陕西驾鹿金矿床发现40种含氧金矿物──地质产状、矿物组合与成因探讨

显微结构分析表明，驾鹿金矿床发现的４０种含氧金矿物主体与黄铁矿、碲金矿和石英共生，显然属于内生热液成因。依据金的地球化学行为，以及区内含氧金矿物富含Ｔｅ（１０％～２０％左右）和含不等量Ｍｎ的成分特征，分析认为该矿床成矿元素（Ａｕ）主要是在碲酸及硫酸溶液中并有氧化剂ＭｎＯ２存在的条件下迁移、富集成矿的。

Enhancement of bio-oxidation of refractory arsenopyritic gold ore by adding pyrolusite in bioleaching system

Pyrolusite was added in the bioleaching process to enhance the bio-oxidation process. Bioleaching tests at different dosages of pyrolusite ore, pH and inoculation amounts of Acidithiobacillus ferrooxidans were studied. The results showed that the time of the bio-oxidation process was decreased obviously and the arsenic leaching rate reached 94.4% after the bioleaching. The bio-oxidation of arsenopyrite and the effective extraction of manganese from pyrolusite were achieved by the bioleaching process. After bioleaching, the leaching rate of gold from the reaction residues reached 95.8% by cyanide leaching. In the bio-oxidation process, pyrolusite increased the redox potential of the solution to accelerate the bioleaching rate. The experiment showed that there were two reaction modes in the bioleaching process.

Mineralogical characterization and pretreatment for antimony extraction by ozone of antimony-bearing refractory gold concentrates

The mineralogical characterization of antimony-bearing refractory gold concentrates and the antimony extraction by ozonein HCl solution were investigated.The mineralogical study shows that there exist stibnite(Sb2S3),arsenopyrite(FeAsS),pyrite(FeS2)and quartz in the concentrates,and the gold is mainly(67.42%)encapsulated in sulfides.The antimony extraction by ozone inhydrochloric acid was employed and the influences of temperature,liquid/solid ratio,HCl concentration and stirring speed on theextraction of antimony were investigated.High antimony extraction(93.75%)is achieved under the optimized conditions.After thepretreatment by ozone,the antimony is recovered efficiently and the gold is enriched in the leaching residue.

Effect of chloride ion on bacterial pre-oxidation of arsenic-containing gold concentrate

The bacterial pre-oxidation process of arsenic-containing gold concentrates and the bacterial activity under different chloride ion concentrations were studied by using a mixture of thermophilic strains TCJ domesticated in production.The experimental result shows that with different samples and leaching systems,the adaptability and Cl- tolerance of bacteria are different,and that appropriate chloride ion concentration is conductive to bacterial oxidation,while higher chloride ion concentration will inhibit the bacterial activity and affect the pre-oxidation performance.Under the present production conditions,TCJ can adapt to the changes of water quality in the source of water and its critical chloride ion tolerance value is 2.7 g/L.

Effect of As(Ⅲ)on kinetics of Fe^(2+)bio-oxidation

Fe^(2+) bio-oxidation influenced by toxic metal ions released from the dissolution of arsenic-bearing gold ores was investigated.Fe^(2+) bio-oxidation by moderately thermophilic microorganisms was studied under different initial concentrations of Fe^(2+) and As(Ⅲ),and Monod equation was used to fit the Fe^(2+) bio-oxidation under different conditions.Results showed that the Fe^(2+) bio-oxidation rate increased as the initial Fe^(2+) concentration increased until it reached 12 g/L.As(Ⅲ)severely inhibited Fe^(2+) bio-oxidation.When the As(Ⅲ)concentration was 8 g/L,9 g/L Fe^(2+) was more than 200 h.The Monod equation fitted the Fe^(2+) bio-oxidation well.In the absence of As(Ⅲ),the maximum specific growth rate of the culture and the substrate affinity constant were 0.142 h^(−1) and 0.053 g/L,respectively.As(Ⅲ)inhibited Fe^(2+) bio-oxidation via competitive inhibition,and the inhibition constant was 0.0035 g/L.