盐穴储气库泥岩夹层渗透性测试新方法

金坛盐穴储气库现场压井试验发现某泥岩夹层密封性欠佳,可能影响储气库运行的密闭性,钻井取芯情况表明,该夹层易破碎,难以开展系统的渗透性测试试验。针对该问题,提出了一种测试易碎泥岩夹层渗透率的新方法,将泥岩夹层岩芯浇筑在环氧树脂中,通过切割打磨等工序制备出符合渗透试验要求的标准试样。为了观测泥岩夹层岩芯与环氧树脂的胶结情况,对人工合成试样进行了镀金电镜扫描试验,发现交界面孔隙较岩石孔隙小、胶结良好,说明夹层岩芯是人工合成试样中的主要渗透通道。利用稳态法对人工合成试样进行渗透率测试,测试结果与其他学者的测试结果吻合,证实了该方法的可靠性。同时开展了理论分析,结果表明,浇筑式方法测得的渗透率与理论结果相符,从理论上进一步证实了其可行性。文中所述的泥岩夹层渗透性测试方法,对测试不规则破碎岩芯的渗透率具有一定参考意义。

双指示剂-催化光度法同时测定痕量铜和铁的研究

研究了在盐酸介质中，痕量铜和铁对过氧化氢氧化甲基橙和煌焦油蓝反应的催化作用。基于两种指示剂催化反应的差异，提出了双指示剂催化光度法同时测量痕量铜和铁的新方法，并用于合成试样和铝合金样中痕量铜和铁的测定．

Joint member angle limits of composite beams and CFT square columns

This work aims to understand the relationship between the member angle limit and the energy ratio for 24 test samples of composite beams and CFT square steel tube columns. This work also compares the formula applicability for member angle limit with the previous test result to provide the basic data for the design of composite beam-CFT column. The evaluation of the member angle limit was performed with concrete compressive strength (fC =22.16 MPa, 30.49 MPa), breadth-to-thickness ratio (B/t=25.0, 33.3, 43.5), and axial capacity ratio (N/N0=0, 0.3, 0.4, 0.5) as the main variables of the test samples. For the relationship between the member angle limit (Ru) and the energy ratio (ES/EC ), the test result shows that the energy ratio becomes lower as the axial capacity ratio and the breadth-to-thickness ratio increase. The energy ratio is lower for the Type B test sample compared with that of Types A and C. For the formula suggested by SATO, the test samples are distributed evenly for comparison between test values and the member angle limit; however, other formulas indicate a deviation. Specifically, for the comparison between R u,cal and R u (Test), Maeda's formula shows severe deviation.