合成气压缩机汽轮机耗汽高的原因与对策

根据合成气压缩机汽轮机设计参数和实际运行工况量化分析该汽轮机耗汽超标的原因 ,提出解决问题的设想以及在设备改造前通过优化操作减少蒸汽消耗的措施 。

高纯元素合成碘化汞及其单晶的生长

研究了“真空冷指升华法”制备高纯碘 (I2 ) ;采用“三温区汽相合成法”将高纯汞 (Hg)与高纯碘合成碘化汞(Hg I2 ) ;α- Hg I2 单晶的“三温区定点成核法”的汽相生长 .分析讨论了温度场对晶体生长的影响 .实验结果表明 :汞与碘合成时对碘源区、汞源区、碘化汞沉积区分别设置成不同的合适温度 ,在合成时碘的量比按化学配比的计算值过量 5 %左右 ,且在长晶时对原料进行碘处理的方法能确保 Hg I2 的纯度及汞与碘的最佳化学比 .长晶时源区温度在 12 5～ 12 6℃ ,长晶区温度在 111～ 112℃ ,源区与长晶区的温度梯度为 1℃ / cm 。

NHD脱硫脱碳装置有关问题的探讨

介绍NHD脱硫脱碳的优越性以及生产中存在的问题，分析了问题的原因，结合生产实践经验，提出解决问题的办法。运行表明，效果良好。

A facile solvent-free synthesis strategy for Co-imbedded zeolite-based Fischer-Tropsch catalysts for direct gasoline production

A series of Co-imbedded zeolite-based catalysts were synthesized following a facile solvent-free grinding route.The catalytic performance for direct syngas conversion to gasoline range hydrocarbons was compared with their counterpart Co-impregnated zeolite-based catalysts.Successful transformation of solid raw materials to targeted zeolite was confirmed by XRD,SEM,STEM,and N2 physisorption analysis.An in-depth study of acidic strength and acidic site distribution was conducted by NH3-TPD and Py-IR spectroscopy.Acidic strength showed a pivotal role in defining product range.Co@S1,with the weakest acidic strength of silicalite-1 among three types of zeolites,evaded over-cracking of product and exhibited the highest gasoline and isoparaffin selectivity(≈70%and 30.7%,respectively).Moreover,the solvent-free raw material grinding route for zeolite synthesis accompanies several advantages like the elimination of production of wastewater,high product yield within confined crystallization space,and elimination of safety concerns regarding high pressure due to the absence of the solvent.Facileness and easiness of the solvent-free synthesis route together with promising catalytic performance strongly support its application on the industrial scale.

Synthesis of Hyperbranched Polymers and Its Effect on Water Vapor Permeability of Microfiber Synthetic Leather

A series of hyperbranched poly(amine-ester)polyols were synthesized by the polycondensation of N,N-diethylol-3-amine-methylpropionate(prepared by Michael addition reaction of methyl acrylate with diethanolamine)as an AB2-type monomer with trimethylol propane as the core moiety,proceeding in one-step procedure in the melt with p-toluenesulfonic acid as catalyst.The obtained monomer and polymers were characterized by FTIR and 1H-NMR spectroscopy.The solubility and surface activity in aqueous solution of the polymers were also examined.The gas permeability,water vapor permeability,and moisture absorption of microfiber synthetic leather treated by hyperbranched polymer were studied.The optimum conditions were that the dosage of dye and hyperbranched polymer was 5% and 10%,respectively.The water vapor permeability and moisture absorption of microfiber synthetic leather reached to 0.525 4 mg/(10 cm2·24 h)and 0.046 7 mg/(10 cm2·24 h).Compared with blank samples,they increased by 15% and 35%,respectively.However,the dosage of hyperbranched polymer has little influence on gas permeability of microfiber synthetic leather.SEM results show that the fiber of microfiber synthetic leather treated by hyperbranched polymer is incompact.

Pore-mouth catalysis boosting the formation of iso-paraffins from syngas over bifunctional catalysts

Recent studies confirm that the emerging bifunctional catalysts consisting of metal oxide and zeolites can directly convert syngas into high-quality gasoline,however,the formation mechanism of iso-paraffins and the difference with the conventional FT/zeolite catalyst have not been investigated.Herein,three one-dimensional SAPO zeolites with diverse micropore sizes were synthesized and assembled with ZnAlO_(x)with spinel structure.It was found that ZnAlO_(x)/SAPO-41 and ZnAlO_(x)/SAPO-11 with medium micropore sizes favored the formation of C_(5)–C_(11)hydrocarbons with a high content of iso-paraffins.The characterizations pointed out that the formation of iso-paraffins over SAPO-11 followed a pore-mouth catalysis mechanism,which means the isomerization of linear hydrocarbons can only take place near the pore mouth region of zeolites.This mechanism only allows the formation of mono-branched iso-paraffins in the C_(5)–C_(11)range,which are less prone to be cracked than their di-branched isomers.A careful comparative analysis between ZnAlO_(x)/SAPO-11 and Co/H-meso-ZSM-5 was also made in terms of product distribution,activity,and stability.

Effect of alloy composition and heat treatment on mechanical performance of 6xxx aluminum alloys

The effect of alloy composition and heat treatment, including natural ageing and pre-ageing, on the mechanical performance of eight 6xxx alloys designed with systematically varying Si, Mg and Cu contents was studied. The results show that not only the alloy composition and heat treatment before forming influence the formability, but also they have an effect on the paint bake response of the alloys. Increasing the alloy Si content, decreasing Mg/Si ratio and adding 0.3% Cu （mass fraction） were generally found to improve the tensile ductility and formability of the alloys studied, while pre-ageing was found to decrease these properties. A full property profile of these alloys in terms of strength, tensile ductility, work hardening, strain rate sensitivity, forming limit and paint bake response was presented.

Determination of Air/Fuel and Steam/Fuel Ratio for Coal Gasification Process to Produce Synthesis Gas

In this study, a coal gasification model is developed based on nine simultaneous reactions. For given gasification temperature and pressure, the air/fuel and water vapor/fuel ratio are optimized for maximum H2/CO ratio by parametric study. Furthermore, the cold gas efficiency and higher heating value of the synthesis gas produced are computed for each case. Optimum locations of investigated parameters are also searched for maximizing cold gas efficiency and higher heating value of the synthesis gas.

Application of new VBHF optimization strategy to improve formability of automobile panels with aluminum alloy sheet

A VBHF(Variable Blank Holder Force) optimization strategy was employed to determine the optimal time-variable and spatial-variable BHF trajectories,aiming at improving the formability of automobile panels with aluminum alloy sheet.The strategy was implemented based on adaptive simulation to calculate the critical wrinkling BHF for each segmented binder of the Numisheet' 05 deck lid in a single round of simulation.The thickness comparison of the stamped part under optimal VBHF and constant BHF shows that the variance of the four sections is decreased by 70%,44%,64% and 61%,respectively,which indicates significant improvement in thickness distribution and variation control.The investigation through strain path comparison reveals the fundamental reason of formability improvement.The study proves the applicability of the new VBHF optimization strategy to complex parts with aluminum alloy sheet.

Forming analysis and application for aluminum-alloy material

The increase in car ownership brought about by energy shortages,and environmental crises became more acute.The most effective way to achieve energy saving and emission reduction of car is to improve engine efficiency.In addition to that,lightweight body is the key.Aluminum,magnesium alloy as significant materials of lightweight,and the application amount in the car body is a significant upward trend.However,there is high cost of material,with immature applied technology and a series of bottleneck problems.All of them affect general application of lightweight materials. This paper focuses on forming process issues for aluminum,magnesium alloy and the solutions to achieve.

Development and experimental validation of a novel hybrid powertrain with dual planetary gear sets for transit bus applications

Given that energy conservation and environmental protection are two important goals for the automotive industry, the application of a hybrid electric powertrain can improve vehicle energy efficiency while decreasing fuel consumption and engine emissions. Planetary gear-based power-split hybrid powertrains have become widely used in passenger vehicles, but remain rarely employed on transit buses. This study proposes a novel hybrid powertrain based on two planetary gear sets(CHS) and presents its operating principles along with development of a control strategy for the powertrain. The CHS hybrid powertrain operates in electric mode when the driving power demand is low, and changes to a hybrid electric mode according to the power-split principle of the planetary gear set. To validate the feasibility of the designed CHS hybrid powertrain, a prototype transit bus equipped with the designed hybrid powertrain system was built, and the operating characteristics of the system were analyzed through a performance test conducted on a chassis dynamometer. Compared with a conventional powertrain, the CHS hybrid powertrain can reduce fuel consumption by 39%. Thus, the CHS hybrid powertrain is a good solution for heavy-duty applications such as hybrid transit buses because of its simple structure and excellent fuel efficiency.