Agricultural cooperative economic organization for water-saving irrigation in arid areas is a new form of economic organization in production,operation and management during the application process of water-saving irr...Agricultural cooperative economic organization for water-saving irrigation in arid areas is a new form of economic organization in production,operation and management during the application process of water-saving irrigation technologies.Currently,there are few researches on this cooperative economic organization.In this study,connotations of cooperative economic organizations for water-saving irrigation are specifically defined,and the characteristics and functions of this cooperative economic organization are analyzed.Based on that,several suggestions are proposed on the continuous development of cooperative economic organizations for water-saving irrigation.展开更多
Self assembled monolayers (SAMs) of 1-tetradecylphosphonic acids (TDPA, CH3(CH2)13P(O)(OH)2 ) were formed on the 2024 aluminum alloy surface in TDPA-containing ethanol-water solutions with different water co...Self assembled monolayers (SAMs) of 1-tetradecylphosphonic acids (TDPA, CH3(CH2)13P(O)(OH)2 ) were formed on the 2024 aluminum alloy surface in TDPA-containing ethanol-water solutions with different water content. The adsorption and corrosion protection properties of the SAMs for 2024 alloy in 0.1 mol/L H2SO4 solution were examined and characterized by potentiodynamic polarization, electrochemical impedance spectrum (EIS), Fourier transformed infrared spectroscopy (FTIR), Auger electron spectra (AES) and atomic force microscopy (AFM). FTIR and AES results show that the TDPA molecules were successfully adsorbed on the 2024 aluminum alloy surface, and the density of the SAMs increased with the increasing water content in the assembly solution. The results of electrochemical studies and corrosion morphologies observed by AFM show that a 4 h modification resulted in maximal inhibition efficiency, and the higher the water content in the assembly solution is, the better the inhibition performance of the SAMs can be achieved. The effect of water content in TDPA solutions on the performance of the SAMs is related to the hydration reaction of the metal surface.展开更多
Three-layer composite ingot of 4045/3004/4045 aluminum alloys was prepared by direct-chill semi-continuous casting process,the temperature field distribution near the composite interface,macro-morphology,microstructur...Three-layer composite ingot of 4045/3004/4045 aluminum alloys was prepared by direct-chill semi-continuous casting process,the temperature field distribution near the composite interface,macro-morphology,microstructure and composition distribution of the composite interface were investigated.The results show that semi-solid layer with a certain thickness forms near the interface due to the effect of cooling plate,which ensures successful implementation of casting the composite ingot.Two different aluminum alloys are well bonded metallurgically.The mechanical properties of composite interface were measured,the tensile and shearing strengths of composite interface are 105 and 88 MPa,respectively,which proves that the composite interface is a kind of metallurgical bonding.展开更多
This paper reports the measurements of enthalpies of natural gas hydrates in typical natural gas mixture containing methane, ethane, propane and iso-butane at pressure in the vicinity of 2000 kPa (300 psi) and 6900 kP...This paper reports the measurements of enthalpies of natural gas hydrates in typical natural gas mixture containing methane, ethane, propane and iso-butane at pressure in the vicinity of 2000 kPa (300 psi) and 6900 kPa(1000psi). The measurements were made in a multi-cell differential scanning calorimeter using modified high pressure cells. The enthalpy of water and the enthalpy of dissociation of the gas hydrate were determined from the calorimeter response during slow temperature scanning at constant pressure. The amount of gas released from the dissociation of hydrate was determined from the pumped volume of the high pressure pump. The occupation ratio (mole ratio) of the water to gas and the enthalpy of hydrate formation are subject to uncertainty of 1.5%.The results show that the enthalpy of hydrate formation and the occupation ratio are essentially independent of pressure.展开更多
The hybrid flow shop scheduling problem with unrelated parallel machine is a typical NP-hard combinatorial optimization problem, and it exists widely in chemical, manufacturing and pharmaceutical industry. In this wor...The hybrid flow shop scheduling problem with unrelated parallel machine is a typical NP-hard combinatorial optimization problem, and it exists widely in chemical, manufacturing and pharmaceutical industry. In this work, a novel mathematic model for the hybrid flow shop scheduling problem with unrelated parallel machine(HFSPUPM) was proposed. Additionally, an effective hybrid estimation of distribution algorithm was proposed to solve the HFSPUPM, taking advantage of the features in the mathematic model. In the optimization algorithm, a new individual representation method was adopted. The(EDA) structure was used for global search while the teaching learning based optimization(TLBO) strategy was used for local search. Based on the structure of the HFSPUPM, this work presents a series of discrete operations. Simulation results show the effectiveness of the proposed hybrid algorithm compared with other algorithms.展开更多
The almost completely dense copper was prepared by ultrafine copper powder prepared with both methods of electrolysis and novel water-gas atomization through cold isostatic pressing(CIP)and sintering under atmospheric...The almost completely dense copper was prepared by ultrafine copper powder prepared with both methods of electrolysis and novel water-gas atomization through cold isostatic pressing(CIP)and sintering under atmospheric hydrogen.Fine copper powder possesses the higher sintering driving force,thereby promoting shrinkage and densification during the sintering process.The grain size of sintered samples by electrolytic copper powder is smaller than that prepared by the atomized copper powder,and the twin crystals are particularly prone to forming in the former sintered microstructure due to the raw powder with low oxygen content and high residual stress originating from the CIP process.The relative density of samples by electrolytic and atomized powder at 1000℃ sintering temperature achieves 99.3%and 97.4%,respectively,significantly higher than that of the powder metallurgy copper parts reported in the literature.Correspondingly,the ultimate tensile strength and yield strength of samples by both kinds of copper powder are approximately similar,while the elongation of the sintered sample by the electrolytic powder(60%)is apparently higher than the atomized powder(44%).The superior performance of samples fabricated by electrolytic powder is inferred from the full density and low oxygen level for there is no cuprous oxide in the grain boundaries.展开更多
With the increase of petroleum and gas production in deep ocean, marine risers of circular cylinder shape are widely used in the offshore oil and gas platform. In order to research the hydrodynamic performance of mari...With the increase of petroleum and gas production in deep ocean, marine risers of circular cylinder shape are widely used in the offshore oil and gas platform. In order to research the hydrodynamic performance of marine risers, the dynamic mesh technique and User-Defined Function(UDF) are used to simulate the circular cylinder motion. The motion of a transversely oscillating circular cylinder in combination of uniform flow and oscillating flow is simulated. The uniform flow and oscillating flow both are in x direction. SIMPLE algorithm is used to solve the Navier-Stokes equations. The User-Defined Function is used to control the cylinder transverse vibration and the inlet flow. The lift and drag coefficient changing with time and the map of vorticity isolines at different phase angle are obtained. Force time histories are shown for uniform flow at Reynolds number(Re) of 200 and for the combination of uniform and oscillating flows. With the increase of amplitude of oscillating flow in combined flow, the change of lift amplitude is not sensitive to the the change of cylinder oscillating frequency. Lift amplitude increases with the increase of oscillating flow amplitude in the combined flow, but there is no definite periodicity of the lift coefficient. The drag and inertia force coefficients change when the maximum velocity of the oscillating flow increases in the combined flow. The vortex shedding near the circular cylinder shows different characteristics.展开更多
Cu-0.36 wt.%Be-0.46 wt.%Co alloy plate with 300 mm in width and 10 mm in thickness prepared by heating-cooling combined mold(HCCM) horizontal continuous casting was cold rolled. Microstructure evolution and mechanical...Cu-0.36 wt.%Be-0.46 wt.%Co alloy plate with 300 mm in width and 10 mm in thickness prepared by heating-cooling combined mold(HCCM) horizontal continuous casting was cold rolled. Microstructure evolution and mechanical properties of the alloy as well as its deformation mechanism were investigated. The results showed that the as-cast alloy plate had columnar grains along the length direction, good surface quality and elongation of 35%, which was directly large-reduction cold rolled without surface treatment, and the accumulative cold rolling reduction reached 98%. When the reduction was small(20%), numerous dislocations and dislocation cells formed, and the deformation mechanism was dislocation slip. When the reduction was 40%, deformation twins appeared, and interactions between twins and dislocation cells induced strip-like dislocation cells. When the reduction exceeded 60%, shear bands formed and apparent crystal rotation in the micro-region happened. Further increasing the reduction, the amount of the shear bands rose and they interacted with each other, which refined the grains apparently. The tensile strength and hardness increased from 353 MPa and HV 119 of the as-cast alloy to 625 MPa and HV 208 with 95% reduction, respectively, and the elongation reduced from 35% to 7.6%. A process of HCCM horizontal continuous casting-cold rolling can work as a novel compact method to fabricate Cu-Be alloy sheet.展开更多
In order to improve the load capacity, seismic performance and performance-cost ratio of the columns, the concrete at the base of reinforced concrete (RC) columns is substituted with engineered cementitious composit...In order to improve the load capacity, seismic performance and performance-cost ratio of the columns, the concrete at the base of reinforced concrete (RC) columns is substituted with engineered cementitious composites (ECC) to form ECC/RC composite columns. Based on the existing material properties, the mechanical behaviors of the ECC columns, ECC/RC composite columns and RC columns were numerically studied under combined vertical and horizontal loading with the software of ATENA. Then, the failure mechanism of ECC columns and ECC/RC composite columns were comprehensively studied and compared with that of the RC columns. Then, the effects of the height of the ECC, the axial compression ratio, and the transverse reinforcement ratio on the mechanical behaviors of the composite or the ECC column are studied. The calculation results show that the ultimate load capacity, ductility and crack resistance of the ECC or ECC/RC composite columns are superior to those of the RC columns. The ECC/RC composite column with a height of the ECC layer of 1.2h ( h is the height of the cross section) can achieve similar mechanical properties of a full ECC column. With high shear strength, ECC can undertake the shear force and significantly reduce the amount of stirrups, avoiding construction issues and promoting its engineering application.展开更多
An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that t...An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.展开更多
Objective To compare the characterization and myocardial differentiation capacity of arnniotic fluid-derived mesenchymal stromal cells (AF MSCs) and umbilical cord Wharton's Jelly-derived mesenchymal stromal cells ...Objective To compare the characterization and myocardial differentiation capacity of arnniotic fluid-derived mesenchymal stromal cells (AF MSCs) and umbilical cord Wharton's Jelly-derived mesenchymal stromal cells (WJ MSCs). Methods The human AF MSCs were cultured from amniotic fluid samples obtained by amniocentesis. The umbilical cord WJ MSCs were obtained from Wharton's Jelly of umbilical cords of infants delivered full-term by normal labor. The morphology, growth curves, and analyses by flow cytometry of cell surface markers were compared between the two types of cells. Myocardial genes (GATA-4, c-TnT, a-actin, and Cx43) were detected by real-time PCR and the corresponding protein expressions were detected by Western blot analysis after myocardial induced in AF MSCs and WJ MSCs. Results Our findings revealed AF MSCs and WJ MSCs shared similar morphological characteristics of the fibroblastoid shape. The AF MSCs were easily obtained than the WJ MSCs and had a shorter time to reach adherence of 2.7 ± 1.6 days to WJ MSCs of 6.5 ± 1.8 days. The growth curves by MTT cytotoxic assay showed the AF MSCs had a similar proliferative capacity at passage 5 and passage 10. However, the proliferative capacities ofWJ MSCs were decreased at 5 passage relative to 10 passage. Both AF stem cells and WJ stem cells had the characteristics of mesenchymal stromal cells with some characteristics of embryonic stem cells. They express CD29 and CD105, but not CD34. They were positive for Class I major histocompatibility (MHC I) antigens (HLA-ABC), and were negative, or mildly positive, for MHC Class II (HLA-DR) antigen. Oct-4 was positive in all the two cells types. Both AF MSCs and WJ MSCs could differentiate along myocardium. The differentiation capacities were detected by the expression of GATA-4, c-TnT, a-actin, Cx43 after myocardial induction. Conclusions Both AF MSCs and WJ MSCs have the potential clinical application for myogenesis in cardiac regenerative therapy.展开更多
[Objective] The paper was to analyze lizi synoptic meteorology of 13 rain- storm processes during the flood season of Hunan Province in 2010. [Method] Using the principle of lizi synoptic meteorology, 13 regional rain...[Objective] The paper was to analyze lizi synoptic meteorology of 13 rain- storm processes during the flood season of Hunan Province in 2010. [Method] Using the principle of lizi synoptic meteorology, 13 regional rainstorm weather processes occurred in Hunan Province in 2010 were analyzed. [Result] Thirteen rainstorms are all closely related to self-organization convergent airflow, rainstorm is the inevitable result after the outbreak of self-organization convergent airflow. The inoculation area of self-organization convergent airflow is accorded with the occurrence area of rain- storm in the next 12-36 h; once the inoculation area of self-organization convergent airflow disappears, there will be no regional rainstorm in the next 12-36 h; the inoc- ulation area of self-organization convergent airflow is produced in the convergence domain of large scale of southern and northern lizi pair. [Conclusion] The existence of southern and northern lizi pair can be used as the short-term forecast model of regional rainstorm during flood season.展开更多
Our study group has developed a unique combined ters from the industries of dyestuff, pharmaceutical, chemical biological technology to treat high-strength organic wastewaengineering and zymolysis by using the princip...Our study group has developed a unique combined ters from the industries of dyestuff, pharmaceutical, chemical biological technology to treat high-strength organic wastewaengineering and zymolysis by using the principles of anaerobic ecological niche and bio-phase separation. The study obtained five national invention patents and eight patent equipments. This technology contains four kernel processes - two-phase anaerobic-aerobic process, hydrolysis-acidification-oxidation process, UASBAF-oxidation process, and internal cycling-hydrolysis-oxidation process. Fifteen pilot projects were accomplished in the basins of Tai Lake, Huai River, Liao River and Songhua River, and their total capital investment reached 185.214 million Yuan (RMB). Compared to conventional wastewater treatment technology, the innovative technology is more costeffective for high-strength organic wastewater treatment, can save capital investment by 15% - 30%, lessen land usage by 20% to 40% and decrease the operating cost by 10% to 25%. The operating cost of treatment per cubic meter industrial wastewater could be below 0.6 to 1.4 Yuan (RMB).展开更多
To solve the problem of vast cement and low strength in the treated sludge, clay mineral used for accessorial solidification material was applied to advance strength. The principle of solidification sludge strength be...To solve the problem of vast cement and low strength in the treated sludge, clay mineral used for accessorial solidification material was applied to advance strength. The principle of solidification sludge strength because of clay mineral is not clear and has not supported the choice of clay mineral. The mineral and pore water is analyzed in order to contrast clay mineral added or not based on the XRD and pore water chemical character. The result shows that the absorbed quantity of Ca2~ was reduced by sludge because of clay mineral added, the hydrated reaction was advanced and integrated solidified materials was formed.展开更多
In the near future, fresh water will be very difficult to get and scarce. It is said that in 2025 half of the mankind will live in the areas where fresh water is not enough. Also, UN and WMO (World Meteorological Org...In the near future, fresh water will be very difficult to get and scarce. It is said that in 2025 half of the mankind will live in the areas where fresh water is not enough. Also, UN and WMO (World Meteorological Organization) are predicting five billion people will be in short of even drinking water. Also, in the present, there are some areas where sea water or chloride contained sand are used as mixing water with or without intension. The authors believe that the possibilities of using sea water as mixing water in concrete should be investigated seriously. In this paper, the authors would like to show various possibilities of using sea water as mixing water in RC (reinforced concrete) members. The possibilities are shown as follows: (1) mixed with pozzolanic materials (Blast furnace slag powder, etc.) expecting to fix the free chloride ion; (2) Mixed with corrosion inhibitor; (3) reinforced with stainless steel or corrosion resistant reinforcement; and (4) used in very dry or submerged conditions.展开更多
Sulpho-aluminate expansive cementitious composite is proved to be one of the most effective ways to prevent concrete cracking too soon. Mix design of sulpho-aluminate expansive cementitious composite completely depend...Sulpho-aluminate expansive cementitious composite is proved to be one of the most effective ways to prevent concrete cracking too soon. Mix design of sulpho-aluminate expansive cementitious composite completely depends on experience and experiments at present. This method ignores the influence of expansion behavior which hinders the application of sulpho-aluminate expansive cementitious composite. The workability,free expansion property,flexural strength and compressive strength of sulpho-aluminate expansive cementitious composite have been investigated by tests. The relationship between expansion ratio and mix design parameters such as curing age,water-cement ratio and cement abundance coefficient is deduced according to the experimental statistics. A new simplified approach to mix design of sulpho-aluminate expansive cementitious composite is proposed as a reference for construction application,which avoids experiments and experience.展开更多
The five chemical associations of heavy metals have been extracted continuously using the Tessier extracting method. Results show that Cu, Pb, Fe, Zn and Cr in the sediments are mainly distributed in residual fraction...The five chemical associations of heavy metals have been extracted continuously using the Tessier extracting method. Results show that Cu, Pb, Fe, Zn and Cr in the sediments are mainly distributed in residual fraction, while the major chemical association of Mn is carbonates. Carbonate heavy metals are converted into Fe-Mn oxides in autumn. And in the low tidal flat, after carbonates have changed into ionic heavy metals, some of the elements are transported to the overlying water. Cu, Pb, Fe and Mn have good correlations with each other, and Zn, Cr also show their similarity of chemical behavior in the sediments.展开更多
Fish assemblage structure in the hypoxic zone in the Changjiang (Yangtze River) estuary and its adjacent waters were analyzed based on data from bottom trawl surveys conducted on the R/V Beidou in June, August and Oct...Fish assemblage structure in the hypoxic zone in the Changjiang (Yangtze River) estuary and its adjacent waters were analyzed based on data from bottom trawl surveys conducted on the R/V Beidou in June, August and October 2006. Four fish assemblages were identified in each survey using two-way indicator species analysis (TWIA). High fish biomass was found in the northern part, central part and coastal waters of the survey area; in contrast, high fish diversity was found in the southern part of the survey area and the Changjiang estuary outer waters. Therefore, it is difficult to maintain high fishery production when high fish diversity is evenly distributed in the fish community. Fish became smaller and fish size spectra tended to be narrower because of fish species variations and differences in growth characteristics. Fish diversity increased, the age to maturity was reduced and some migrant species were not collected in the surveys. Fish with low economic value, small size, simple age structure and low tropic level were predominant in fish assemblages in the Changjiang estuary and its adjacent waters. The lowest hypoxic value decreased in the Changjiang estuary and its adjacent waters.展开更多
AIM: To investigate the expression levels of lymphatic vessel endothelial hyaluronan receptor-1 (LYVE-1), vascular endothelial growth factor receptor-3 (VEGFR-3) and CD44 genes and the relationship between their lev- ...AIM: To investigate the expression levels of lymphatic vessel endothelial hyaluronan receptor-1 (LYVE-1), vascular endothelial growth factor receptor-3 (VEGFR-3) and CD44 genes and the relationship between their lev- els and clinicopathological parameters in gastric cancer.METHODS: Tissue samples were obtained from 33 patients (8 females) with gastric cancer. mRNA levels of LYVE-1, VEGFR-3 and CD44 in normal and tumor tissues were quantitatively measured using real time polymerase chain reaction. The results were correlated with lymph node metastasis, histological type and differentiation of the tumor, T-stage, and presence of vascular, perineural and lymphatic invasions. The distribution of molecules in the tissue was evaluated using immunohistochemistry. RESULTS: LYVE-1, CD44 and VEGFR-3 gene expression levels were significantly higher in gastric cancer than in normal tissue. While there was no correlation between gene expressions and clinicopathologic fea- tures such as histologic type, differentiation and stage, gene expression levels were found to be increased in conjunction with positive lymph node/total lymph node ratio and the presence of perineural invasion. A significant correlation was also found between LYVE-1 and CD44 over-expressions and perineural invasion and lymph node positivity in gastric cancers. When the dis- tribution of LYVE-1 antibody-stained lymphatic vessels in tissue was evaluated, lymphatic vessels were located intra-tumorally in 13% and peri-tumorally in 27% of the patients. Moreover, lymph node metastases were also positive in all patients with LYVE-1-staining. CONCLUSION: LYVE-1, VEGFR-3 and CD44 all play an important role in lymphangiogenesis, invasion and metastasis. LYVE-1 is a perfectly reliable lymphatic vessel marker and useful for immunohistochemistry.展开更多
Nutrition plays an essential role in normal linear growth in children. Knowledge of the eating styles and dietary consumption of healthy short children from developed countries is scarce. The aim of this study was to ...Nutrition plays an essential role in normal linear growth in children. Knowledge of the eating styles and dietary consumption of healthy short children from developed countries is scarce. The aim of this study was to investigate the dietary patterns in idiopathic short stature (ISS) and relatively low weight children compared to children with normal stature and weight. This research is a case-control study of 86 pre-pubertal healthy children, mean age 5.9 ± 1.5 years. The study group comprised 43 ISS children; 43 age-matched children with normal stature and weight served as controls. Outcome measures included: dietary patterns and physical activity. The absolute daily average energy, protein and carbohydrate intake was significantly lower in the ISS children (P 〈 0.05); after correcting for body surface area, no significant differences were found between groups. Intake of micronutrients calcium, iron, zinc, vitamin A and vitamin C, expressed as percentage from Recommended Dietary Allowance, was significantly lower in the ISS children (P 〈 0.05), who had lower food responsiveness, higher satiety responsiveness, lesser enjoyment of food and were slower eaters (P 〈 0.001). Physical activity was sedentary in both the ISS cases and controls. Our findings in healthy, pre-pubertal, relatively lean ISS children point to a distinct eating pattern with no alteration in physical activity. Understanding the differences in dietary intake and eating behaviors may be beneficial in the development of targeted nutritional intervention for lean ISS children.展开更多
基金Supported by National Science and Technology Support Program(2007BAD38B09)~~
文摘Agricultural cooperative economic organization for water-saving irrigation in arid areas is a new form of economic organization in production,operation and management during the application process of water-saving irrigation technologies.Currently,there are few researches on this cooperative economic organization.In this study,connotations of cooperative economic organizations for water-saving irrigation are specifically defined,and the characteristics and functions of this cooperative economic organization are analyzed.Based on that,several suggestions are proposed on the continuous development of cooperative economic organizations for water-saving irrigation.
基金Project(Q20120110)supported by Youth Foundation of Hubei Provincial Education Bureau,ChinaProject(2009CDB347)supported by the Hubei Provincial Natural Science Foundation,ChinaProject(51001045)supported by the National Natural Science Foundation of China
文摘Self assembled monolayers (SAMs) of 1-tetradecylphosphonic acids (TDPA, CH3(CH2)13P(O)(OH)2 ) were formed on the 2024 aluminum alloy surface in TDPA-containing ethanol-water solutions with different water content. The adsorption and corrosion protection properties of the SAMs for 2024 alloy in 0.1 mol/L H2SO4 solution were examined and characterized by potentiodynamic polarization, electrochemical impedance spectrum (EIS), Fourier transformed infrared spectroscopy (FTIR), Auger electron spectra (AES) and atomic force microscopy (AFM). FTIR and AES results show that the TDPA molecules were successfully adsorbed on the 2024 aluminum alloy surface, and the density of the SAMs increased with the increasing water content in the assembly solution. The results of electrochemical studies and corrosion morphologies observed by AFM show that a 4 h modification resulted in maximal inhibition efficiency, and the higher the water content in the assembly solution is, the better the inhibition performance of the SAMs can be achieved. The effect of water content in TDPA solutions on the performance of the SAMs is related to the hydration reaction of the metal surface.
基金Project (2005CB623707) supported by the National Basic Research Program of China
文摘Three-layer composite ingot of 4045/3004/4045 aluminum alloys was prepared by direct-chill semi-continuous casting process,the temperature field distribution near the composite interface,macro-morphology,microstructure and composition distribution of the composite interface were investigated.The results show that semi-solid layer with a certain thickness forms near the interface due to the effect of cooling plate,which ensures successful implementation of casting the composite ingot.Two different aluminum alloys are well bonded metallurgically.The mechanical properties of composite interface were measured,the tensile and shearing strengths of composite interface are 105 and 88 MPa,respectively,which proves that the composite interface is a kind of metallurgical bonding.
文摘This paper reports the measurements of enthalpies of natural gas hydrates in typical natural gas mixture containing methane, ethane, propane and iso-butane at pressure in the vicinity of 2000 kPa (300 psi) and 6900 kPa(1000psi). The measurements were made in a multi-cell differential scanning calorimeter using modified high pressure cells. The enthalpy of water and the enthalpy of dissociation of the gas hydrate were determined from the calorimeter response during slow temperature scanning at constant pressure. The amount of gas released from the dissociation of hydrate was determined from the pumped volume of the high pressure pump. The occupation ratio (mole ratio) of the water to gas and the enthalpy of hydrate formation are subject to uncertainty of 1.5%.The results show that the enthalpy of hydrate formation and the occupation ratio are essentially independent of pressure.
基金Projects(61573144,61773165,61673175,61174040)supported by the National Natural Science Foundation of ChinaProject(222201717006)supported by the Fundamental Research Funds for the Central Universities,China
文摘The hybrid flow shop scheduling problem with unrelated parallel machine is a typical NP-hard combinatorial optimization problem, and it exists widely in chemical, manufacturing and pharmaceutical industry. In this work, a novel mathematic model for the hybrid flow shop scheduling problem with unrelated parallel machine(HFSPUPM) was proposed. Additionally, an effective hybrid estimation of distribution algorithm was proposed to solve the HFSPUPM, taking advantage of the features in the mathematic model. In the optimization algorithm, a new individual representation method was adopted. The(EDA) structure was used for global search while the teaching learning based optimization(TLBO) strategy was used for local search. Based on the structure of the HFSPUPM, this work presents a series of discrete operations. Simulation results show the effectiveness of the proposed hybrid algorithm compared with other algorithms.
基金Project(92066205)supported by the National Natural Science Foundation of ChinaProject(2019-Z10)supported by the State Key Lab for Advanced Metals and Materials of ChinaProject(FRF-MP-20-52)supported by the Fundamental Research Funds for the Central Universities,China。
文摘The almost completely dense copper was prepared by ultrafine copper powder prepared with both methods of electrolysis and novel water-gas atomization through cold isostatic pressing(CIP)and sintering under atmospheric hydrogen.Fine copper powder possesses the higher sintering driving force,thereby promoting shrinkage and densification during the sintering process.The grain size of sintered samples by electrolytic copper powder is smaller than that prepared by the atomized copper powder,and the twin crystals are particularly prone to forming in the former sintered microstructure due to the raw powder with low oxygen content and high residual stress originating from the CIP process.The relative density of samples by electrolytic and atomized powder at 1000℃ sintering temperature achieves 99.3%and 97.4%,respectively,significantly higher than that of the powder metallurgy copper parts reported in the literature.Correspondingly,the ultimate tensile strength and yield strength of samples by both kinds of copper powder are approximately similar,while the elongation of the sintered sample by the electrolytic powder(60%)is apparently higher than the atomized powder(44%).The superior performance of samples fabricated by electrolytic powder is inferred from the full density and low oxygen level for there is no cuprous oxide in the grain boundaries.
基金supported financially by the Natural Science Foundation of China (No. 51079136/51179179/51239008)
文摘With the increase of petroleum and gas production in deep ocean, marine risers of circular cylinder shape are widely used in the offshore oil and gas platform. In order to research the hydrodynamic performance of marine risers, the dynamic mesh technique and User-Defined Function(UDF) are used to simulate the circular cylinder motion. The motion of a transversely oscillating circular cylinder in combination of uniform flow and oscillating flow is simulated. The uniform flow and oscillating flow both are in x direction. SIMPLE algorithm is used to solve the Navier-Stokes equations. The User-Defined Function is used to control the cylinder transverse vibration and the inlet flow. The lift and drag coefficient changing with time and the map of vorticity isolines at different phase angle are obtained. Force time histories are shown for uniform flow at Reynolds number(Re) of 200 and for the combination of uniform and oscillating flows. With the increase of amplitude of oscillating flow in combined flow, the change of lift amplitude is not sensitive to the the change of cylinder oscillating frequency. Lift amplitude increases with the increase of oscillating flow amplitude in the combined flow, but there is no definite periodicity of the lift coefficient. The drag and inertia force coefficients change when the maximum velocity of the oscillating flow increases in the combined flow. The vortex shedding near the circular cylinder shows different characteristics.
基金Project(2016YFB0301404)supported by the National Key R&D Program of China。
文摘Cu-0.36 wt.%Be-0.46 wt.%Co alloy plate with 300 mm in width and 10 mm in thickness prepared by heating-cooling combined mold(HCCM) horizontal continuous casting was cold rolled. Microstructure evolution and mechanical properties of the alloy as well as its deformation mechanism were investigated. The results showed that the as-cast alloy plate had columnar grains along the length direction, good surface quality and elongation of 35%, which was directly large-reduction cold rolled without surface treatment, and the accumulative cold rolling reduction reached 98%. When the reduction was small(20%), numerous dislocations and dislocation cells formed, and the deformation mechanism was dislocation slip. When the reduction was 40%, deformation twins appeared, and interactions between twins and dislocation cells induced strip-like dislocation cells. When the reduction exceeded 60%, shear bands formed and apparent crystal rotation in the micro-region happened. Further increasing the reduction, the amount of the shear bands rose and they interacted with each other, which refined the grains apparently. The tensile strength and hardness increased from 353 MPa and HV 119 of the as-cast alloy to 625 MPa and HV 208 with 95% reduction, respectively, and the elongation reduced from 35% to 7.6%. A process of HCCM horizontal continuous casting-cold rolling can work as a novel compact method to fabricate Cu-Be alloy sheet.
基金The National Natural Science Foundation of China(No.51278118)the Natural Science Foundation of Jiangsu Province(No.BK2012756)the Key Project of Ministry of Education of China(No.113029A)
文摘In order to improve the load capacity, seismic performance and performance-cost ratio of the columns, the concrete at the base of reinforced concrete (RC) columns is substituted with engineered cementitious composites (ECC) to form ECC/RC composite columns. Based on the existing material properties, the mechanical behaviors of the ECC columns, ECC/RC composite columns and RC columns were numerically studied under combined vertical and horizontal loading with the software of ATENA. Then, the failure mechanism of ECC columns and ECC/RC composite columns were comprehensively studied and compared with that of the RC columns. Then, the effects of the height of the ECC, the axial compression ratio, and the transverse reinforcement ratio on the mechanical behaviors of the composite or the ECC column are studied. The calculation results show that the ultimate load capacity, ductility and crack resistance of the ECC or ECC/RC composite columns are superior to those of the RC columns. The ECC/RC composite column with a height of the ECC layer of 1.2h ( h is the height of the cross section) can achieve similar mechanical properties of a full ECC column. With high shear strength, ECC can undertake the shear force and significantly reduce the amount of stirrups, avoiding construction issues and promoting its engineering application.
基金Supported by the Key Program of National Natural Science Foundation of China(50736001) the National High Technology Research and Development Program of China(2006AA09A209-5) the Major State Basic Research Development Program of China(2009CB219507)
文摘An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.
文摘Objective To compare the characterization and myocardial differentiation capacity of arnniotic fluid-derived mesenchymal stromal cells (AF MSCs) and umbilical cord Wharton's Jelly-derived mesenchymal stromal cells (WJ MSCs). Methods The human AF MSCs were cultured from amniotic fluid samples obtained by amniocentesis. The umbilical cord WJ MSCs were obtained from Wharton's Jelly of umbilical cords of infants delivered full-term by normal labor. The morphology, growth curves, and analyses by flow cytometry of cell surface markers were compared between the two types of cells. Myocardial genes (GATA-4, c-TnT, a-actin, and Cx43) were detected by real-time PCR and the corresponding protein expressions were detected by Western blot analysis after myocardial induced in AF MSCs and WJ MSCs. Results Our findings revealed AF MSCs and WJ MSCs shared similar morphological characteristics of the fibroblastoid shape. The AF MSCs were easily obtained than the WJ MSCs and had a shorter time to reach adherence of 2.7 ± 1.6 days to WJ MSCs of 6.5 ± 1.8 days. The growth curves by MTT cytotoxic assay showed the AF MSCs had a similar proliferative capacity at passage 5 and passage 10. However, the proliferative capacities ofWJ MSCs were decreased at 5 passage relative to 10 passage. Both AF stem cells and WJ stem cells had the characteristics of mesenchymal stromal cells with some characteristics of embryonic stem cells. They express CD29 and CD105, but not CD34. They were positive for Class I major histocompatibility (MHC I) antigens (HLA-ABC), and were negative, or mildly positive, for MHC Class II (HLA-DR) antigen. Oct-4 was positive in all the two cells types. Both AF MSCs and WJ MSCs could differentiate along myocardium. The differentiation capacities were detected by the expression of GATA-4, c-TnT, a-actin, Cx43 after myocardial induction. Conclusions Both AF MSCs and WJ MSCs have the potential clinical application for myogenesis in cardiac regenerative therapy.
文摘[Objective] The paper was to analyze lizi synoptic meteorology of 13 rain- storm processes during the flood season of Hunan Province in 2010. [Method] Using the principle of lizi synoptic meteorology, 13 regional rainstorm weather processes occurred in Hunan Province in 2010 were analyzed. [Result] Thirteen rainstorms are all closely related to self-organization convergent airflow, rainstorm is the inevitable result after the outbreak of self-organization convergent airflow. The inoculation area of self-organization convergent airflow is accorded with the occurrence area of rain- storm in the next 12-36 h; once the inoculation area of self-organization convergent airflow disappears, there will be no regional rainstorm in the next 12-36 h; the inoc- ulation area of self-organization convergent airflow is produced in the convergence domain of large scale of southern and northern lizi pair. [Conclusion] The existence of southern and northern lizi pair can be used as the short-term forecast model of regional rainstorm during flood season.
文摘Our study group has developed a unique combined ters from the industries of dyestuff, pharmaceutical, chemical biological technology to treat high-strength organic wastewaengineering and zymolysis by using the principles of anaerobic ecological niche and bio-phase separation. The study obtained five national invention patents and eight patent equipments. This technology contains four kernel processes - two-phase anaerobic-aerobic process, hydrolysis-acidification-oxidation process, UASBAF-oxidation process, and internal cycling-hydrolysis-oxidation process. Fifteen pilot projects were accomplished in the basins of Tai Lake, Huai River, Liao River and Songhua River, and their total capital investment reached 185.214 million Yuan (RMB). Compared to conventional wastewater treatment technology, the innovative technology is more costeffective for high-strength organic wastewater treatment, can save capital investment by 15% - 30%, lessen land usage by 20% to 40% and decrease the operating cost by 10% to 25%. The operating cost of treatment per cubic meter industrial wastewater could be below 0.6 to 1.4 Yuan (RMB).
基金Acknowledgments Foundation item: National Science Foundation of China (No. 50808068) The Ph.D. Programs Foundation of Ministry of Education of China (No. 200802941001).
文摘To solve the problem of vast cement and low strength in the treated sludge, clay mineral used for accessorial solidification material was applied to advance strength. The principle of solidification sludge strength because of clay mineral is not clear and has not supported the choice of clay mineral. The mineral and pore water is analyzed in order to contrast clay mineral added or not based on the XRD and pore water chemical character. The result shows that the absorbed quantity of Ca2~ was reduced by sludge because of clay mineral added, the hydrated reaction was advanced and integrated solidified materials was formed.
文摘In the near future, fresh water will be very difficult to get and scarce. It is said that in 2025 half of the mankind will live in the areas where fresh water is not enough. Also, UN and WMO (World Meteorological Organization) are predicting five billion people will be in short of even drinking water. Also, in the present, there are some areas where sea water or chloride contained sand are used as mixing water with or without intension. The authors believe that the possibilities of using sea water as mixing water in concrete should be investigated seriously. In this paper, the authors would like to show various possibilities of using sea water as mixing water in RC (reinforced concrete) members. The possibilities are shown as follows: (1) mixed with pozzolanic materials (Blast furnace slag powder, etc.) expecting to fix the free chloride ion; (2) Mixed with corrosion inhibitor; (3) reinforced with stainless steel or corrosion resistant reinforcement; and (4) used in very dry or submerged conditions.
基金Supported by Projects of NSFC(No.51108207)Science and Technology Development Planning of Jilin Province(No.201201057)
文摘Sulpho-aluminate expansive cementitious composite is proved to be one of the most effective ways to prevent concrete cracking too soon. Mix design of sulpho-aluminate expansive cementitious composite completely depends on experience and experiments at present. This method ignores the influence of expansion behavior which hinders the application of sulpho-aluminate expansive cementitious composite. The workability,free expansion property,flexural strength and compressive strength of sulpho-aluminate expansive cementitious composite have been investigated by tests. The relationship between expansion ratio and mix design parameters such as curing age,water-cement ratio and cement abundance coefficient is deduced according to the experimental statistics. A new simplified approach to mix design of sulpho-aluminate expansive cementitious composite is proposed as a reference for construction application,which avoids experiments and experience.
基金This work is supported by the National Natural Science Focal Projects Foundation of China(Grant No.40131020)the National Natural Science Foundation of China(Grant No.49833030)+2 种基金the Venus Program Foundation for Young Scientists of Shanghai(Grant No.97QA14023)its Tracking Program(Grant No.01QMH1406)the Dawn Program of Shanghai Ecucational Development Foundation.
文摘The five chemical associations of heavy metals have been extracted continuously using the Tessier extracting method. Results show that Cu, Pb, Fe, Zn and Cr in the sediments are mainly distributed in residual fraction, while the major chemical association of Mn is carbonates. Carbonate heavy metals are converted into Fe-Mn oxides in autumn. And in the low tidal flat, after carbonates have changed into ionic heavy metals, some of the elements are transported to the overlying water. Cu, Pb, Fe and Mn have good correlations with each other, and Zn, Cr also show their similarity of chemical behavior in the sediments.
基金Supported by the National Natural Science Foundation of China (No. 30490233, 40906086)the National Basic Research Program of China (973 Program) (No. 2006CB400608)Taishan Scholar Program of Shandong Province, Postdoctoral creative foundation of Shandong Province and the Yellow & Bohai Sea Scientific Observation and Experiment Station for Fishery Resources and Environment, Ministry of Agriculture
文摘Fish assemblage structure in the hypoxic zone in the Changjiang (Yangtze River) estuary and its adjacent waters were analyzed based on data from bottom trawl surveys conducted on the R/V Beidou in June, August and October 2006. Four fish assemblages were identified in each survey using two-way indicator species analysis (TWIA). High fish biomass was found in the northern part, central part and coastal waters of the survey area; in contrast, high fish diversity was found in the southern part of the survey area and the Changjiang estuary outer waters. Therefore, it is difficult to maintain high fishery production when high fish diversity is evenly distributed in the fish community. Fish became smaller and fish size spectra tended to be narrower because of fish species variations and differences in growth characteristics. Fish diversity increased, the age to maturity was reduced and some migrant species were not collected in the surveys. Fish with low economic value, small size, simple age structure and low tropic level were predominant in fish assemblages in the Changjiang estuary and its adjacent waters. The lowest hypoxic value decreased in the Changjiang estuary and its adjacent waters.
基金Supported by TUBTAK-SBAG (Project Number 104S581)the Turkish Academy of Sciences (TUBA)
文摘AIM: To investigate the expression levels of lymphatic vessel endothelial hyaluronan receptor-1 (LYVE-1), vascular endothelial growth factor receptor-3 (VEGFR-3) and CD44 genes and the relationship between their lev- els and clinicopathological parameters in gastric cancer.METHODS: Tissue samples were obtained from 33 patients (8 females) with gastric cancer. mRNA levels of LYVE-1, VEGFR-3 and CD44 in normal and tumor tissues were quantitatively measured using real time polymerase chain reaction. The results were correlated with lymph node metastasis, histological type and differentiation of the tumor, T-stage, and presence of vascular, perineural and lymphatic invasions. The distribution of molecules in the tissue was evaluated using immunohistochemistry. RESULTS: LYVE-1, CD44 and VEGFR-3 gene expression levels were significantly higher in gastric cancer than in normal tissue. While there was no correlation between gene expressions and clinicopathologic fea- tures such as histologic type, differentiation and stage, gene expression levels were found to be increased in conjunction with positive lymph node/total lymph node ratio and the presence of perineural invasion. A significant correlation was also found between LYVE-1 and CD44 over-expressions and perineural invasion and lymph node positivity in gastric cancers. When the dis- tribution of LYVE-1 antibody-stained lymphatic vessels in tissue was evaluated, lymphatic vessels were located intra-tumorally in 13% and peri-tumorally in 27% of the patients. Moreover, lymph node metastases were also positive in all patients with LYVE-1-staining. CONCLUSION: LYVE-1, VEGFR-3 and CD44 all play an important role in lymphangiogenesis, invasion and metastasis. LYVE-1 is a perfectly reliable lymphatic vessel marker and useful for immunohistochemistry.
文摘Nutrition plays an essential role in normal linear growth in children. Knowledge of the eating styles and dietary consumption of healthy short children from developed countries is scarce. The aim of this study was to investigate the dietary patterns in idiopathic short stature (ISS) and relatively low weight children compared to children with normal stature and weight. This research is a case-control study of 86 pre-pubertal healthy children, mean age 5.9 ± 1.5 years. The study group comprised 43 ISS children; 43 age-matched children with normal stature and weight served as controls. Outcome measures included: dietary patterns and physical activity. The absolute daily average energy, protein and carbohydrate intake was significantly lower in the ISS children (P 〈 0.05); after correcting for body surface area, no significant differences were found between groups. Intake of micronutrients calcium, iron, zinc, vitamin A and vitamin C, expressed as percentage from Recommended Dietary Allowance, was significantly lower in the ISS children (P 〈 0.05), who had lower food responsiveness, higher satiety responsiveness, lesser enjoyment of food and were slower eaters (P 〈 0.001). Physical activity was sedentary in both the ISS cases and controls. Our findings in healthy, pre-pubertal, relatively lean ISS children point to a distinct eating pattern with no alteration in physical activity. Understanding the differences in dietary intake and eating behaviors may be beneficial in the development of targeted nutritional intervention for lean ISS children.