K—Ar法同位素年龄测试在西秦岭1:5万区调中的应用

本文是K-Ar同位素测龄资料的重新应用研究。采用了线性回归和引入参数加减等统计方法,使所获数据能较好解释地层间的时代关系。文章对原同位素数据来源的异同,线性回归的合理性以及参数加减的依据等问题论述还不够,但作为数据资料二次整理应用的思路,是值得提供读者参考的,以期引起更多类似的探索研究。

云母、辉石和蛇纹石中原位LA-MC-ICP-MS锂和硼同位素分析

硼（B）和锂（Li）是不相容元素,倾向于进入液相（熔体或者高水活度流体）,它们被广泛用于跟踪岩石中与流体活动相关的过程。现阶段大多数与俯冲相关的岩石锂同位素数据都来自于全岩分析;而硼同位素数据要么来自于全岩分析,要么来自于副矿物（如电气石）的原位分析,这制约了对锂和硼同位素在整个岩石及矿物中赋存和分配的认识。

美国墨西哥湾沿岸地压地热含水层中铀的地球化学

本文分析了来自美国墨西哥湾沿岸砂岩地压地热含水层的地层水,以确定这些层系中铀的地球化学。化学分析结果和化学平衡模型表明,这种地层水与晶质铀矿(UO_2)和铀石(USiO_4)保持平衡。地层水中^(234)U/^(238)U的活度比为1.06—1.69。这些同位素数据证实,在其形成温度下,铀在水和UO或USiO_4两者的固相之间发生连续地再平衡,同时通过α反冲作用^(234)U组分供给了来自基质物质的含水层。

Vital effects of K isotope fractionation in organisms： observations and a hypothesis

Compared with the measureable but limited K isotope variation in geological samples,biological samples have much larger variations in δ^41 values：from-1.3‰ to＋1.1‰ relative to the international K standard NIST SRM 3141a.Notably,higher plants generally have δ^41 values that are lower than igneous rocks,whereas sea plants（algae）have δ^41 values that are higher than seawater;the range in δ^41K values of plants encompasses the δ^41 values of both igneous rocks and seawater.Plant cells utilize different K uptake mechanisms in response to highand low-K conditions.In a low-K environment,plant cells use energy-consuming ion pumps for active uptake of K;plant cells in high-K environments use non-energy-consuming ion channels.Based on these facts and on K isotope data from sea and land plants,it is hypothesized that the different K uptake mechanisms are accompanied by distinct K isotope fractionation behaviors or vital effects.The enrichment of light K isotopes in terrestrial plants could be attributed to preferential transport of isotopically light K in the energy-consuming active uptake process by K ion pumps in the membranes of plant root cells.On the other hand,the enrichment of heavy K isotopes in algae may be caused by a combination of the lack of K isotope fractionation during K uptake from seawater via ion channels and the preferential efflux of light K isotopes across the cell membrane back to the seawater.The large variation of K isotope compositions in biological samples therefore may reflect the diversity of isotopic vital effects for K in organisms,which implies the great potential of K isotopes in biogeochemical studies.

Geochronology,geochemistry and Hf isotopic study of Early Carboniferous granodiorites in Taerqi region,central Daxing'anling and its tectonic implication

Zircon U-Pb age,whole rock geochemical and zircon Hf isotopic data are presented for Late Paleozoic granodiorites from the Taerqi region,central Daxing'anling to constrain its petrogenesis and tectonic implication.LA-ICP-MS zircon U-Pb age data indicates that the Late Paleozoic granodiorites were emplaced with age of333.4 ± 2.2 Ma(Early Carboniferous).Geochemically,the granodiorite samples have Si O2= 60.54%-71.40%,Na2 O = 4.04%--4.66%,K2 O = 1.65%--4.27% and Mg O = 0.96%--3.53%,belonging to medium-K to high-K calc-alkaline I-type granites.They are slightly enriched in large ion lithophile elements(e.g.Rb,Th,U and K) and light rare earth elements,and depleted in high field strength elements(e.g.Nb,Ta and Ti),with εHf(t) values of 8.0--11.8 and Hf two-stage model ages of 586-829 Ma.All these geochemical features suggest that the primary magma was derived from partial melting of Neoproterozoic to Phanerozoic newly accreted lower crust.According to the geochemical data and regional geological investigations,the Early Carboniferous granodiorites formed in an island arc setting linked to the subduction of the Paleo-Asian Oceanic Plate beneath the Xing'an Terrane.This also implies that the Xing'an and Songliao terranes have not amalgamated before the Early Carboniferous.

An Improved Method for Modeling Spatial Distribution of δD in Surface Snow over Antarctic Ice Sheet

Using the recent compilation of the isotopic composition data of surface snow of Antarctic ice sheet, we proposed an improved interpolation method of δD, which utilizes geographical factors （i.e., latitude and altitude） as the primary predictors and incorporates inverse distance weighting （IDW） technique. The method was applied to a high-resolution digital elevation model （DEM） to produce a grid map of multi-year mean δD values with lkm spatial resolution for Antarctica. The mean absolute deviation between observed and estimated data in the map is about 5.4‰, and the standard deviation is 9‰. The resulting δD pattern resembles well known characteristics such as the depletion of the heavy isotopes with increasing latitude and distance from coast line, but also reveals the complex topographic effects.

Transformation Pathway of Carbonate Pedofeatures Based on Their Micromorhology and Carbon Isotope Data in the Northern Caucasus Region,Russia

Carbonate pedofeatures (CPs) in a chronosequence of paleosols buried under kurgans in the Northern Caucasus region of Russia in a period from the end of the 4th to the middle of the 5th centuries AD (It seams that there is no time left) were studied by using a set of morphological and isotopic methods. The CPs in chernozem-type soils of Russia are usually represented by crystallomorphic calcite whereas the non-segregated carbonates occurred at the same horizons-by collomorphic one. Those two morphotypes of calcite have the differences in elemental composition and isotopic composition of carbon and, hence, should have different origins-from true and colloidal solutions, respectively. The same differences including radiocarbon age have been revealed for pseudomycelium of the ABca horizon of the youngest paleosols as compared with the same CPs of other paleosols in the chronosequence studied. Our assumption is that it was succeeded in finding that the pseudomycelium right away after its precipitation from a colloidal solution migrated from the lower soil horizons to the surface horizons during the periods of climatic aridization. After a short time interval (not more than 25-50 years) collomorphic calcite in the pseudomicelium of the yongest paleosols mentioned above will likely become by "usual" acicular calcite.

Radium isotopes assess water mixing processes and its application in the Zhujiang River estuary

Radium （Ra） isotopes are useful for tracing water mass transport and examining estuarine hydrological dynamics. In this study, several hydrological parameters, nutrients, ehlorophyll-a （ehl-a）, suspended particulate matter （SPM） and Ra isotopes （223Ra, 224Ra and 226Ra） of surface waters of the Zhujiang （Pearl） River estuary （ZRE） were measured. This was done for both winter （December） and summer （July） seasons, to quantitatively understand the seasonal characteristics of river plume flow rate and trajectories, as well as the ecological response. The results show that Ra concentrations in summer were higher than in winter, especially Z24Ra （about 2-5 times higher）. The spatial distribution of three Ra isotopes and relative Ra water ages indicated that river water mainly flushed out of ZRE through the western side in winter, where the water transport was about 5 days faster than in the eastern zone. In summer, diluted river water expended to the east side, resulting in fairly similar water ages for both sides of the river mouth. Although nutrients were higher during the summer season, lower chl-a concentrations indicated that reduced primary production might be caused by high SPM （low light penetration）. The results obtained from this study will provide knowledge needed for effectively developing and managing the ZRE.

Screening-Dependent Study of Superconductivity in 3d-Transition Metals Binary Alloys Superconductors

In the present article, we report the screening-dependent study of the superconducting state parameters （SSPs）, viz. electron-phonon coupling strength A, Coulomb pseudopotential μ^＊, transition temperature TC, isotope effect exponent a, and effective interaction strength No V of 3d-band transition metals binary alloys superconductors have been made extensively in the present work using a model potential formalism and employing the pseudo-alloy-atom （PAA） model for the first time. Five local field correction functions proposed by Hartree （H）, Taylor （T）, Ichimaru-Utsumi （IU）, Farid et al. （F） and Sarkar et al. （S） are used in the present investigation to study the screening influence on the aforesaid properties. The present results of the SSPs obtained from H-screening are found in qualitative agreement with the available experimental data wherever exist.

Laser-induced Fluorescence Spectroscopy of NiCl in 12900-15000 cm-1

Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13.0]2II3/2（v＇=0-5）-X2II3/2（v＂=0） transition progression. The relevant rotational constants, significant isotopic shifts, and （equilibrium） molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.

Genesis and Quality of Groundwater in the Southeastern Region of Southern Vietnam

The origin and quality of groundwater in the Southeastern region （belongs to Southern Plain） were identified by using isotopic techniques and geochemical analysis. Groundwater samples were collected from 7 aquifers： the Holocene, upper Pleistocene, middle Pleistocene, lower Pleistocene, upper Pliocene, middle Pliocene and Miocene aquifers. The water isotopic compositions （82H and 8180） were determined to elucidate the origin and the interaction between surface water and groundwater studies. Transit time （age） of the groundwater samples was determined to explain the direction of groundwater flow. The dating techniques included 3H and ^14C isotopes measurement, followed by a correction for the initial ^14C-activity by the ^13C-composition （^13C） in TDIC （Total Dissolved Inorganic Carbon）. Geochemical parameters of the groundwater samples were measured either directly in the field or in the laboratory. The results showed that the groundwater from the Holocene and upper Pleistocene aquifers was most recharged from the local meteorological and hydrological systems, including local precipitation, fiver and reservoirs. Thus, it has short transit time and its stable isotopic composition is spread around the local meteoric waterline and lines for rivers or reservoirs water. The groundwater in the deeper aquifers： middle and lower Pleistocene, and Neogene aquifers has old age up to 22.5 ka BP. Its water seems to be recharged from the areas with an altitude from 600 to 700 m higher to the Neogene deposit layer altitude. The groundwater in the SE SP （South-Eastern Southern Plain） region has a high quality. The water type is Na-Ca-Mg-HCO3 with low content of chloride and TDS （Total Dissolved Solids）. Calcite/dolomite and gypsum dissolution, organic matter decomposition and sequence of red-ox reactions proceeding through different electron acceptors sediment were controlled the chemistry of the groundwater in the study region.

通往未来之路

对国际原子能机构第十一届科学论坛上提出的国际原子能机构未来作用的思考在这个不断变革的时代,人们常说,"未来往往突然降临"。因此,各组织面临着努力明辨可能影响其未来之趋势并绘制其前行之蓝图的持续挑战。人们承认,对于未来蕴藏着什么,存在并将继续存在着不同的期望。

Multi-quasiparticle rotational bands in neutron-rich erbium isotopes

Multi-quasiparticle states and rotational bands in neutron-rich erbium isotopes have been investigated by the configuration- constrained pairing-deformation-frequency self-consistent total-Routhian-surface （TRS） method with particle-number-conserved pairing. Specifically, the recently observed Kπ = 4- bands in 168,170,172Er have been found to experience a configuration change in our calculation. Some other multi-quasiparticle states with uncertain configuration assignments have been reinvestigated by calculating their collective rotations. The configuration-constrained TRS calculation can reproduce experimental data consistently.

A new paleoenvironmental index for anoxic events—Mo isotopes in black shales from Upper Yangtze marine sediments

This paper investigates the high-solution of Mo isotopes and uses trace-element analyses for fresh and representative black shales and siliceous shales collected from the transition between the Late Ordovician and the Early Silurian at the Wangjiawan section in Yichang and the Late Permian Dalong Formation in the Shangsi Section of Sichuan. The applicability of different geochemical parameters used as paleo-oxygenation indices are also compared. The preliminary results show that V/（V＋Ni）, Uauth （auth U）, V/Cr, Ceanom and U/Th have a scattered variation range, but most samples plot within the suboxic-anoxic fields. The suboxic-anoxic environment was dominant during the deposition and formation of the two anoxic facies. These redox indicators show little correspondence to the δ98M0 values. The U/Mo ratio can be used as a potential proxy for the paleo-redox conditions due to the possibility that Mo is enriched relative to U at different redox gradients during early diagenesis. This evidence is more significant for the euxinicity condition and corresponds to positive δ98M0 （〉1.5%o） values with low U/Mo ratios. This evidence is likely related to the depositional conditions near the boundary between anoxic and euxinic environ- ments, which are characterised by low bioturbation or water circulation. Other samples reveal a wide scatter of U/Mo ratios and δ98M0 〈1.5%0. These results are likely due to punctuated improvements in oxygenation with intense bioturbation or water circulation, which led to the redistribution of trace element.

Petrogenesis and tectonic setting of the Queershan composite granitic pluton, eastern Tibetan Plateau: Constraints from geochronology, geochemistry and Hf isotope data

The Queershan composite granitic pluton is located in the north of the late Paleozoic Yidun arc collision-orogenic belt, eastern Tibetan Plateau. The main rock types are coarse-grained porphyritic alkalic-monzonite granite with minor fine-grained porphyritic monzogranite and granodiorite distributed in the eastern and southwestern regions. Here we report their zircon U-Pb ages and geo chemical data. The intrusive contact relations indicate that granodiorite was formed earlier than the alkalic-monzonite granite （105.9±1.3 Ma） and monzogranite （102.6±1.1 Ma）. These suggest that the Queershan composite granitic pluton was formed through three-stage magmatic events. The alkalic-monzonite granite （105.9±1.3 Ma） and monzogranite （102.6±1.1 Ma） are characterized by high SiO2 （73.5%-77.7%）, KzO＋Na20 （6.9%-8.5%）, Ga/AI ratios （2.6-3.4） and low A1203 （11.8%-14.5%）, CaO （0.25%-1.5%）, MgO （0.18%-0.69%）, negative Ba, Sr and Eu anomalies, showing A-type granite affinities. The granodi- orite exhibits lower SiO2, P205 and K20＋Na20 contents, but higher A1203, CaO and MgO contents than alkalic-monzonite granite and monzogranite, showing I-type granite affinity. 176Hff177Hf ratios of the alkalic-monzonite granite and the monzogranite are 0.282692-0.282749 and 0.282685-0.282765, respectively, and with similar cHf（t） values （-0.56 to 1.43 and -0.87 to 1.90 respectively）. They also present similar T1-M2 model ages （1.04-1.22 and 1.07-1.2 Ga respectively）, indicating they may be sourced from a similar rock source, mostly like Kangding Complex. The homogeneity of the Hf isotopic compositions and the absence of the MMEs demonstrate that little depleted mantle materials have contributed to the source. We propose that the Mesoproterozoic crust materials of the Yangtze Craton exist beneath the Yidun arc terrane and support it was a dismembered part of the Yangtze Craton. The A-type granites of Queershan composite granitic pluton are most probably related to the clo- sure of the Bangong-Nujiang Tethys ocean.

Description of the shape coexistence in neutron-deficient ^(74,76)Kr with IBM2

The shape deformation and shape coexistence in ^(74,76) Kr isotopes are investigated within the framework of the proton-neutron interacting boson model(IBM2). By considering the relative energy of the d proton boson to be different from that of the neutron boson, the low-lying energy spectrum is in good agreement with experimental results both qualitatively and quantitatively. In particular, the low-lying 0_2^+ states associated with the shape-coexistence phenomenon are reproduced quite well. The calculated key sensitive quantities of B(E2) transition branch ratios are fairly consistent with the experimental data except for R_4. The predicated deformation parameter is very similar for the ground states in ^(74)Kr and ^(76)Kr, showing good agreement with the experimental result,and the calculated deformation parameter for the second 0^+ state in ^(74)Kr is close to the experimental data. The calculated results of the triaxiality parameter indicated an almost purely prolate shape for the ground state of ^(76)Kr and a mostly prolate shape with a little triaxiality for the ground state of ^(74)Kr. The calculations also show an oblate triaxial shape for the second 0^+ state in ^(76)Kr and maximum triaxiality for the second 0^+ state in ^(74)Kr. These results confirm the importance of the triaxial deformation for the description of such shape coexistence.

Efect of Tensor Force on the Halo Structure of ^(29)Ne and ^(31)Ne

The structure of Ne isotopes has been investigated by using deformed Skyrme-Hartree-Fock （SHF） method and BCS approximation. Especially the effect of tensor force on the halo structure of 29Ne and 31Ne is discussed. To this end, the tensor contributions are considered to the energy density function and the single particle potential in SHF theory. For comparison, four Skyrme interactions are used： SLy5 and SGII without tensor force, and SLy5＋T and SGII＋ T with tensor force. The results indicate that the inclusion of tensor force shows a more pronounced halo structure for 31Ne.

Effects of Isotopic Concentrations on Thermodynamic Parameters of Deuterium-Tritium Mixtures

Thermodynamic estimation is still too much requested for scientific applications in spite of great advances in simulation methods for efficient determination of phase equilibrium of multi-component systems. In this work, thermodynamic properties of deuterium-tritium mixture in a wide range of temperatures and pressures have been predicted. Buckingham exp-6 potential has been utilized in calculations, based on statistical perturbation theory. The effects of various values of density, temperature and isotopic concentrations on pressure have been studied. Eventually, we have found out symmetrical effects of tritium concentration in deuterium-tritium mixtures.

Structure Evolution in the Even-Even ^124-134Xe with IBM2

We have investigated the structure evolution of the ^124-134Xe isotopic chain in the framework of the proton-neutron interacting model IBM2. The positive parity spectra of the ground state, quasi-β and quasi-γ bands are reproduced well. The staggering in ^124-130Xe are almost completely removed and the ？ band agree well with the experiment data, even for the high-spin quasi-3 states. The key quantities of the collective structure evolution, including level energies, the B（E2） transition branching ratios, and the M1 excitations to 11^＋ mixer-symmetry states are analyzed by comparing with the experimental data. The parameters for representation of the Oπν（6） and SUπν^＊（3） features in isotopes are examined. Both experimental data and theoretical results show that the shape phase transition of ^124-134Xe isotopic chain is from the SUπν^＊ （3） （triaxial rotation） to the Uπν（5） （vibration motion） with a considerable constituent of the Oπν（6） symmetry （γ-unstable rotation）, where the shape phase transition rapidly takes place between the neutron number N = 76 and N = 78.

Source of the condensates from the Hetianhe Field and the genetic relationship between the condensates and their associated gases

A detailed correlation of Hetianhe condensates versus typical source rocks from the Tarim Basin was established. Moreover, the genetic relationship between the condensates and their associated gases was also studied based on their geochemical com- positions and fluid inclusion data. Hetianhe condensates are characterized by high pristine/phytane （Pr/Ph） ratios, high relative abundances of Czs regular steranes, C26-C27 triaromatic steroids, and triaromatic dinosteranes, and relatively heavy stable car- bon isotopic compositions. They geochemically correlate well with the Cambrian source rocks, indicating that these conden- sates are derived from the Cambrian rocks. Based on several molecular maturity parameters, the condensates are recognized as being moderately to highly mature, which are too low in maturity to extensively crack into gases. The gases and condensates of the Hetianhe Field are derived from the same source rocks and the gases are from oil-cracking; however, clear evidence indi- cates that the gases were not cracked from their associated condensates and that the gas generation from oil-cracking did not occur in the present reservoirs. The liquid condensates produced from wellheads were likely dissolved in their associated gases underground and carried into the reservoirs by the gases.