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含重金属固废地聚合物的化学药剂改性及其机理初探 被引量:2
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作者 郭晓潞 伍亮 +1 位作者 张丽艳 施惠生 《建筑材料学报》 EI CAS CSCD 北大核心 2016年第6期976-982,共7页
以粉煤灰为主要原材料,分别单掺冶金污泥(MS)和城市垃圾焚烧飞灰(MSWIFA),制备了含重金属固废地聚合物,并引入化学药剂对其进行改性,同时进行了机理研究.结果表明:冶金污泥-粉煤灰(FS)地聚合物中冶金污泥的适宜处置量(质量分数,下同)为1... 以粉煤灰为主要原材料,分别单掺冶金污泥(MS)和城市垃圾焚烧飞灰(MSWIFA),制备了含重金属固废地聚合物,并引入化学药剂对其进行改性,同时进行了机理研究.结果表明:冶金污泥-粉煤灰(FS)地聚合物中冶金污泥的适宜处置量(质量分数,下同)为15%,最佳化学药剂为二硫代氨基甲酸盐(DTCR);城市垃圾焚烧飞灰-粉煤灰(FM)地聚合物中城市垃圾焚烧飞灰的适宜处置量为5%,最佳化学药剂为三巯基均三嗪三钠盐(TMT).化学药剂的掺入抑制了重金属的破坏作用,提高了地聚合反应程度,使产物结构更匀质、致密,提升了固化效果;采用DTCR改性、含15%MS的地聚合物试样FS-15-D和经TMT改性、含5%MSWIFA的地聚合物试样FM-5-T具有良好的抗酸碱侵蚀性能. 展开更多
关键词 地聚合物 粉煤灰 含重金属固废 化学药剂
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Environmental risk assessment on slag and iron-rich matte produced from reducing-matting smelting of lead-bearing wastes and iron-rich wastes 被引量:3
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作者 柴立元 吴见珣 +2 位作者 吴延婧 唐朝波 杨卫春 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第10期3429-3435,共7页
A new process for utilization of hazardous lead-bearing wastes and iron-rich wastes by reducing-matting smelting has been developed.The slag(SG) and the iron-rich matte(IRM) are the main by-products from reducing-... A new process for utilization of hazardous lead-bearing wastes and iron-rich wastes by reducing-matting smelting has been developed.The slag(SG) and the iron-rich matte(IRM) are the main by-products from reducing-matting smelting of lead-bearing wastes and iron-rich wastes.The environmental risk of heavy metals(Cd,Zn,Pb and As) in the main by-products versus the charging material for reducing-matting smelting(CM) has been systematically assessed using leaching toxicity test,the three-stage sequential extraction procedure of European Community Bureau of Reference(BCR) and Hakanson Potential Ecological Risk Index Method(PERI).The results demonstrate that the ecological risk level of heavy metals for SG and IRM is significantly reduced after the reducing-matting smelting process compared with that for CM. 展开更多
关键词 reducing-matting smelting lead-bearing waste heavy metal environmental risk
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