We report the adsorption of phosphate and discuss the mechanisms of phosphate removal from aqueous solution by burst furnace slag (BFS) and steel furnace slag (SFS). The results show that the adsorption of phosphate o...We report the adsorption of phosphate and discuss the mechanisms of phosphate removal from aqueous solution by burst furnace slag (BFS) and steel furnace slag (SFS). The results show that the adsorption of phosphate on the slag was rapid and the majority of adsorption was completed in 5~10 min. The adsorption capacity of phosphate by the slag was reduced dramatically by acid treatment. The relative contribution of adsorption to the total removal of phosphate was 26%~28%. Phosphate adsorption on BFS and SFS follows the Freundlich isotherm, with the related constants of k 6.372 and 1/n 1.739 for BFS, and of k 1.705 and 1/n 1.718 for SFS. The pH and Ca2+ concentration were decreased with the addition of phosphate, suggesting the formation of calcium phosphate precipitation. At pH 2.93 and 6.93, phosphate was desorbed by about 36%~43% and 9%~11%, respectively. These results indicate that the P adsorption on the slag is not completely reversible and that the bond between the slag particles and adsorbed phosphate is strong. The X-ray diffraction (XRD) patterns of BFS and SFS before and after phosphate adsorption verify the formation of phosphate salts (CaHPO4·2H2O) after adsorption process. We conclude that the removal of phosphate by BFS and SFS is related to the formation of phosphate calcium precipitation and the adsorption on hydroxylated oxides. The results show that BFS and SFS removed phosphate nearly 100%, indicating they are promising adsorbents for the phosphate removal in wastewater treatment and pollution control.展开更多
In the near future, fresh water will be very difficult to get and scarce. It is said that in 2025 half of the mankind will live in the areas where fresh water is not enough. Also, UN and WMO （World Meteorological Org...In the near future, fresh water will be very difficult to get and scarce. It is said that in 2025 half of the mankind will live in the areas where fresh water is not enough. Also, UN and WMO （World Meteorological Organization） are predicting five billion people will be in short of even drinking water. Also, in the present, there are some areas where sea water or chloride contained sand are used as mixing water with or without intension. The authors believe that the possibilities of using sea water as mixing water in concrete should be investigated seriously. In this paper, the authors would like to show various possibilities of using sea water as mixing water in RC （reinforced concrete） members. The possibilities are shown as follows： （1） mixed with pozzolanic materials （Blast furnace slag powder, etc.） expecting to fix the free chloride ion; （2） Mixed with corrosion inhibitor; （3） reinforced with stainless steel or corrosion resistant reinforcement; and （4） used in very dry or submerged conditions.展开更多
Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid was...Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid wastes from one form to another to be reused either by the same production unit or by different industrial installation is very much essential not only for conserving metals and mineral resources but also for protecting the environment. The sustainable development concept requires a more efficient management of waste materials and preservation of environment. The paper presents the basic characteristics of slag, analyses and it＇s modification by incorporating some essential plant nutrients and the possibility of its application as fertilizer was studied.展开更多
基金Project supported by the Foundation for the Author of NationalExcellent Doctoral Dissertation of China (No. 200149)the NaturalScience Foundation of Zhejiang Province (No. R305078), China
文摘We report the adsorption of phosphate and discuss the mechanisms of phosphate removal from aqueous solution by burst furnace slag (BFS) and steel furnace slag (SFS). The results show that the adsorption of phosphate on the slag was rapid and the majority of adsorption was completed in 5~10 min. The adsorption capacity of phosphate by the slag was reduced dramatically by acid treatment. The relative contribution of adsorption to the total removal of phosphate was 26%~28%. Phosphate adsorption on BFS and SFS follows the Freundlich isotherm, with the related constants of k 6.372 and 1/n 1.739 for BFS, and of k 1.705 and 1/n 1.718 for SFS. The pH and Ca2+ concentration were decreased with the addition of phosphate, suggesting the formation of calcium phosphate precipitation. At pH 2.93 and 6.93, phosphate was desorbed by about 36%~43% and 9%~11%, respectively. These results indicate that the P adsorption on the slag is not completely reversible and that the bond between the slag particles and adsorbed phosphate is strong. The X-ray diffraction (XRD) patterns of BFS and SFS before and after phosphate adsorption verify the formation of phosphate salts (CaHPO4·2H2O) after adsorption process. We conclude that the removal of phosphate by BFS and SFS is related to the formation of phosphate calcium precipitation and the adsorption on hydroxylated oxides. The results show that BFS and SFS removed phosphate nearly 100%, indicating they are promising adsorbents for the phosphate removal in wastewater treatment and pollution control.
文摘In the near future, fresh water will be very difficult to get and scarce. It is said that in 2025 half of the mankind will live in the areas where fresh water is not enough. Also, UN and WMO （World Meteorological Organization） are predicting five billion people will be in short of even drinking water. Also, in the present, there are some areas where sea water or chloride contained sand are used as mixing water with or without intension. The authors believe that the possibilities of using sea water as mixing water in concrete should be investigated seriously. In this paper, the authors would like to show various possibilities of using sea water as mixing water in RC （reinforced concrete） members. The possibilities are shown as follows： （1） mixed with pozzolanic materials （Blast furnace slag powder, etc.） expecting to fix the free chloride ion; （2） Mixed with corrosion inhibitor; （3） reinforced with stainless steel or corrosion resistant reinforcement; and （4） used in very dry or submerged conditions.
文摘Significant quantities of slag are generated as waste material or by-product every day from steel industries. They usually contain considerable quantities of valuable metals and materials. Transforming these solid wastes from one form to another to be reused either by the same production unit or by different industrial installation is very much essential not only for conserving metals and mineral resources but also for protecting the environment. The sustainable development concept requires a more efficient management of waste materials and preservation of environment. The paper presents the basic characteristics of slag, analyses and it＇s modification by incorporating some essential plant nutrients and the possibility of its application as fertilizer was studied.
