Bimetallic CoCu nanocomposites were synthesized in polyol by using Ru as heterogeneous nucleation agent and stearic acid as surfactant, and their catalytic properties were investi- gated by hydrogenolysis of glycerol ...Bimetallic CoCu nanocomposites were synthesized in polyol by using Ru as heterogeneous nucleation agent and stearic acid as surfactant, and their catalytic properties were investi- gated by hydrogenolysis of glycerol to propanediols. It was found that the surfactant could induce Co nanocrystals to form nanowires as structure-directing agent, while it＇s ineffective for Cu because only spherical Cu particles were produced under the same condition. When Co2＋ and Cu2＋ coexist in polyol, Cu2＋ is firstly reduced and forms the spherical particles, and then the Cu particles afford surface for the subsequential reduction of Co2＋ and growth of Co nanocrystals to form the nanorods, obtaining the urchin-like CoCu nanocomposites. The catalytic performance in selective hydrogenolysis of glycerol to propanediols proposed that the CoCu urchin-like nanocomposites was superior to the Co nanowires possibly due to that the synergistic effect between Co and Cu component promoted conversion of glyc- erol and obtained the higher propanediol yields based on the specific surface areas of the catalysts.展开更多
The problem of joint eigenvalue estimation for the non-defective commuting set of matrices A is addressed. A procedure revealing the joint eigenstructure by simultaneous diagonalization of. A with simultaneous Schur d...The problem of joint eigenvalue estimation for the non-defective commuting set of matrices A is addressed. A procedure revealing the joint eigenstructure by simultaneous diagonalization of. A with simultaneous Schur decomposition （SSD） and balance procedure alternately is proposed for performance considerations and also for overcoming the convergence difficulties of previous methods based only on simultaneous Schur form and unitary transformations, it is shown that the SSD procedure can be well incorporated with the balancing algorithm in a pingpong manner, i. e., each optimizes a cost function and at the same time serves as an acceleration procedure for the other. Under mild assumptions, the convergence of the two cost functions alternately optimized, i. e., the norm of A and the norm of the left-lower part of A is proved. Numerical experiments are conducted in a multi-dimensional harmonic retrieval application and suggest that the presented method converges considerably faster than the methods based on only unitary transformation for matrices which are not near to normality.展开更多
By making use of the direct integration method,an exact analysis of the general three-dimensional thermoelasticity problem is performed for the case of a transversely isotropic homogeneous half-space subject to local ...By making use of the direct integration method,an exact analysis of the general three-dimensional thermoelasticity problem is performed for the case of a transversely isotropic homogeneous half-space subject to local thermal and force loadings.The material plane of isotropy is assumed to be parallel to the limiting surface of the halfspace.By reducing the original thermoelasticity equations to the governing ones for individual stress-tensor components,the effect of material anisotropy in the stress field is analyzed with regard to the feasibility requirement,i.e.,the finiteness of the stress field at a distance from the disturbed area.As a result,the solution is constructed in the form of explicit analytical dependencies on the force and thermal loadings for various kinds of transversely isotropic materials and agrees with the basic principles of the continua mechanics.The solution can be efficiently used as a benchmark one for the direct computation of temperature and thermal stresses in transversely isotropic semi-infinite domains,as well as for the verification of solutions constructed by different means.展开更多
Astrocytes have potential to break synchrony between neurons. Authors＇ recent researches reveal that astrocytes vary the synchronization threshold and provide an appropriate feedback control in stabilizing neural act...Astrocytes have potential to break synchrony between neurons. Authors＇ recent researches reveal that astrocytes vary the synchronization threshold and provide an appropriate feedback control in stabilizing neural activities. In this study, we propose an astrocyte-inspired controller for desynchronization of two coupled limit-cycle oscillators as a minimal network model. The design procedure consists of two parts. First, based on the astrocyte model, the structure of the dynamic controller is suggested. Then, to have an emcient controller, parameters of controller are tuned through an optimization algo- rithm. The proposed bio-inspired controller takes advantages of three important proper- ties： （1） the controller desynchronizes the oscillators without any undesirable effects （e.g. stopping, annihilating or starting divergent oscillations）; （2） it consumes little effort to preserve the desirable desynchronized state; and （3） the controller is robust with respect to parameters＇ variations. Simulation results reveal the ability of the proposed controller.展开更多
基金This work was supported by the National Ba- sic Research Program of China （No.2012CB215304）, tile Science Foundation of Guangdong Province （No.$2012040006992）, and the International Co- operation Project of Ministry of Science and Technology of China （No.2012DFA61080）.
文摘Bimetallic CoCu nanocomposites were synthesized in polyol by using Ru as heterogeneous nucleation agent and stearic acid as surfactant, and their catalytic properties were investi- gated by hydrogenolysis of glycerol to propanediols. It was found that the surfactant could induce Co nanocrystals to form nanowires as structure-directing agent, while it＇s ineffective for Cu because only spherical Cu particles were produced under the same condition. When Co2＋ and Cu2＋ coexist in polyol, Cu2＋ is firstly reduced and forms the spherical particles, and then the Cu particles afford surface for the subsequential reduction of Co2＋ and growth of Co nanocrystals to form the nanorods, obtaining the urchin-like CoCu nanocomposites. The catalytic performance in selective hydrogenolysis of glycerol to propanediols proposed that the CoCu urchin-like nanocomposites was superior to the Co nanowires possibly due to that the synergistic effect between Co and Cu component promoted conversion of glyc- erol and obtained the higher propanediol yields based on the specific surface areas of the catalysts.
基金The National Natural Science Foundation of China(No.60572072,60496311),the National High Technology Researchand Development Program of China (863Program ) ( No.2003AA123310),the International Cooperation Project on Beyond 3G Mobile of China (No.2005DFA10360).
文摘The problem of joint eigenvalue estimation for the non-defective commuting set of matrices A is addressed. A procedure revealing the joint eigenstructure by simultaneous diagonalization of. A with simultaneous Schur decomposition （SSD） and balance procedure alternately is proposed for performance considerations and also for overcoming the convergence difficulties of previous methods based only on simultaneous Schur form and unitary transformations, it is shown that the SSD procedure can be well incorporated with the balancing algorithm in a pingpong manner, i. e., each optimizes a cost function and at the same time serves as an acceleration procedure for the other. Under mild assumptions, the convergence of the two cost functions alternately optimized, i. e., the norm of A and the norm of the left-lower part of A is proved. Numerical experiments are conducted in a multi-dimensional harmonic retrieval application and suggest that the presented method converges considerably faster than the methods based on only unitary transformation for matrices which are not near to normality.
基金supported by Joint Fund of Advanced Aerospace Manufacturing Technology Research(No. U1937601)the partial financial support of this research by the budget program of Ukraine“Support for the Development of Priority Research Areas”(No.CPCEC 6451230)。
文摘By making use of the direct integration method,an exact analysis of the general three-dimensional thermoelasticity problem is performed for the case of a transversely isotropic homogeneous half-space subject to local thermal and force loadings.The material plane of isotropy is assumed to be parallel to the limiting surface of the halfspace.By reducing the original thermoelasticity equations to the governing ones for individual stress-tensor components,the effect of material anisotropy in the stress field is analyzed with regard to the feasibility requirement,i.e.,the finiteness of the stress field at a distance from the disturbed area.As a result,the solution is constructed in the form of explicit analytical dependencies on the force and thermal loadings for various kinds of transversely isotropic materials and agrees with the basic principles of the continua mechanics.The solution can be efficiently used as a benchmark one for the direct computation of temperature and thermal stresses in transversely isotropic semi-infinite domains,as well as for the verification of solutions constructed by different means.
文摘Astrocytes have potential to break synchrony between neurons. Authors＇ recent researches reveal that astrocytes vary the synchronization threshold and provide an appropriate feedback control in stabilizing neural activities. In this study, we propose an astrocyte-inspired controller for desynchronization of two coupled limit-cycle oscillators as a minimal network model. The design procedure consists of two parts. First, based on the astrocyte model, the structure of the dynamic controller is suggested. Then, to have an emcient controller, parameters of controller are tuned through an optimization algo- rithm. The proposed bio-inspired controller takes advantages of three important proper- ties： （1） the controller desynchronizes the oscillators without any undesirable effects （e.g. stopping, annihilating or starting divergent oscillations）; （2） it consumes little effort to preserve the desirable desynchronized state; and （3） the controller is robust with respect to parameters＇ variations. Simulation results reveal the ability of the proposed controller.
