The phase diagram of ZrO_(2)−CaO−TiO_(2)system was essential for the development of photocatalytic materials and refractory materials.In this work,the ZrO_(2)−CaO−TiO_(2)system was accessed by using the CALPHAD method...The phase diagram of ZrO_(2)−CaO−TiO_(2)system was essential for the development of photocatalytic materials and refractory materials.In this work,the ZrO_(2)−CaO−TiO_(2)system was accessed by using the CALPHAD method.The substitutional solution models were used to describe liquid and solid solution phases,the sub-lattice models were used to describe ternary compounds,and then the thermodynamic parameters were obtained by the least square method combined with literature experiment results.The acquired thermodynamic parameters were used to calculate the isothermal sections of the ZrO_(2)−CaO−TiO_(2)system at 1473 and 1673 K.There existed a good agreement between experimental and predicted phase relationships,the experimental points which were inconsistent with calculated results may be attributed to experimental errors and the sluggish kinetics of cations for ZrO_(2)-based materials.In order to further verify the validity of the database,the thermodynamic parameters were also used to simulate the thermodynamic properties(specific heat capacity,enthalpy,and entropy)of CaZrTi_(2)O_(7) within 5%errors.Good consistency demonstrated that the present thermodynamic database was self-consistent and credible.展开更多
The texture analysis is often discussed in image processing domain, but most methods are limited within gray-level image or color image, and the present conception of texture is defined mainly based on gray-level imag...The texture analysis is often discussed in image processing domain, but most methods are limited within gray-level image or color image, and the present conception of texture is defined mainly based on gray-level image of single band. One of the essential characters of remote sensing image is multidimensional or even high-dimensional, and the traditional texture conception cannot contain enough information for these. Therefore, it is necessary to pursuit a proper texture definition based on remote sensing images, which is the first discussion in this paper. This paper describes the mapping model of spectral vector in two-dimensional image space using Markov random field (MRF), establishes a texture model of multiband remote sensing image based on MRF, and analyzes the calculations of Gibbs potential energy and Gibbs parameters. Further, this paper also analyzes the limitations of the traditional Gibbs model, prefers a new Gibbs model avoiding estimation of parameters, and presents a new texture segmentation algorithm for hy-perspectral remote sensing image later.展开更多
基金the Open Project of State Key Laboratory of Advanced Special Steel and Shanghai Key Laboratory of Advanced Ferrometallurgy,China(No.SKLASS2019-11)the National Natural Science Foundation of China(No.52104305).
文摘The phase diagram of ZrO_(2)−CaO−TiO_(2)system was essential for the development of photocatalytic materials and refractory materials.In this work,the ZrO_(2)−CaO−TiO_(2)system was accessed by using the CALPHAD method.The substitutional solution models were used to describe liquid and solid solution phases,the sub-lattice models were used to describe ternary compounds,and then the thermodynamic parameters were obtained by the least square method combined with literature experiment results.The acquired thermodynamic parameters were used to calculate the isothermal sections of the ZrO_(2)−CaO−TiO_(2)system at 1473 and 1673 K.There existed a good agreement between experimental and predicted phase relationships,the experimental points which were inconsistent with calculated results may be attributed to experimental errors and the sluggish kinetics of cations for ZrO_(2)-based materials.In order to further verify the validity of the database,the thermodynamic parameters were also used to simulate the thermodynamic properties(specific heat capacity,enthalpy,and entropy)of CaZrTi_(2)O_(7) within 5%errors.Good consistency demonstrated that the present thermodynamic database was self-consistent and credible.
基金Supported by the National Key Basic Research and Development Program(No.2006CB701303, No. 2004CB318206)
文摘The texture analysis is often discussed in image processing domain, but most methods are limited within gray-level image or color image, and the present conception of texture is defined mainly based on gray-level image of single band. One of the essential characters of remote sensing image is multidimensional or even high-dimensional, and the traditional texture conception cannot contain enough information for these. Therefore, it is necessary to pursuit a proper texture definition based on remote sensing images, which is the first discussion in this paper. This paper describes the mapping model of spectral vector in two-dimensional image space using Markov random field (MRF), establishes a texture model of multiband remote sensing image based on MRF, and analyzes the calculations of Gibbs potential energy and Gibbs parameters. Further, this paper also analyzes the limitations of the traditional Gibbs model, prefers a new Gibbs model avoiding estimation of parameters, and presents a new texture segmentation algorithm for hy-perspectral remote sensing image later.
