The pyrolysis of pyridine （5.26% pyridine in argon） was performed with tunable synchrotron vacuum ultraviolet photoionization and molecular-beam mass spectrometry technique at the temperature range of 1255-1765 K at...The pyrolysis of pyridine （5.26% pyridine in argon） was performed with tunable synchrotron vacuum ultraviolet photoionization and molecular-beam mass spectrometry technique at the temperature range of 1255-1765 K at 267 Pa. About 20 products and intermediates, containing major species H2, HCN, C2H2, C5H3N, C4H2, and C3H3N, were identified by near-threshold measurements of photoionization mass spectra and their mole fractions vs. temperatures were estimated. The major reaction pathways are analyzed based on the experimental observations.展开更多
A comprehensive experimental study of the premixed ethylene/oxygen/argon flame at 2.667 kPa with a stoichiometric equivalence ratio （Ф=1） was performed with the tunable synchrotron photoionization and molecular-bea...A comprehensive experimental study of the premixed ethylene/oxygen/argon flame at 2.667 kPa with a stoichiometric equivalence ratio （Ф=1） was performed with the tunable synchrotron photoionization and molecular-beam sampling mass spectrometry techniques. The isomers of most observed species in the flame were unambiguously identified by measurements of the photoionization etticiency spectra, e.g. C3H4, C2H4O and C4H4. The mole fraction profiles of species up to C7H8 were measured by scanning the burner position at the selected photon energies near ionization thresholds, and the flame temperature profile was obtained by using Pt/Pt-13%Rh thermocouple. Compared with the previous studies, a lot of new flame species： C3H2, C3H3, C3H5, C2H6O, C4H2, C4H4, C4H6, C3H4O, C3H6O, C3H8O, C5H6, C4H8O and C7H8, were observed. A series of free radicals in the flame are detected to be CH3, C2H3, C2H5, HCO, C3H3 and C3H5. Based on the experimental work, a reduced reaction mechanism was developed including 40 species and 223 reactions. Modeling and measurements agree well for the major species and most intermediates. A detailed kinetic model is desired for this flame.展开更多
To eliminate harmonic pollution incurred from the static synchronous compensator(STATCOM), a method of applying artificial neural network is presented. When PWM wave is formed based on the harmonic suppression theory,...To eliminate harmonic pollution incurred from the static synchronous compensator(STATCOM), a method of applying artificial neural network is presented. When PWM wave is formed based on the harmonic suppression theory, a concave is set on certain angle of the square wave to suppress unnecessary harmonics, by timely and on-line determining the chopping angle corresponding to respective harmonics through artificial neural network, i.e. by setting the position of concave to eliminate corresponding harmonics, the harmonic component on output voltage of the inverter can be improved. To conclude through computer simulation test, the perfect control effect has been proved.展开更多
基金Ⅴ. ACKNOWLEDGMENTS This work was supported by the Chinese Academy of Sciences, the Natural Science Foundation of China （No.20533040）, the National Basic Research Program of China （973） （No.2007CB815204m）, and the Ministry of Science and Technology of China （No.2007DFA61310）.
文摘The pyrolysis of pyridine （5.26% pyridine in argon） was performed with tunable synchrotron vacuum ultraviolet photoionization and molecular-beam mass spectrometry technique at the temperature range of 1255-1765 K at 267 Pa. About 20 products and intermediates, containing major species H2, HCN, C2H2, C5H3N, C4H2, and C3H3N, were identified by near-threshold measurements of photoionization mass spectra and their mole fractions vs. temperatures were estimated. The major reaction pathways are analyzed based on the experimental observations.
基金Ⅵ. ACKN0WLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20473081 and No.20533040）, and Chinese Academy of Sciences. The authors are also thankful for the valuable help in the experimental work from Aigou Zhu. Fei Qi thanks the Combustion Research Facility of Sandia National Labs to provide a Chemkin program package for kinetic modeling study.
文摘A comprehensive experimental study of the premixed ethylene/oxygen/argon flame at 2.667 kPa with a stoichiometric equivalence ratio （Ф=1） was performed with the tunable synchrotron photoionization and molecular-beam sampling mass spectrometry techniques. The isomers of most observed species in the flame were unambiguously identified by measurements of the photoionization etticiency spectra, e.g. C3H4, C2H4O and C4H4. The mole fraction profiles of species up to C7H8 were measured by scanning the burner position at the selected photon energies near ionization thresholds, and the flame temperature profile was obtained by using Pt/Pt-13%Rh thermocouple. Compared with the previous studies, a lot of new flame species： C3H2, C3H3, C3H5, C2H6O, C4H2, C4H4, C4H6, C3H4O, C3H6O, C3H8O, C5H6, C4H8O and C7H8, were observed. A series of free radicals in the flame are detected to be CH3, C2H3, C2H5, HCO, C3H3 and C3H5. Based on the experimental work, a reduced reaction mechanism was developed including 40 species and 223 reactions. Modeling and measurements agree well for the major species and most intermediates. A detailed kinetic model is desired for this flame.
文摘To eliminate harmonic pollution incurred from the static synchronous compensator(STATCOM), a method of applying artificial neural network is presented. When PWM wave is formed based on the harmonic suppression theory, a concave is set on certain angle of the square wave to suppress unnecessary harmonics, by timely and on-line determining the chopping angle corresponding to respective harmonics through artificial neural network, i.e. by setting the position of concave to eliminate corresponding harmonics, the harmonic component on output voltage of the inverter can be improved. To conclude through computer simulation test, the perfect control effect has been proved.
