The simulations of Cr atom substitution character during the formation of L12 and DO22 phases in Ni-Cr-Al alloy were performed at 873 K based on microscopic phase-field model. It is found that the substitution of Cr i...The simulations of Cr atom substitution character during the formation of L12 and DO22 phases in Ni-Cr-Al alloy were performed at 873 K based on microscopic phase-field model. It is found that the substitution of Cr is affected by Cr and Al contents and limits of occupation probabilities of Cr atom in L12 phase are present. The precipitate is single L12 phase when the component is less than the limit, Cr atoms substitute the Al sublattices in Ll2 phase, and both of atoms Al and Cr occupy the β-sites and complex phases Ni3（Al1-xCrx） are formed; Cr atoms enter Ni sites when Al and Cr contents exceed the limit, and substitute β-sites or both of α- and β-sites. The DO22 phase is formed at the boundary of Ll2 phase.展开更多
While conventional wastewater treatments for urban effluents are fairly routine and have proved highly effective,industrial wastewater requires more complex and specific treatments.This paper provides a technological ...While conventional wastewater treatments for urban effluents are fairly routine and have proved highly effective,industrial wastewater requires more complex and specific treatments.This paper provides a technological strategy for removal of recalcitrant contaminants based on a hybrid treatment system.The model effluent containing a binary mixture of synthetic dyes is treated by a combination of a preliminary physicochemical stage followed by a biological stage based on ligninolytic enzymes produced by Phanerochaete chrysosporium.This proposal includes biosorption onto peat as pretreatment,which decreases the volume and concentration to be treated in the biological reactor,thereby obtaining a completely decolorized effluent.The treated wastewater can therefore be reused in the dyeing baths with the consequent saving of water resources.展开更多
The Upper Blue Nile Basin, the highest sources of the Nile River flow through this area, is still under severe land degradation, which aggravates water scarcity. The productivity of subsistence farming is below 50% of...The Upper Blue Nile Basin, the highest sources of the Nile River flow through this area, is still under severe land degradation, which aggravates water scarcity. The productivity of subsistence farming is below 50% of the potential of agriculture, mainly because of inappropriate rainwater management. At farm level, rainwater is exposed to poor partitioning described as flooding, land degradation, siltation and water scarcity for domestic, irrigation, hydropower and environmental uses in the basin. Hence, it is one of the root causes of food-insecurity in the region. To reverse this situation and achieve increased rainwater productivity knowledge of rainfall partitioning at grassroots level is significantly important. However, rainwater partitioning and partitioning points are not clearly known by farmers in the area. Besides, understanding water-routes helps to manage rainwater with integrated water resources management （IWRM） processes. The objective of this study was to identify the knowledge gap of farmers and experts on rainwater partitioning that help for increased water productivity. Intensive monitoring and interviews have been carried out for 81 farmers and 22 local experts in three pilot sites. The interviewed farmers and experts are clearly aware of the runoff partitioning, since it is easily observable. While, only 10% of the farmers and 25% of experts know about evaporation partitioning, which is the largest compared to other losses. The paper gives recommendations for better understanding of rainfall partitioning points and management of water-routes at grassroots level to increase rainwater productivity and enhance food security in the area with IWRM processes.展开更多
A regional coupled prediction system for the Asia-Pacific(AP-RCP)(38°E-180°,20°S-60°N) area has been established.The AP-RCP system consists of WRF-ROMS(Weather Research and Forecast,and Regional Oc...A regional coupled prediction system for the Asia-Pacific(AP-RCP)(38°E-180°,20°S-60°N) area has been established.The AP-RCP system consists of WRF-ROMS(Weather Research and Forecast,and Regional Ocean Model System) coupled models combined with local observational information through dynamically downscaling coupled data assimilation(CDA).The system generates 18-day forecasts for the atmosphere and ocean environment on a daily quasi-operational schedule at Pilot National Laboratory for Marine Science and Technology(Qingdao)(QNLM),consisting of 2 different-resolution coupled models:27 km WRF coupled with 9 km ROMS,9 km WRF coupled with 3 km ROMS,while a version of 3 km WRF coupled with 3 km ROMS is in a test mode.This study is a first step to evaluate the impact of high-resolution coupled model with dynamically downscaling CDA on the extended-range predictions,focusing on forecasts of typhoon onset,improved precipitation and typhoon intensity forecasts as well as simulation of the Kuroshio current variability associated with mesoscale oceanic activities.The results show that for realizing the extended-range predictability of atmospheric and oceanic environment characterized by statistics of mesoscale activities,a fine resolution coupled model resolving local mesoscale phenomena with balanced and coherent coupled initialization is a necessary first step.The next challenges include improving the planetary boundary physics and the representation of air-sea and air-land interactions to enable the model to resolve kilometer or sub-kilometer processes.展开更多
Based on the phase field theory, the phase precipitation sequence of Ni75A110Cr15 alloy and the free energy of each phase were studied. Moreover, the interatomic potentials of Llo phase, L12 phase and DO22 phase chang...Based on the phase field theory, the phase precipitation sequence of Ni75A110Cr15 alloy and the free energy of each phase were studied. Moreover, the interatomic potentials of Llo phase, L12 phase and DO22 phase changing with temperature and concen- trations were computed through utilizing the interatomic potentials equations induced by Khachaturyan＇s relational equations between the interatomic potentials and the long-range order （LRO） parameters. Results match preceding work and demonstrate that the phase precipitation sequence of Ni75AlloCr15 alloy is the disordered phase -L10 pre-precipitation phase -L12 equilibrium phase -L12＋DO22 equilibrium phase. Free energies of Llo pre-precipitation phase are higher and interatomic potentials are smaller than those of L12 equilibrium phase; therefore, it is concluded that Llo phase is unstable, and phase transformation would occur to L12 which is more stable; L12 phase precipitates earlier than DO22 phase because L12＇s interaction potentials are larger than DO22＇s.展开更多
基金Project(50071046) supported by the National Natural Science Foundation of China
文摘The simulations of Cr atom substitution character during the formation of L12 and DO22 phases in Ni-Cr-Al alloy were performed at 873 K based on microscopic phase-field model. It is found that the substitution of Cr is affected by Cr and Al contents and limits of occupation probabilities of Cr atom in L12 phase are present. The precipitate is single L12 phase when the component is less than the limit, Cr atoms substitute the Al sublattices in Ll2 phase, and both of atoms Al and Cr occupy the β-sites and complex phases Ni3（Al1-xCrx） are formed; Cr atoms enter Ni sites when Al and Cr contents exceed the limit, and substitute β-sites or both of α- and β-sites. The DO22 phase is formed at the boundary of Ll2 phase.
基金Supported by the Proyecto Fondecyt (1040089,1090098)
文摘While conventional wastewater treatments for urban effluents are fairly routine and have proved highly effective,industrial wastewater requires more complex and specific treatments.This paper provides a technological strategy for removal of recalcitrant contaminants based on a hybrid treatment system.The model effluent containing a binary mixture of synthetic dyes is treated by a combination of a preliminary physicochemical stage followed by a biological stage based on ligninolytic enzymes produced by Phanerochaete chrysosporium.This proposal includes biosorption onto peat as pretreatment,which decreases the volume and concentration to be treated in the biological reactor,thereby obtaining a completely decolorized effluent.The treated wastewater can therefore be reused in the dyeing baths with the consequent saving of water resources.
文摘The Upper Blue Nile Basin, the highest sources of the Nile River flow through this area, is still under severe land degradation, which aggravates water scarcity. The productivity of subsistence farming is below 50% of the potential of agriculture, mainly because of inappropriate rainwater management. At farm level, rainwater is exposed to poor partitioning described as flooding, land degradation, siltation and water scarcity for domestic, irrigation, hydropower and environmental uses in the basin. Hence, it is one of the root causes of food-insecurity in the region. To reverse this situation and achieve increased rainwater productivity knowledge of rainfall partitioning at grassroots level is significantly important. However, rainwater partitioning and partitioning points are not clearly known by farmers in the area. Besides, understanding water-routes helps to manage rainwater with integrated water resources management （IWRM） processes. The objective of this study was to identify the knowledge gap of farmers and experts on rainwater partitioning that help for increased water productivity. Intensive monitoring and interviews have been carried out for 81 farmers and 22 local experts in three pilot sites. The interviewed farmers and experts are clearly aware of the runoff partitioning, since it is easily observable. While, only 10% of the farmers and 25% of experts know about evaporation partitioning, which is the largest compared to other losses. The paper gives recommendations for better understanding of rainfall partitioning points and management of water-routes at grassroots level to increase rainwater productivity and enhance food security in the area with IWRM processes.
基金supported by the National Key Research and Development Program of China(2017YFC1404100,2017YFC1404104)the National Natural Science Foundation of China(41775100,41830964)+1 种基金the Shandong Province’s"Taishan"Scientist Project(2018012919)the collaborative project between the Ocean University of China(OUC),Texas A&M University(TAMU)and the National Center for Atmospheric Research(NCAR)and completed through the International Laboratory for High Resolution Earth System Prediction(iHESP)-a collaboration among QNLM,TAMU and NCAR。
文摘A regional coupled prediction system for the Asia-Pacific(AP-RCP)(38°E-180°,20°S-60°N) area has been established.The AP-RCP system consists of WRF-ROMS(Weather Research and Forecast,and Regional Ocean Model System) coupled models combined with local observational information through dynamically downscaling coupled data assimilation(CDA).The system generates 18-day forecasts for the atmosphere and ocean environment on a daily quasi-operational schedule at Pilot National Laboratory for Marine Science and Technology(Qingdao)(QNLM),consisting of 2 different-resolution coupled models:27 km WRF coupled with 9 km ROMS,9 km WRF coupled with 3 km ROMS,while a version of 3 km WRF coupled with 3 km ROMS is in a test mode.This study is a first step to evaluate the impact of high-resolution coupled model with dynamically downscaling CDA on the extended-range predictions,focusing on forecasts of typhoon onset,improved precipitation and typhoon intensity forecasts as well as simulation of the Kuroshio current variability associated with mesoscale oceanic activities.The results show that for realizing the extended-range predictability of atmospheric and oceanic environment characterized by statistics of mesoscale activities,a fine resolution coupled model resolving local mesoscale phenomena with balanced and coherent coupled initialization is a necessary first step.The next challenges include improving the planetary boundary physics and the representation of air-sea and air-land interactions to enable the model to resolve kilometer or sub-kilometer processes.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10902086, 51075335 and 50875217)the Basic Re-search Fund of the Northwestern Polytechnical University (Grant No. JC201005)the Doctoral Foundation of Northwestern Polytechnical University (Grant No. CX201103)
文摘Based on the phase field theory, the phase precipitation sequence of Ni75A110Cr15 alloy and the free energy of each phase were studied. Moreover, the interatomic potentials of Llo phase, L12 phase and DO22 phase changing with temperature and concen- trations were computed through utilizing the interatomic potentials equations induced by Khachaturyan＇s relational equations between the interatomic potentials and the long-range order （LRO） parameters. Results match preceding work and demonstrate that the phase precipitation sequence of Ni75AlloCr15 alloy is the disordered phase -L10 pre-precipitation phase -L12 equilibrium phase -L12＋DO22 equilibrium phase. Free energies of Llo pre-precipitation phase are higher and interatomic potentials are smaller than those of L12 equilibrium phase; therefore, it is concluded that Llo phase is unstable, and phase transformation would occur to L12 which is more stable; L12 phase precipitates earlier than DO22 phase because L12＇s interaction potentials are larger than DO22＇s.
