采用基于密度泛函理论的第一性原理方法,利用Materials Studio 6.0中的CASTEP模块对不同浓度的过渡金属元素Mn替位掺杂γ-TiAl得到的8个合金体系的原子平均形成能、晶格参量及轴比、弹性模量和重叠布居数等进行了计算分析。原子平均形...采用基于密度泛函理论的第一性原理方法,利用Materials Studio 6.0中的CASTEP模块对不同浓度的过渡金属元素Mn替位掺杂γ-TiAl得到的8个合金体系的原子平均形成能、晶格参量及轴比、弹性模量和重叠布居数等进行了计算分析。原子平均形成能的计算结果表明,各掺杂体系的形成能均为负值,表明其均可稳定存在,同时Mn原子占据Al原子位置得到的掺杂体系原子平均形成能更低,说明Mn原子倾向于替代Al原子;对晶胞轴比和弹性模量的计算分析表明,Mn掺杂能够提高合金的延性,以Ti12Al11Mn体系效果最为明显;重叠布居数的计算结果表明,Mn原子的掺入减弱了体系内共价键的各向异性程度,从化学键的角度解释了掺杂体系延性得到改善的机理。展开更多
The effect of carbon addition on the microstructures of TiAl-based alloy(Ti-45Al-3Fe-2Mo) was studied.The proportion of β/B2 phase reduces with the content of carbon increasing,while the colony size increases.With ...The effect of carbon addition on the microstructures of TiAl-based alloy(Ti-45Al-3Fe-2Mo) was studied.The proportion of β/B2 phase reduces with the content of carbon increasing,while the colony size increases.With increasing the carbon content,the lamellar spacing first decreases from 267 nm(Ti-45Al-3Fe-2Mo) to 237 nm(Ti-45Al-3Fe-2Mo-0.3C) and 155 nm(Ti-45Al-3Fe-2Mo-0.5C),but then increases to 230 nm(Ti-45Al-3Fe-2Mo-1.0C) with further increase in C level,which is affected by the inhibition of carbon atom and precipitation of carbides at the lamellar interface.Precipitation of carbides shows a response to aging time at 800 ℃.P-type carbides grow up at the boundaries and near the dislocation areas with the prolonging of aging time.And these carbides are projected different morphology in different beam directions(BD).The effects of these microstructural modifications were examined and the observations were discussed.展开更多
The properties of Sc-dopedθ′(Al_(2)Cu)/Al interface in Al−Cu alloys were investigated by first-principles calculations.Sc-doped semi-coherent and coherentθ′(Al_(2)Cu)/Al interfaces(Sc doped in Al slab(S1 site),Sc ...The properties of Sc-dopedθ′(Al_(2)Cu)/Al interface in Al−Cu alloys were investigated by first-principles calculations.Sc-doped semi-coherent and coherentθ′(Al_(2)Cu)/Al interfaces(Sc doped in Al slab(S1 site),Sc doped inθ′slab(S2 site))were modeled based on calculated results and reported experiments.Through the analysis of interfacial bonding strength,it is revealed that the doping of Sc at S1 site can significantly decrease the interface energy and increase the work of adhesion.In particular,the doped coherent interface with Sc at S1 site which is occupied by interstitial Cu atoms has very good bonding strength.The electronic structure shows the strong Al—Cu bonds at the interfaces with Sc at S1 site,and the Al—Al bonds at the interfaces with Sc at S2 site are formed.The formation of strong Al—Cu and Al—Al bonds plays an important role in the enhancement of doped interface strength.展开更多
A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabric...A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabricate the ultrafine-grained W-1.0 wt.%La2O3 alloys by pressureless sintering. Compared with pure tungsten, W-1.0 wt.%La2O3 alloys exhibit ultrafine grains and excellent mechanical properties. After sintering, the average grain size of the WLO sample is larger than that of WL10 and WLNO samples;the microhardness values of WL10 and WLNO samples are similar but larger than the value of WLO sample. The optimized La2O3 particles are obtained in the WL10 sample after sintering at 1500 ℃ with the minimum mean size by comparing with WLNO and WLO samples, which are uniformly distributed either at grain boundaries or in the grain interior with the sizes of(57±29.7) and(27±13.1) nm, respectively. This study exhibits ultrafine microstructure and outperforming mechanical properties of the W-1.0 wt.%La2O3 alloy via the liquid-liquid doping route, as compared with conventionally-manufactured tungsten materials.展开更多
The flow stress behavior of Al-3.5Cu-1.5Li-0.25(Sc+Zr) alloy during hot compression deformation was studied by isothermal compression test using Gleeble-1500 thermal-mechanical simulator. Compression tests were prefor...The flow stress behavior of Al-3.5Cu-1.5Li-0.25(Sc+Zr) alloy during hot compression deformation was studied by isothermal compression test using Gleeble-1500 thermal-mechanical simulator. Compression tests were preformed in the temperature range of 653-773 K and in the strain rate range of 0.001-10 s-1 up to a true plastic strain of 0.7. The results indicate that the flow stress of the alloy increases with increasing strain rate at a given temperature,and decreases with increasing temperature at a given imposed strain rate. The relationship between the flow stress and the strain rate and the temperature was derived by analyzing the experimental data. The flow stress is in a hyperbolic sine relationship with the strain rate,and in an Arrhenius relationship with the temperature,which imply that the process of plastic deformation at an elevated temperature for this material is thermally activated. The flow stress of the alloy during the elevated temperature deformation can be represented by a Zener-Hollomon parameter with the inclusion of the Arrhenius term. The values of n,α and A in the analytical expressions of flow stress σ are fitted to be 5.62,0.019 MPa-1 and 1.51×1016 s-1,respectively. The hot deformation activation energy is 240.85 kJ/mol.展开更多
Phase decomposition kinetics and the corresponding mechanical properties of the severe cold-rolled(SCRed) carbon-doped(1.3 at.%) equimolar FeCoCrNiMn high-entropy alloy(HEA) after being annealed at 500 ℃ were investi...Phase decomposition kinetics and the corresponding mechanical properties of the severe cold-rolled(SCRed) carbon-doped(1.3 at.%) equimolar FeCoCrNiMn high-entropy alloy(HEA) after being annealed at 500 ℃ were investigated. This single face-centered cubic(FCC) solid-solution HEA decomposed to M23 C6+L10, B2, and σ in chronological order. The formation kinetics of the L10, B2, and σ phases followed the Johnson-Mehl-AvramiKolmogorov(JMAK) equation. The yield strength of the HEA was 1520 MPa and increased to 1920 MPa after being annealed at 500 ℃ for 1 h, as a result of the formation of nanosized M23 C6 and L10. Both strength and ductility decreased after 2 d of annealing due to the increase of volume fractions and the coarsening of the M23C6 and L10 precipitates. From 4 to 32 d, the hardness was found to increase, which is ascribed to the rapid formation of the B2 and σ phases. From 32 to 64 d, the hardness increased further to finally reach about HV 760, with the FCC matrix almost exhausted to form the M23 C6, L10, B2, and σ phases. The results of this work may serve as a guide for the heat-treatment of carbon-doped HEAs.展开更多
文摘采用基于密度泛函理论的第一性原理方法,利用Materials Studio 6.0中的CASTEP模块对不同浓度的过渡金属元素Mn替位掺杂γ-TiAl得到的8个合金体系的原子平均形成能、晶格参量及轴比、弹性模量和重叠布居数等进行了计算分析。原子平均形成能的计算结果表明,各掺杂体系的形成能均为负值,表明其均可稳定存在,同时Mn原子占据Al原子位置得到的掺杂体系原子平均形成能更低,说明Mn原子倾向于替代Al原子;对晶胞轴比和弹性模量的计算分析表明,Mn掺杂能够提高合金的延性,以Ti12Al11Mn体系效果最为明显;重叠布居数的计算结果表明,Mn原子的掺入减弱了体系内共价键的各向异性程度,从化学键的角度解释了掺杂体系延性得到改善的机理。
基金Project (2011CB605505) supported by the National Basic Research Program of China
文摘The effect of carbon addition on the microstructures of TiAl-based alloy(Ti-45Al-3Fe-2Mo) was studied.The proportion of β/B2 phase reduces with the content of carbon increasing,while the colony size increases.With increasing the carbon content,the lamellar spacing first decreases from 267 nm(Ti-45Al-3Fe-2Mo) to 237 nm(Ti-45Al-3Fe-2Mo-0.3C) and 155 nm(Ti-45Al-3Fe-2Mo-0.5C),but then increases to 230 nm(Ti-45Al-3Fe-2Mo-1.0C) with further increase in C level,which is affected by the inhibition of carbon atom and precipitation of carbides at the lamellar interface.Precipitation of carbides shows a response to aging time at 800 ℃.P-type carbides grow up at the boundaries and near the dislocation areas with the prolonging of aging time.And these carbides are projected different morphology in different beam directions(BD).The effects of these microstructural modifications were examined and the observations were discussed.
基金the financia supports from the National Key Research and Development Program of China (No. 2019YFB2006500)the National Natura Science Foundation of China (Nos. 52171024 51771234, 51601228)。
文摘The properties of Sc-dopedθ′(Al_(2)Cu)/Al interface in Al−Cu alloys were investigated by first-principles calculations.Sc-doped semi-coherent and coherentθ′(Al_(2)Cu)/Al interfaces(Sc doped in Al slab(S1 site),Sc doped inθ′slab(S2 site))were modeled based on calculated results and reported experiments.Through the analysis of interfacial bonding strength,it is revealed that the doping of Sc at S1 site can significantly decrease the interface energy and increase the work of adhesion.In particular,the doped coherent interface with Sc at S1 site which is occupied by interstitial Cu atoms has very good bonding strength.The electronic structure shows the strong Al—Cu bonds at the interfaces with Sc at S1 site,and the Al—Al bonds at the interfaces with Sc at S2 site are formed.The formation of strong Al—Cu and Al—Al bonds plays an important role in the enhancement of doped interface strength.
基金Projects(2017YFB0306000,2017YFB0305600)supported by the National Key Research and Development Program of ChinaProjects(51774035,51604025,51574031,51574030,51574029,51604240)supported by the National Natural Science Foundation of China+2 种基金Project(2019JZZY010327)supported by the Shandong Key Research and Development Plan Project,ChinaProjects(2174079,2162027)supported by the Natural Science Foundation Program of Beijing,ChinaProjects(FRF-IDRY-19-025,FRF-TP-17-034A2,FRF-TP-19-015A3,FRF-IDRY-19-003C2)supported by the Fundamental Research Funds for the Central Universities of China。
文摘A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabricate the ultrafine-grained W-1.0 wt.%La2O3 alloys by pressureless sintering. Compared with pure tungsten, W-1.0 wt.%La2O3 alloys exhibit ultrafine grains and excellent mechanical properties. After sintering, the average grain size of the WLO sample is larger than that of WL10 and WLNO samples;the microhardness values of WL10 and WLNO samples are similar but larger than the value of WLO sample. The optimized La2O3 particles are obtained in the WL10 sample after sintering at 1500 ℃ with the minimum mean size by comparing with WLNO and WLO samples, which are uniformly distributed either at grain boundaries or in the grain interior with the sizes of(57±29.7) and(27±13.1) nm, respectively. This study exhibits ultrafine microstructure and outperforming mechanical properties of the W-1.0 wt.%La2O3 alloy via the liquid-liquid doping route, as compared with conventionally-manufactured tungsten materials.
基金Project(2002AA305104) supported by the National High-Tech Research and Development Program of China
文摘The flow stress behavior of Al-3.5Cu-1.5Li-0.25(Sc+Zr) alloy during hot compression deformation was studied by isothermal compression test using Gleeble-1500 thermal-mechanical simulator. Compression tests were preformed in the temperature range of 653-773 K and in the strain rate range of 0.001-10 s-1 up to a true plastic strain of 0.7. The results indicate that the flow stress of the alloy increases with increasing strain rate at a given temperature,and decreases with increasing temperature at a given imposed strain rate. The relationship between the flow stress and the strain rate and the temperature was derived by analyzing the experimental data. The flow stress is in a hyperbolic sine relationship with the strain rate,and in an Arrhenius relationship with the temperature,which imply that the process of plastic deformation at an elevated temperature for this material is thermally activated. The flow stress of the alloy during the elevated temperature deformation can be represented by a Zener-Hollomon parameter with the inclusion of the Arrhenius term. The values of n,α and A in the analytical expressions of flow stress σ are fitted to be 5.62,0.019 MPa-1 and 1.51×1016 s-1,respectively. The hot deformation activation energy is 240.85 kJ/mol.
基金Project(51901134)supported by the National Natural Science Foundation of ChinaProject(SJTU.18X100040023)supported by the Program of Scientific Research Ability Cultivation for Young Researchers,China。
文摘Phase decomposition kinetics and the corresponding mechanical properties of the severe cold-rolled(SCRed) carbon-doped(1.3 at.%) equimolar FeCoCrNiMn high-entropy alloy(HEA) after being annealed at 500 ℃ were investigated. This single face-centered cubic(FCC) solid-solution HEA decomposed to M23 C6+L10, B2, and σ in chronological order. The formation kinetics of the L10, B2, and σ phases followed the Johnson-Mehl-AvramiKolmogorov(JMAK) equation. The yield strength of the HEA was 1520 MPa and increased to 1920 MPa after being annealed at 500 ℃ for 1 h, as a result of the formation of nanosized M23 C6 and L10. Both strength and ductility decreased after 2 d of annealing due to the increase of volume fractions and the coarsening of the M23C6 and L10 precipitates. From 4 to 32 d, the hardness was found to increase, which is ascribed to the rapid formation of the B2 and σ phases. From 32 to 64 d, the hardness increased further to finally reach about HV 760, with the FCC matrix almost exhausted to form the M23 C6, L10, B2, and σ phases. The results of this work may serve as a guide for the heat-treatment of carbon-doped HEAs.