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羧酸吡啶类氢键液晶分子的合成及表征
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作者 程显光 韩相恩 +2 位作者 贾永飞 冯卫方 韩辉 《化工新型材料》 CAS CSCD 北大核心 2010年第3期91-92,117,共3页
以4-己氧基苯甲酸为质子给体,4-硝基苯乙烯基吡啶为受体,四氢呋喃为溶剂,制备了一种液晶超分子复合物—羧酸吡啶类氢键自主装型液晶复合物,用DSC和热台偏光显微镜对所合成化合物进行了相态和液晶性研究,并用IR1、H-NMR对所合成化合物进... 以4-己氧基苯甲酸为质子给体,4-硝基苯乙烯基吡啶为受体,四氢呋喃为溶剂,制备了一种液晶超分子复合物—羧酸吡啶类氢键自主装型液晶复合物,用DSC和热台偏光显微镜对所合成化合物进行了相态和液晶性研究,并用IR1、H-NMR对所合成化合物进行了结构表征。结果表明:合成了目标化合物;IR结果证明了羧基和吡啶环间分子间氢键代替了羧基间的分子间氢键;相态及液晶行为研究证明了氢键复合物具有典型的热致液晶性能且呈现明显的向列型液晶态。 展开更多
关键词 羧酸吡啶类 氢键液晶分子 相态和液晶 向列性液晶 合成 表征
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SYNTHESIS AND CHARAOTERIZATION OF NOVEL THERMOTROPIO LIQUID ORYSTALLINE POLYESTERS BEARING NONLINEAR OPTICAL AZOBENZENE SIDE GROUP
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作者 张会旗 张莹 +2 位作者 甘湘萍 阴航明 孙经武 《Transactions of Tianjin University》 EI CAS 1999年第1期93-97,共5页
A series of novel thermotropic liquid crystalline polyesters bearing nonlinear optical azobenzene side group were synthesized by high temperature solution polycondensation and their structures,thermal stability, phas... A series of novel thermotropic liquid crystalline polyesters bearing nonlinear optical azobenzene side group were synthesized by high temperature solution polycondensation and their structures,thermal stability, phase transition behavior and crystallinity were characterized by IR,elemental analysis, TG-DTA, polarizing optical microscope (POM) equipped with a hot stage and X-ray diffraction techniques. The results demonstrate that all the synthesized polyesters exhibit nematic liquid crystalline phases and show relatively high glass transition temperatures and good thermal stability. 展开更多
关键词 AZOBENZENE POLYESTER thermotropic liquid crystalline polymer nematic phase nonlinear optical material
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Global well-posedness for the dynamical Q-tensor model of liquid crystals 被引量:2
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作者 HUANG JinRui DING ShiJin 《Science China Mathematics》 SCIE CSCD 2015年第6期1349-1366,共18页
We consider a complex fluid modeling nematic liquid crystal flows, which is described by a system coupling Navier-Stokes equations with a parabolic Q-tensor system. We first prove the global existence of weak solution... We consider a complex fluid modeling nematic liquid crystal flows, which is described by a system coupling Navier-Stokes equations with a parabolic Q-tensor system. We first prove the global existence of weak solutions in dimension three. Furthermore, the global well-posedness of strong solutions is studied with sufficiently large viscosity of fluid. Finally, we show a continuous dependence result on the initial data which directly yields the weak-strong uniqueness of solutions. 展开更多
关键词 dynamical tensor Stokes parabolic nematic viscosity Navier estimates uniqueness proof
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Several Types of Similarity Solutions for the Hunter-Saxton Equation 被引量:2
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作者 Mathew Baxter Robert A.Van Gorder Kuppalapalle Vajravelu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2015年第6期675-681,共7页
We study separable and self-similar solutions to the Hunter-Saxton equation, a nonlinear wave equation which has been used to describe an instability in the director field of a nematic liquid crystal (among other app... We study separable and self-similar solutions to the Hunter-Saxton equation, a nonlinear wave equation which has been used to describe an instability in the director field of a nematic liquid crystal (among other applications). Essentially, we study solutions which arise from a nonlinear inhomogeneous ordinary differential equation which is obtained by an exact similarity transform for the ttunter-Saxton equation. For each type of solution, we are able to obtain some simple exact solutions in closed-form, and more complicated solutions through an analytical approach. We find that there is a whole family of self-similar solutions, each of which depends on an arbitrary parameter. This parameteressentially controls the manner of self-similarity and can be chosen so that the self-similar solutions agree with given initial data. The simpler solutions found constitute exact soIutions to a nonlinear partial differential equation, and hence are also useful in a mathematical sense. Analytical solutions demonstrate the variety of behaviors possible within the wider family of similarity solutions. Both types of solutions cast light on self-similar phenomenon arising in the Hunter-Saxton equation. 展开更多
关键词 Hunter-Saxton equation nonlinear waves self-similar solutions analytical methods exact solutions
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