基于SEDRIS的虚拟试验合成环境建模技术研究

为解决虚拟试验中合成环境数据的统一描述和可交互问题,在分析了合成环境数据表示与转换标准SEDRIS的基础上,对大气、红外、电磁环境建模,并对得到的环境数据进行统一格式的转换,提出了一种基于SEDRIS标准的虚拟试验合成环境建模技术,开发了虚拟试验合成环境原型系统和大气环境可视化,实现了大气、红外、电磁及混合模式等4种试验环境条件下对产品性能的验证与评估;试验结果表明,建立的环境模型具有良好的交互性,建模方法可应用于多种试验环境的描述,为虚拟试验合成环境模型体系、标准规范和辅助工具的形成打下了基础。

汉语文语转换系统NLG-TTS的设计与实现

该文介绍了一个实用的汉语文语转换系统NLG-TTS.该系统的输入为自然汉语文本,对输入文本进行规格化处理和分词处理之后,根据汉语语言学规则对文本进行音位和韵律标注;系统选用汉语有调音节和常用词为语音合成基元,音元数据的压缩选用矢量和激励线性预测(VSELP)算法;NLG-TTS合成语音的实验试听效果良好.

浅析Motion Control系统合成技术

MOCO系统是一种高科技交互式摄影控制系统,可以同时同步控制摄影机拍摄物、灯光等的运动路线及拍摄底片的速度。本文重点介绍了MOCO系统的合成技术,包括运动轨迹的无限次重复拍摄、空间坐标系转换合成、变速合成等。

MXene quantum dots of Ti_(3)C_(2):Properties,synthesis,and energy-related applications

The emerging two-dimensional MXene-derived quantum dots(MQDs)have garnered considerable research interest owing to their abundant active edge atoms,excellent electrical conductivity,and remarkable optical properties.Compared with their two-dimensional(2D)counterpart MXene,MQDs with forceful size and quantum confinement effects exhibit more unparalleled properties and have considerably contributed to the advanced photocatalysis,detection,energy storage,and biomedicine fields.This critical review summarizes the fundamental properties of MQDs in terms of structure,electricity,and optics.The mechanism,characteristics,and comparisons of two typical synthesis strategies(traditional chemical method and novel fluorine-free or chemical-free method)are also presented.Furthermore,the similarities and differences between MQDs and 2D MXenes are introduced in terms of their functional groups,light absorption capacity,energy band structure,and other properties.Moreover,recent advances in the applications of MQD-based materials for energy conversion and storage(ECS)are discussed,including photocatalysis,batteries,and supercapacitors.Finally,current challenges and future opportunities for advancing MQD-based materials in the promising ECS field are presented.

Synthesis of indirect work exchange networks considering both isothermal and adiabatic process together with exergy analysis

In this paper, an efficient methodology for synthesizing the indirect work exchange networks(WEN) considering isothermal process and adiabatic process respectively based on transshipment model is first proposed. In contrast with superstructure method, the transshipment model is easier to obtain the minimum utility consumption taken as the objective function and more convenient for us to attain the optimal network configuration for further minimizing the number of units. Different from division of temperature intervals in heat exchange networks,different pressure intervals are gained according to the maximum compression/expansion ratio in consideration of operating principles of indirect work exchangers and the characteristics of no pressure constraints for stream matches. The presented approach for WEN synthesis is a linear programming model applied to the isothermal process, but for indirect work exchange networks with adiabatic process, a nonlinear programming model needs establishing. Additionally, temperatures should be regarded as decision variables limited to the range between inlet and outlet temperatures in each sub-network. The constructed transshipment model can be solved first to get the minimum utility consumption and further to determine the minimum number of units by merging the adjacent pressure intervals on the basis of the proposed merging methods, which is proved to be effective through exergy analysis at the level of units structures. Finally, two cases are calculated to confirm it is dramatically feasible and effective that the optimal WEN configuration can be gained by the proposed method.

Study of seismic spectrum decomposition based on CEEMD

Empirical mode decomposition( EMD) is a powerful tool of time-frequency analysis. EMD decomposes a signal into a series of sub-signals,called Intrinsic mode functions( IMFs). Each IMF contains different frequency components which can deal with the nonlinear and non-stationary of signal. Complete ensemble empirical mode decomposition( CEEMD) is an improved algorithm,which can provide an accurate reconstruction of the original signal and better spectral separation of the modes. The authors studied the decomposition result of a synthetic signal obtained from EMD and CEEMD. The result shows that the CEEMD has suitability in spectrum decomposition time-frequency analysis. Compared with traditional methods,a higher time-frequency resolution is obtained through verifying the method on both synthetic and real data.

Effective Response of Nonlinear Composite under External AC and DC Electric Field

A perturbation method is used to study effective response of nonlinear Kerr composites, which are subject to the constitutive relation of electric displacement and electric field, Dα=εαE＋xα｜E｜^2E. Under the external AG and DC electric field Eapp = Eα（1 ＋ sinωt）, the effective nonlinear responses and local potentials are induced by the cubic nonlinearity of Kerr materials at all harmonics. As an example in three dimensions, we have investigated this kind of nonlinear composites with spherical inclusions embedded in a host. At all harmonic frequencies, the potentials in inclusion and host regions are derived. Furthermore, the formulae of the effective linear and nonlinear responses are given in the dilute Iimit.

The effect of transition metal ions (M^(2+)=Mn^(2+),Ni^(2+),Co^(2+),Cu^(2+)) on the chemical synthesis polyaniline as counter electrodes in dye-sensitized solar cells

The effect of transition metal ions(M^(2+)=Mn^(2+),Ni^(2+),Co^(2+),Cu^(2+)) on the chemical synthesis of polyaniline(PANI) used as a platinum-free counter electrode(CE) in dye-sensitized solar cells(DSSCs) was investigated.PANI was synthesized by co-polymerization of aniline in the presence of different transition metal ions by using potassium dichromate in acidic medium. It was found that the ion doping of PANI showed a certain catalytic activity for the regeneration of traditional iodide/triiodide(I^-/I_3^-) redox couples. The power conversion efficiency(η) of PANI CEs doped with Mn^(2+),Ni^(2+),Co^(2+) (4.41%, 2.36% and 2.10%, respectively) were higher than 1.94%, the value measured for PANI CE without doping. Doping with Cu^(2+)decreased the power conversion efficiency of PANI CE(PANI-Cu^(2+) η = 1.41%). The electrical properties of the PANI, PANI-Ni^(2+), PANI-Co^(2+),PANI-Mn^(2+) and PANI-Cu^(2+) were studied by cyclic voltammetry(CV), impedance(EIS), and Tafel polarization curve. The experimental results confirmed that PANI was affected by the doping of different transition metal ions(M^(2+)=Mn^(2+),Ni^(2+),Co^(2+),Cu^(2+)). These results indicate a potential application of ion doped PANI as counter electrode in cost-effective DSSCs.

Mosaic of the Curved Human Retinal Images Based on the Scale-Invariant Feature Transform

To meet the needs in the fundus examination,including outlook widening,pathology tracking,etc.,this paper describes a robust feature-based method for fully-automatic mosaic of the curved human retinal images photographed by a fundus microscope. The kernel of this new algorithm is the scale-,rotation-and illumination-invariant interest point detector & feature descriptor-Scale-Invariant Feature Transform. When matched interest points according to second-nearest-neighbor strategy,the parameters of the model are estimated using the correct matches of the interest points,extracted by a new inlier identification scheme based on Sampson distance from putative sets. In order to preserve image features,bilinear warping and multi-band blending techniques are used to create panoramic retinal images. Experiments show that the proposed method works well with rejection error in 0.3 pixels,even for those cases where the retinal images without discernable vascular structure in contrast to the state-of-the-art algorithms.

N,N-二甲基甲酰胺: 一个多用途的有机合成试剂

发展简单有效的方法从价廉易得的原料制备各种功能有机分子一直是合成化学领域追求的目标之一.N,N-二甲基甲酰胺(DMF)是常见的、优良的极性非质子溶剂,也是一种重要的工业原料和多功能合成反应试剂.从羰基化、甲酰化、氨基化、氨甲酰化及提供碳源、氢源和氧源几个方面综述DMF作为多功能合成反应试剂的最新进展.

Semiconductor nanowires for photovoltaic and photoelectrochemical energy conversion

Semiconductor nanowires （NW） possess several beneficial properties for efficient conversion of solar energy into electricity and chemical energy. Due to their efficient absorption of light, short distances for minority carriers to travel, high surface-to-volume ratios, and the availability of scalable synthesis methods, they provide a pathway to address the low cost-to-power requirements for widescale adaptation of solar energy conversion technologies. Here we highlight recent progress in our group towards implementation of NW components as photovoltaic and photoelectrochemical energy conversion devices. An emphasis is placed on the unique properties of these one-dimensional （1D） structures, which enable the use of abundant, low-cost materials and improved energy conversion efficiency compared to bulk devices.

Monodisperse Upconversion NaYF4 Nanocrystals： Syntheses and Bioapplications

A facile strategy using cheap and readily available precursors has been successfully developed for the synthesis of rare-earth doped hexagonal phase NaYF4 nanocrystals with uniform shape and small particle size as well as strong photoluminescence. Due to their optical properties and good biocornpatibility, these multicolor nanocrystals were successfully used as a bio-tag for cancer cell imaging. This novel synthetic method should also be capable of extension to the synthesis of other fluoride nanocrystals such as YF3 and LaF3.

BCCIPβ modulates the ribosomal and extraribosomal function of S7 through a direct interaction

Extraribosomal functions of ribosomal proteins （RPs） have gained much attention for their implications in tumorigenesis and pro- gression. However, the regulations for transition between the ribosomal and extraribosomal functions of RPs are rarely reported. Herein, we identified a ribosomal protein S7-interacting partner, BCCIPβ, which modulates the functional conversion of S7. Through the N-terminal acidic domain, BCCIPβ interacts with the central basic region in S7 and regulates the extraribosomal dis- tribution of S7. BCCIPI~ deficiency abrogates the ribosomal accumulation but enhances the ribosome-free location of S7. This translocation further impairs protein synthesis and triggers ribosomal stress. Consequently, BCCIPβ deficiency suppresses the ribosomal function and initiates the extraribosomal function of S7, resulting in restriction of cell proliferation. Moreover, clinically relevant S7 mutations were found to dampen the interaction with BCCIPβ and facilitate the functional transition of S7. In conclu- sion, BCCIPβ, as a S7 modulator, contributes to the regulation of ribosomal and extraribosomai functions of S7 and has implica- tions in cell growth and tumor development.

PhI(OAc)2-promoted umpolung acetoxylation of enamides for the synthesis of α-acetoxy ketones

Umpolung is a fundamental concept in organic chemistry, which provides an alternative strategy for the synthesis of target compounds which were not easily accessible by conventional methods. Herein, a mild and efficient PhI(OAc)_2-promoted umpolung acetoxylation reactions of enamides was developed for the synthesis of α-acetoxy ketones. The reaction tolerates a wide range of functional groups and affords α-acetoxy ketones in good to excellent yields. PhI(OAc)_2 serves as a source of acetoxy in the reaction.

Synthesis of two-dimensional π-conjugated polymers pendent with benzothiadiazole and naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole moieties for polymer solar cells

Four new 2D donor–acceptor conjugated polymers were designed and synthesized.These new polymers comprised fluorenealt-triphenylamine or carbazole-alt-triphenylamine as the backbones,and pendants with 2,1,3-benzothiadiazole(BT)or naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole(NT)in a triphenylamine unit as the side groups.By changing the acceptor BT for a stronger electron-withdrawing unit of NT moiety in the side chain,the energy levels,absorption spectra,band gaps,and charge-transport abilities of the resultant polymers could be effectively tuned.Bulk heterojunction solar cells with these polymers as the electron donors and(6,6)-phenyl-C71-butyric acid methyl ester as the electron acceptor exhibited high open-circuit voltage(more than 0.8 e V).The power conversion efficiency can be improved from 1.37%to 3.52%by replacing the BT with an NT moiety,which indicates that introducing NT as the side-chain building block can be an effective strategy to construct efficient 2D conjugated polymers for PSCs.