Mouse oocytes undergo polarization during meiotic maturation, and this polarization is essential for asymmetric cell divisions that maximize retention of maternal components required for early development. Without con...Mouse oocytes undergo polarization during meiotic maturation, and this polarization is essential for asymmetric cell divisions that maximize retention of maternal components required for early development. Without conventional centrosomes, the meiotic spindle has less focused poles and is barrel-shaped. The migration of meiotic spindles to the cortex is accompanied by a local reorganization and polarization of the cortex. LGN is a conserved protein involved in cell polarity and regulation of spindle organization. In the present study, we characterized the localization dynamics of LGN during mouse oocyte maturation and analyzed the effects of LGN upregulation and downregulation on meiotic spindle organization. At the germinal vesicle stage, LGN is distributed both cytoplasmically and at the cortex. During maturation, LGN localizes to the meiotic spindle apparatus and cortical LGN becomes less concentrated at the actin cap region. Excessive LGN induces meiotic spindle organization defects by elongating the spindle and enhancing pole focusing, whereas depletion of LGN by RNA interference results in meiotic spindle deformation and chromosome misalignment. Furthermore, the N-terminus of LGN has the ability of full-length LGN to regulate spindle organization, whereas the C-terminus of LGN controls cortical localization and polarization. Our results reveal that LGN is cortically polarized in mouse oocytes and is critical for meiotic spindle organization.展开更多
Based on analyses of the components of crude oil hydrocarbons and carbon isotopes,the content of normal alkane decreased from 49.00% to 20.10% when moving from the No.3 to No.5 tectonic belt of the Lenghu area of the ...Based on analyses of the components of crude oil hydrocarbons and carbon isotopes,the content of normal alkane decreased from 49.00% to 20.10% when moving from the No.3 to No.5 tectonic belt of the Lenghu area of the Qaidam Basin,while cycloalkanes increased from 30.00% to 52.20% and aromatic and branch chain alkanes increased gradually as well. The maturity of sterane in crude oil is higher than that of its source-rock,which shows that the hydrocarbons were generated from a deep source-rock of high maturity around the tectonic belts of the Lenghu area. The analysis of the characteristics of carbon isotopes also shows that these isotopes of hydrocarbon compounds in the No.4 and No.5 tectonic belt are apparently heavier than those in the No.3 belt. The results of our research show that the hydrocarbons in the No.3 tectonic belt are mainly from a relatively rich sapropelic substance,while the hydrocarbons in the No.4 and No.5 tectonic belt originated mainly from organic matter of a relatively rich humic type substance.展开更多
Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C,Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ13CPDB values of siderite wer...Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C,Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ13CPDB values of siderite were close to the δ13CPDB value of original magma; δ30Si values of the samples at the ore-forming stage were close to the δ30Si value range of magma, δ30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials.展开更多
The homologues temperature of a crystalline material is defined as T/Tm, where T is temperature and Tm is the melting (solidus) temperature in Kelvin. It has been widely used to compare the creep strength of crystal...The homologues temperature of a crystalline material is defined as T/Tm, where T is temperature and Tm is the melting (solidus) temperature in Kelvin. It has been widely used to compare the creep strength of crystalline materials. The melting temperature of olivine system, (Mg,Fe)2SiO4, decreases with increasing iron content and water content, and increases with confining pressure. At high pressure, phase transition will lead to a sharp change in the melting curve of olivine. After calibrating previous melting experiments on fayalite (Fe2SiO4), the triple point of fayalite-Fe2SiO4 spinel-liquid is determined to be at 6.4 GPa and 1793 K. Using the generalized means, the solidus and liquidus of dry olivine are described as a function of iron content and pressure up to 6.4 GPa. The change of T/Tm of olivine with depth allows us to compare the strength of the up- per mantle with different thermal states and olivine composition. The transition from semi-brittle to ductile deformation in the upper mantle occurs at a depth where T/Tm of olivine equals 0.5. The lithospheric mantle beneath cratons shows much smaller T/Tm of olivine than orogens and extensional basins until the lithosphere-asthenosphere boundary where T/Tm 〉 0.66, suggesting a stronger lithosphere beneath cratons. In addition, T/Tm is used to analyze deformation experiments on olivine. The results indicate that the effect of water on fabric transitions in olivine is closely related with pressure. The hydrogen-weakening effect and its relationship with T/Tm of olivine need further investigation. Below 6.4 GPa (〈200 kin), T/TIn of olivine controls the transition of dislocation glide from [100] slip to [001] slip. Under the strain rate of 10-12-10-15 s-1 and low stress in the upper mantle, the [100](010) slip system (A-type fabric) becomes dominant when T/TIn〉 0.55-0.60. When T/Tm〈 0.55-0.60, [001] slip is easier and low T/Tm favors the operation of [001](100) slip system (C-type fabric). This is consistent with the widely observed A-type olivine fabric in naturally deformed peridotites, and the C-type olivine fabric in peridotites that experienced deep subduction in ultrahigh-pressure metamorphic terranes. However, the B-type fabric will develop under high stress and relatively low T/Tm. Therefore, the homologues temperature of olivine established a bridge to extrapolate deformation experi- ments to rheology of the upper mantle. Seismic anisotropy of the upper mantle beneath cratons should be simulated using a four-layer model with the relic A-type fabric in the upper lithospheric mantle, the B-type fabric in the middle layer, the newly formed A- or B-type fabric near the lithosphere-asthenosphere boundary, and the asthenosphere dominated by diffusion creep below the Lehmann discontinuity. Knowledge about transition mechanisms of olivine fabrics is critical for tracing the water distribution and mantle flow from seismic anisotropy.展开更多
Plate subduction is an important mechanism for exchanging the mass and energy between the mantle and the crust,and the igneous rocks in subduction zones are the important carriers for studying the recycling of crustal...Plate subduction is an important mechanism for exchanging the mass and energy between the mantle and the crust,and the igneous rocks in subduction zones are the important carriers for studying the recycling of crustal materials and the crust-mantle interaction.This study presents a review of geochronology and geochemistry for postcollisional mafic igneous rocks from the Hong’an-Dabie-Sulu orogens and the southeastern edge of the North China Block.The available results indicate two types of the crust-mantle interaction in the continental subduction zone,which are represented by two types of mafic igneous rocks with distinct geochemical compositions.The first type of rocks exhibit arc-like trace element distribution patterns(i.e.enrichment of LILE,LREE and Pb,but depletion of HFSE)and enriched radiogenic Sr-Nd isotope compositions,whereas the second type of rocks show OIB-like trace element distribution patterns(i.e.enrichment of LILE and LREE,but no depletion of HFSE)and depleted radiogenic Sr-Nd isotope compositions.Both of them have variable zircon O isotope compositions,which are different from those of the normal mantle zircon,and contain residual crustal zircons.These geochemical features indicate that the two types of mafic igneous rocks were originated from the different natures of mantle sources.The mantle source for the second type of rocks would be generated by reaction of the overlying juvenile lithospheric mantle with felsic melts originated from previously subducted oceanic crust,whereas the mantle source for the first type of rocks would be generated by reaction of the overlying ancient lithospheric mantle of the North China Block with felsic melts from subsequently subducted continental crust of the South China Block.Therefore,there exist two types of the crust-mantle interaction in the continental subduction zone,and the postcollisional mafic igneous rocks provide petrological and geochemical records of the slab-mantle interactions in continental collision orogens.展开更多
Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas ge...Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter (solid bitumen and heavy oil), and kerogen. order of crude oil (light oil and condensate), dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln(CffC3) can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln(CJC2)-(δ13C1-δ13C2) can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.展开更多
Magnetite separates from the Shaquanzi Fe-Cu deposit in the eastern Tianshan are used for Re-Os geochronological study. Re-Os data show that magnetite separates contain ca. 0.7 to 50.9 ppb Re and ca. 16 to 63 ppt Os. ...Magnetite separates from the Shaquanzi Fe-Cu deposit in the eastern Tianshan are used for Re-Os geochronological study. Re-Os data show that magnetite separates contain ca. 0.7 to 50.9 ppb Re and ca. 16 to 63 ppt Os. Eight samples yield a model 3 isochron age of (303 ±12) Ma (2or), which is within uncertainty consistent with of the Re-Os date (295±7 Ma) of associated pyrite. Tectonic evolution shows that the Late Carboniferous Aqishan-Yamansu belt was a back-arc rift. Therefore, the Re-Os age of ca. 300 Ma indicates that the Shaquanzi Fe-Cu deposit may have formed in a back-arc extensional environment and was closely related to mantle-derived magmatism. The successful application of Re-Os magnetite geochronology in the Shaquanzi Fe-Cu deposit suggests that the purity of magnetite, relatively high Re and Os contents, and the closure of Re-Os systematic are base factors for a successful Re-Os geochronology. There would be a good prospect for Re-Os geochronology for magnet- ite.展开更多
Aromatic hydrocarbons are generally main distillation of crude oil and organic extract of source rocks. Bicyclic and tricyclic aromatic hydrocarbons can be purified by two-step method of chromatography on alumina. Car...Aromatic hydrocarbons are generally main distillation of crude oil and organic extract of source rocks. Bicyclic and tricyclic aromatic hydrocarbons can be purified by two-step method of chromatography on alumina. Carbon isotopic composition of in- dividual aromatic hydrocarbons is affected not only by thermal maturity, but also by organic matter input, depositional envi- ronment, and hydrocarbon generation process based on the GC-IRMS analysis of Upper Ordovician, Lower Ordovician, and Cambrian source rocks in different areas in the Tarim Basin, western China. The subgroups of aromatic hydrocarbons as well as individual aromatic compound, such as 1-MP, 9-MP, and 2,6-DMP from Cambrian-Lower Ordovician section show more depleted 13C distribution. The δ13C value difference between Cambrian-Lower Ordovician section and Upper Ordovician source rocks is up to 16.1%o for subgroups and 14%o for individual compounds. It can provide strong evidence for oil source correlation by combing the δ13C value and biomarker distribution of different oil and source rocks from different strata in the Tarim Basin. Most oils from Tazhong area have geochemical characteristics such as more negative δI3Cg_Mp value, poor gam macerane, and abundant homohopanes, which indicate that Upper Ordovician source rock is the main source rock. In contrast, oils from Tadong area and some oils from Tazhong area have geochemical characteristics such as high 613C9-MP, value, abun dant gammacerane, and poor homohopanes, which suggest that the major contributor is Cambrian-Lower Ordovician source rock.展开更多
The water contents of minerals and whole-rock in mantle-derived xenoliths from eastern China exhibit large variations and are generally lower than those from other on- and off-craton lithotectonic units. Nevertheless,...The water contents of minerals and whole-rock in mantle-derived xenoliths from eastern China exhibit large variations and are generally lower than those from other on- and off-craton lithotectonic units. Nevertheless, the water contents of mineral and whole-rock in Junan peridotite xenoliths, which sourced from the juvenile lithospheric mantle, are generally higher than those elsewhere in eastern China. This suggests that the initial water content of juvenile lithospheric mantle is not low. There is no obvious correlation between the water contents and Mg~# values of minerals in the mantle xenoliths and no occurrence of diffusion profile in pyroxene, suggesting no relationship between the low water content of mantle xenolith and the diffusion loss of water during xenolith ascent with host basaltic magmas. If the subcontinental lithospheric mantle(SCLM) base is heated by the asthenospheric mantle, the diffusion loss of water is expected to occur. On the other hand, extraction of basaltic melts from the SCLM is a more efficient mechanism to reduce the water content of xenoliths. The primary melts of Mesozoic and Cenozoic basalts in eastern China have water contents, as calculated from the water contents of phenocrysts, higher than those of normal mid-ocean ridge basalts(MORB). The Mesozoic basalts exhibit similar water contents to those of island arc basalts, whereas the Cenozoic basalts exhibit comparable water contents to oceanic island basalts and backarc basin basalts with some of them resembling island arc basalts. These observations suggest the water enrichment in the mantle source of continental basalts due to metasomatism by aqueous fluids and hydrous melts derived from dehydration and melting of deeply subducted crust. Mantle-derived megacrysts, minerals in xenoliths and phenocrysts in basalts from eastern China also exhibit largely variable hydrogen isotope compositions, indicating a large isotopic heterogeneity for the Cenozoic SCLM in eastern China. The water content that is higher than that of depleted MORB mantle and the hydrogen isotope composition that is deviated from that of depleted MORB mantle suggest that the Cenozoic continental lithospheric mantle suffered the metasomatism by hydrous melts derived from partial melting of the subducted Pacific slab below eastern China continent. The metasomatism would lead to the increase of water content in the SCLM base and then to the decrease of its viscosity. As a consequence, the SCLM base would be weakened and thus susceptible to tectonic erosion and delamination. As such, the crust-mantle interaction in oceanic subduction channel is the major cause for thinning of the craton lithosphere in North China.展开更多
文摘Mouse oocytes undergo polarization during meiotic maturation, and this polarization is essential for asymmetric cell divisions that maximize retention of maternal components required for early development. Without conventional centrosomes, the meiotic spindle has less focused poles and is barrel-shaped. The migration of meiotic spindles to the cortex is accompanied by a local reorganization and polarization of the cortex. LGN is a conserved protein involved in cell polarity and regulation of spindle organization. In the present study, we characterized the localization dynamics of LGN during mouse oocyte maturation and analyzed the effects of LGN upregulation and downregulation on meiotic spindle organization. At the germinal vesicle stage, LGN is distributed both cytoplasmically and at the cortex. During maturation, LGN localizes to the meiotic spindle apparatus and cortical LGN becomes less concentrated at the actin cap region. Excessive LGN induces meiotic spindle organization defects by elongating the spindle and enhancing pole focusing, whereas depletion of LGN by RNA interference results in meiotic spindle deformation and chromosome misalignment. Furthermore, the N-terminus of LGN has the ability of full-length LGN to regulate spindle organization, whereas the C-terminus of LGN controls cortical localization and polarization. Our results reveal that LGN is cortically polarized in mouse oocytes and is critical for meiotic spindle organization.
基金Project 2009011 supported by the Resource Exploration Projects of the Ministry of Land and Resources of Chinathe State Key Laboratory of Petroleum Resource and Prospecting of China Petroleum University (Beijing)
文摘Based on analyses of the components of crude oil hydrocarbons and carbon isotopes,the content of normal alkane decreased from 49.00% to 20.10% when moving from the No.3 to No.5 tectonic belt of the Lenghu area of the Qaidam Basin,while cycloalkanes increased from 30.00% to 52.20% and aromatic and branch chain alkanes increased gradually as well. The maturity of sterane in crude oil is higher than that of its source-rock,which shows that the hydrocarbons were generated from a deep source-rock of high maturity around the tectonic belts of the Lenghu area. The analysis of the characteristics of carbon isotopes also shows that these isotopes of hydrocarbon compounds in the No.4 and No.5 tectonic belt are apparently heavier than those in the No.3 belt. The results of our research show that the hydrocarbons in the No.3 tectonic belt are mainly from a relatively rich sapropelic substance,while the hydrocarbons in the No.4 and No.5 tectonic belt originated mainly from organic matter of a relatively rich humic type substance.
文摘Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C,Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ13CPDB values of siderite were close to the δ13CPDB value of original magma; δ30Si values of the samples at the ore-forming stage were close to the δ30Si value range of magma, δ30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41590623 & 41172182)the Ministry of Land Resources Public Welfare Industry Special Scientific Research Projects (Grant No. 201311178-3)
文摘The homologues temperature of a crystalline material is defined as T/Tm, where T is temperature and Tm is the melting (solidus) temperature in Kelvin. It has been widely used to compare the creep strength of crystalline materials. The melting temperature of olivine system, (Mg,Fe)2SiO4, decreases with increasing iron content and water content, and increases with confining pressure. At high pressure, phase transition will lead to a sharp change in the melting curve of olivine. After calibrating previous melting experiments on fayalite (Fe2SiO4), the triple point of fayalite-Fe2SiO4 spinel-liquid is determined to be at 6.4 GPa and 1793 K. Using the generalized means, the solidus and liquidus of dry olivine are described as a function of iron content and pressure up to 6.4 GPa. The change of T/Tm of olivine with depth allows us to compare the strength of the up- per mantle with different thermal states and olivine composition. The transition from semi-brittle to ductile deformation in the upper mantle occurs at a depth where T/Tm of olivine equals 0.5. The lithospheric mantle beneath cratons shows much smaller T/Tm of olivine than orogens and extensional basins until the lithosphere-asthenosphere boundary where T/Tm 〉 0.66, suggesting a stronger lithosphere beneath cratons. In addition, T/Tm is used to analyze deformation experiments on olivine. The results indicate that the effect of water on fabric transitions in olivine is closely related with pressure. The hydrogen-weakening effect and its relationship with T/Tm of olivine need further investigation. Below 6.4 GPa (〈200 kin), T/TIn of olivine controls the transition of dislocation glide from [100] slip to [001] slip. Under the strain rate of 10-12-10-15 s-1 and low stress in the upper mantle, the [100](010) slip system (A-type fabric) becomes dominant when T/TIn〉 0.55-0.60. When T/Tm〈 0.55-0.60, [001] slip is easier and low T/Tm favors the operation of [001](100) slip system (C-type fabric). This is consistent with the widely observed A-type olivine fabric in naturally deformed peridotites, and the C-type olivine fabric in peridotites that experienced deep subduction in ultrahigh-pressure metamorphic terranes. However, the B-type fabric will develop under high stress and relatively low T/Tm. Therefore, the homologues temperature of olivine established a bridge to extrapolate deformation experi- ments to rheology of the upper mantle. Seismic anisotropy of the upper mantle beneath cratons should be simulated using a four-layer model with the relic A-type fabric in the upper lithospheric mantle, the B-type fabric in the middle layer, the newly formed A- or B-type fabric near the lithosphere-asthenosphere boundary, and the asthenosphere dominated by diffusion creep below the Lehmann discontinuity. Knowledge about transition mechanisms of olivine fabrics is critical for tracing the water distribution and mantle flow from seismic anisotropy.
基金supported by the Chinese Ministry of Science and Techno-logy(Grant No.2015CB856102)the National Natural Science Foundation of China(Grant Nos.41125012,41221062)
文摘Plate subduction is an important mechanism for exchanging the mass and energy between the mantle and the crust,and the igneous rocks in subduction zones are the important carriers for studying the recycling of crustal materials and the crust-mantle interaction.This study presents a review of geochronology and geochemistry for postcollisional mafic igneous rocks from the Hong’an-Dabie-Sulu orogens and the southeastern edge of the North China Block.The available results indicate two types of the crust-mantle interaction in the continental subduction zone,which are represented by two types of mafic igneous rocks with distinct geochemical compositions.The first type of rocks exhibit arc-like trace element distribution patterns(i.e.enrichment of LILE,LREE and Pb,but depletion of HFSE)and enriched radiogenic Sr-Nd isotope compositions,whereas the second type of rocks show OIB-like trace element distribution patterns(i.e.enrichment of LILE and LREE,but no depletion of HFSE)and depleted radiogenic Sr-Nd isotope compositions.Both of them have variable zircon O isotope compositions,which are different from those of the normal mantle zircon,and contain residual crustal zircons.These geochemical features indicate that the two types of mafic igneous rocks were originated from the different natures of mantle sources.The mantle source for the second type of rocks would be generated by reaction of the overlying juvenile lithospheric mantle with felsic melts originated from previously subducted oceanic crust,whereas the mantle source for the first type of rocks would be generated by reaction of the overlying ancient lithospheric mantle of the North China Block with felsic melts from subsequently subducted continental crust of the South China Block.Therefore,there exist two types of the crust-mantle interaction in the continental subduction zone,and the postcollisional mafic igneous rocks provide petrological and geochemical records of the slab-mantle interactions in continental collision orogens.
基金supported by Petroleum & Chemical United Fund Project(Grant No. 40739902)
文摘Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter (solid bitumen and heavy oil), and kerogen. order of crude oil (light oil and condensate), dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln(CffC3) can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln(CJC2)-(δ13C1-δ13C2) can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.
基金financially supported by the National Basic Research Program of China(Grant No.2012CB416804)the ‘‘CAS Hundred Talents’’ Project from the Chinese Academy of Sciences(Grant No.KZCX2-YW-BR-09)to Qi Liang
文摘Magnetite separates from the Shaquanzi Fe-Cu deposit in the eastern Tianshan are used for Re-Os geochronological study. Re-Os data show that magnetite separates contain ca. 0.7 to 50.9 ppb Re and ca. 16 to 63 ppt Os. Eight samples yield a model 3 isochron age of (303 ±12) Ma (2or), which is within uncertainty consistent with of the Re-Os date (295±7 Ma) of associated pyrite. Tectonic evolution shows that the Late Carboniferous Aqishan-Yamansu belt was a back-arc rift. Therefore, the Re-Os age of ca. 300 Ma indicates that the Shaquanzi Fe-Cu deposit may have formed in a back-arc extensional environment and was closely related to mantle-derived magmatism. The successful application of Re-Os magnetite geochronology in the Shaquanzi Fe-Cu deposit suggests that the purity of magnetite, relatively high Re and Os contents, and the closure of Re-Os systematic are base factors for a successful Re-Os geochronology. There would be a good prospect for Re-Os geochronology for magnet- ite.
基金supported by National Natural Science Foundation of China(Grant No.40973041)College Fund for the Doctoral Project(Grant No.20104220110001)Natural Science Foundation of Hubei Province(Grant No.2009CDB205)
文摘Aromatic hydrocarbons are generally main distillation of crude oil and organic extract of source rocks. Bicyclic and tricyclic aromatic hydrocarbons can be purified by two-step method of chromatography on alumina. Carbon isotopic composition of in- dividual aromatic hydrocarbons is affected not only by thermal maturity, but also by organic matter input, depositional envi- ronment, and hydrocarbon generation process based on the GC-IRMS analysis of Upper Ordovician, Lower Ordovician, and Cambrian source rocks in different areas in the Tarim Basin, western China. The subgroups of aromatic hydrocarbons as well as individual aromatic compound, such as 1-MP, 9-MP, and 2,6-DMP from Cambrian-Lower Ordovician section show more depleted 13C distribution. The δ13C value difference between Cambrian-Lower Ordovician section and Upper Ordovician source rocks is up to 16.1%o for subgroups and 14%o for individual compounds. It can provide strong evidence for oil source correlation by combing the δ13C value and biomarker distribution of different oil and source rocks from different strata in the Tarim Basin. Most oils from Tazhong area have geochemical characteristics such as more negative δI3Cg_Mp value, poor gam macerane, and abundant homohopanes, which indicate that Upper Ordovician source rock is the main source rock. In contrast, oils from Tadong area and some oils from Tazhong area have geochemical characteristics such as high 613C9-MP, value, abun dant gammacerane, and poor homohopanes, which suggest that the major contributor is Cambrian-Lower Ordovician source rock.
基金supported by funds from the Chinese Ministry of Science and Technology (Grant No. 2015CB856100)the National Natural Science Foundation of China (Grant Nos. 41303005 & 41590620)the Fundamental Research Funds for the Central Universities
文摘The water contents of minerals and whole-rock in mantle-derived xenoliths from eastern China exhibit large variations and are generally lower than those from other on- and off-craton lithotectonic units. Nevertheless, the water contents of mineral and whole-rock in Junan peridotite xenoliths, which sourced from the juvenile lithospheric mantle, are generally higher than those elsewhere in eastern China. This suggests that the initial water content of juvenile lithospheric mantle is not low. There is no obvious correlation between the water contents and Mg~# values of minerals in the mantle xenoliths and no occurrence of diffusion profile in pyroxene, suggesting no relationship between the low water content of mantle xenolith and the diffusion loss of water during xenolith ascent with host basaltic magmas. If the subcontinental lithospheric mantle(SCLM) base is heated by the asthenospheric mantle, the diffusion loss of water is expected to occur. On the other hand, extraction of basaltic melts from the SCLM is a more efficient mechanism to reduce the water content of xenoliths. The primary melts of Mesozoic and Cenozoic basalts in eastern China have water contents, as calculated from the water contents of phenocrysts, higher than those of normal mid-ocean ridge basalts(MORB). The Mesozoic basalts exhibit similar water contents to those of island arc basalts, whereas the Cenozoic basalts exhibit comparable water contents to oceanic island basalts and backarc basin basalts with some of them resembling island arc basalts. These observations suggest the water enrichment in the mantle source of continental basalts due to metasomatism by aqueous fluids and hydrous melts derived from dehydration and melting of deeply subducted crust. Mantle-derived megacrysts, minerals in xenoliths and phenocrysts in basalts from eastern China also exhibit largely variable hydrogen isotope compositions, indicating a large isotopic heterogeneity for the Cenozoic SCLM in eastern China. The water content that is higher than that of depleted MORB mantle and the hydrogen isotope composition that is deviated from that of depleted MORB mantle suggest that the Cenozoic continental lithospheric mantle suffered the metasomatism by hydrous melts derived from partial melting of the subducted Pacific slab below eastern China continent. The metasomatism would lead to the increase of water content in the SCLM base and then to the decrease of its viscosity. As a consequence, the SCLM base would be weakened and thus susceptible to tectonic erosion and delamination. As such, the crust-mantle interaction in oceanic subduction channel is the major cause for thinning of the craton lithosphere in North China.