量、储能密度和加工工艺,依托有限元计算优化金属飞轮设计,以应对不同工况要求。飞轮材料选用35Cr Mo A,设计储能量大于20 k W·h。频繁充放电飞轮采用4倍安全系数,具备高可靠性;高速待机飞轮以疲劳极限强度作为设计准则,平衡储能量和寿命。计算对比发现,"哑铃"形截面有利于实现轻质量大转动惯量,相同储能量下降低轴承负荷。此外,文章依托模块化设计思想,提出叠层铆合飞轮设计,评估轴孔螺孔应力集中影响。上述讨论为低速大功率金属飞轮进一步设计和量产化提供了有力参考。
基金The Special Project of the Ministry of Construction ofChina (No.20060909).
文摘In order to establish the relationship between the measured dynamic response and the health status of long-span bridges, a double-layer model updating method for steel-concrete composite beam cable-stayed bridges is proposed. Measured frequencies are selected as the first-layer reference data, and the mass of the bridge deck, the grid density, the modulus of concrete and the ballast on the side span are modified by using a manual tuning technique. Measured global positioning system （GPS） data is selected as the second-layer reference data, and the degradation of the integral structure stiffness EI of the whole bridge is taken into account for the second-layer model updating by using the finite element iteration algorithm. The Nanpu Bridge in Shanghai is taken as a case to verify the applicability of the proposed model updating method. After the first-layer model updating, the standard deviation of modal frequencies is smaller than 7%. After the second-layer model updating, the error of the deflection of the mid-span is smaller than 10%. The integral structure stiffness of the whole bridge decreases about 20%. The research results show a good agreement between the calculated response and the measured response.
基金Project (2010DFA51650) supported by the Ministry of Science and Technology of China
文摘Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques.The results reveal that when the sintering temperature is above the melting point of aluminum,the self-propagating high-temperature synthesis reaction occurs between Ti and Al,and forms various phases of Ti-based solid solutions including α-Ti Ti3Al,TiAl,TiAl2 and α-Ti including TiAl3,etc.When the sintering time increased,Ti-based solid solution,TiAl2 and TiAl3 disappeared gradually,and the sheet containing Ti3Al and TiAl phases in a multilayered structure formed finally.A lot of voids were also observed in the sintered structures,which were caused by the melting Al,Kirkendall effect and the difference of molar volumes between reactants and products.The voids were eliminated and a dense sample was obtained by the following hot press.
文摘Electrical properties of high quality ultra thin nitride/oxynitride(N/O)stack dielectrics pMOS capacitor with refractory metal gate electrode are investigated,and ultra thin (<2 nm) N/O stack gate dielectrics with significant low leakage current and high resistance to boron penetration are fabricated.Experiment results show that the stack gate dielectric of nitride/oxynitride combined with improved sputtered tungsten/titanium nitride (W/TiN) gate electrode is one of the candidates for deep sub-micron metal gate CMOS devices.
文摘Tazobactam,β lactamase inhibitor, was synthesized from 6 aminopenicillanic acid through eleven steps, including diazotization, bromination, oxidation, chlorization, cyclization, deprotection and so on. The designed route was examined, particularly the azide substitution and cyclization. In the latter reaction, vinyl acetic ester was employed in place of acetylene.
文摘Bottom-simulating reflectors (BSRs) in seismic profile always indicate the bottom of gas hydrate stability zone, but is difficult to determine the distribution and features of gas hydrate sediments (GHS). In this study, based on AVA forward modeling and angle-domain common-image gathers we use prestack AVA parameters consistency inversion in predicting gas hydrate sediments in the Shenhu area at northern slope of South China Sea, and obtain the vertical and lateral features and saturation of GHS.
