The roles of Zn content and thermo-mechanical treatment in affecting microstructures and mechanical properties of Mg-x%Zn-1%Mn（mass fraction,x=4,5,6,7,8,9） wrought Mg alloys were investigated.The microstructure was ...The roles of Zn content and thermo-mechanical treatment in affecting microstructures and mechanical properties of Mg-x%Zn-1%Mn（mass fraction,x=4,5,6,7,8,9） wrought Mg alloys were investigated.The microstructure was extremely refined by dynamic recrystallization（DRC） during extrusion.With increasing Zn content,the DRC grains tended to grow up,at the same time,more second phase streamlines would be present,which restricted the further growing.During solution treatment,the DRC grains would rapidly grow up;however,higher Zn content could hinder the grain boundary expanding,which results in finer ultimate grains.MgZn2 dispersoid particles which are coherent with the matrix would precipitate from the supersaturated solid solution during the one-step aging process,and nano-sized GP zones formed during the pre-aging stage of the two-step aging provide a huge amount of effective nuclei for the MgZn2 phases formed in the second stage,which makes the MgZn2 particles much finer and more dispersed.The mechanical properties of as-extruded samples were not so sensitive to the variation of Zn content,the tensile strength fluctuates between 300 and 320 MPa,and the elongation maintains a high value between 11% and 14%.The strength of aged samples rises as a parabolic curve with increasing Zn content,specifically,the tensile strength of one-step aged samples rises from 278 to 374 MPa,and that of two-step aged ones rises from 284 to 378 MPa,yet the elongation of all aged samples is below 8%.When Zn content exceeds its solid solution limit in Mg-Zn system（6.2%,mass fraction）,the strength rises slowly but the elongation deteriorates sharply,so a Mg-Zn-Mn alloy with 6% Zn possesses the best mechanical properties,that is,the tensile strengths after one-and two-step aging are 352 and 366 MPa,respectively,and the corresponding elongations are 7.98% and 5.2%,respectively.展开更多
Effects of Mg content on the microstructure and mechanical properties of low Zn-containing Al−xMg−3Zn−1Cu cast alloys(x=3−5,wt.%)were investigated.As Mg content increased in the as-cast alloys,the grains were refined ...Effects of Mg content on the microstructure and mechanical properties of low Zn-containing Al−xMg−3Zn−1Cu cast alloys(x=3−5,wt.%)were investigated.As Mg content increased in the as-cast alloys,the grains were refined due to enhanced growth restriction,and the formation ofη-Mg(AlZnCu)_(2) and S-Al_(2)CuMg phases was inhibited while the formation of T-Mg_(32)(AlZnCu)_(49 )phase was promoted when Mg content exceeded 4 wt.%.The increase of Mg content encumbered the solution kinetics by increasing the size of eutectic phase but accelerated and enhanced the age-hardening through expediting precipitation kinetics and elevating the number density of the precipitates.As Mg content increased,the yield strength and tensile strength of the as-cast,solution-treated and peak-aged alloys were severally improved,while the elongation of the alloys decreased.The tensile strength and elongation of the peak-aged Al−5Mg−3Zn−1Cu alloy exceed 500 MPa and 5%,respectively.Precipitation strengthening implemented by T′precipitates is the predominant strengthening mechanism in the peak-aged alloys and is enhanced by increasing Mg content.展开更多
In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cas...In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cast microstructure characteristics including grains and phases were thoroughly investigated. The results indicated that fine grain boundaries existed in these alloys and fine MgZn2phases discontinuously distributed on them. Besides,AlZnMgCu eutectic phases and Sc, Zr-containing phases with flocculent morphology were observed. As scandium contents vary from 0.06 wt.% to 0.17 wt.%, the average grain size continuously decreased and its equiaxial characteristics were strengthened. Meanwhile, the content of AlZnMgCu eutectic phase showed a decrease trend. When scandium contents were 0.20 wt.% and 0.25 wt.%, no further enhancement on grain refinement was observed, so as to the reduction of AlZnMgCu eutectic phase content. Besides, Sc, Zr-containing phases with blocky morphology were observed and the alloy with a scandium content of 0.25 wt.% possessed a larger amount of blocky Sc, Zr-containing phase than the alloy with a scandium content of 0.20 wt.%. Grain refinement and reduction of AlZnMgCu eutectic phase content associated with scandium addition were discussed.展开更多
Zn plays an important role in the protection of iron and steel from corrosion in sea water, and the alloying of Zn and Ni can improve its corrosion resistance. The corrosion behavior of Zn？Ni alloys in synthetic sea ...Zn plays an important role in the protection of iron and steel from corrosion in sea water, and the alloying of Zn and Ni can improve its corrosion resistance. The corrosion behavior of Zn？Ni alloys in synthetic sea water （3.5% NaCl, mass fraction） was studied using Tafel plot and electrochemical impedance spectroscopy （EIS） techniques. The corrosion resistance of the investigated alloys with various Ni contents （0.5%？10%, mass fraction） was compared with that of Zn. The results show that the corrosion resistance of Zn？Ni alloys （except 0.5% Ni） is superior to that of Zn. The 10% Ni gives the highest corrosion resistance due to the formation ofγ-Zn3Ni withγ-ZnNi phases in the alloy. In the case of alloy I （0.5% Ni）, it exhibits a higher corrosion rate （less corrosion resistance） than Zn.展开更多
Mangrove sediments were sampled form 14 main mangrove reserves of China. Concentrations of Cu, Pb, Zn, Cr and Cd were analyzed with a PE ICP-MS, and physical and physicochemical factors such as particle size distribut...Mangrove sediments were sampled form 14 main mangrove reserves of China. Concentrations of Cu, Pb, Zn, Cr and Cd were analyzed with a PE ICP-MS, and physical and physicochemical factors such as particle size distribution, pH, salinity and Total Organic Matter （TOM） were also determined. In the mangrove sediments of China, the average contents of heavy metals decreased in the order ofZn 〉 Pb 〉 Cu 〉 Cr 〉 Cd. The average contents of heavy metals were： Cu = 22.8 4- 16.46 mg/kg, Pb = 76.1 4- 52.33 mg/kg, Zn = 86.3 4- 42.65 mg/kg, Cr = 18.4 4- 5.83 mg/kg and Cd = 0.21 4- 0.25 mg/kg. Compared with previous studies, levels of heavy metals increased greatly. Contents of Cd, Cu, Pb and Zn were higher than the Background Values （BV）. However, the contents of Cr was under the BV. The results revealed that levels of heavy metals changes significantly with anthropogenic input, physical and physicochemical factors. Significant correlations were found between concentrations of Cu, Ph and pH, TOM.展开更多
Elements （vanadium and zinc） were determined in the two most abundant species of shell mollusks （Unio tigridis and Fiviparous bengalensis） and the water where they live in five stations in the Iraqi marshes. The s...Elements （vanadium and zinc） were determined in the two most abundant species of shell mollusks （Unio tigridis and Fiviparous bengalensis） and the water where they live in five stations in the Iraqi marshes. The study of concentrations elements was a target organ for aquatic environmental. Comparison between the mean concentrations of the elements in the water concentration levels of all studied elements was the highest with the mollusks. The results show that the station 5 is where the highest concentrations are found in water and in the two species. There is a significant correlation （P = 0.224） for concentrations of vanadium and P = 0.735 for zinc in two species of mollusks relative to their concentrations in surface water. All significant differences were accepted at a level of P 〈 0.05. The potential uptake of elements including V and Zn, as Viviparous bengalensi 〉 Unio tigridis, The mechanism for elements uptake determined by water for organisms confined to the contaminated areas seemed to be largely independent of species, mollusks demonstrated a significant positive relationship with water. These results have important implications for the utility of marshes biota as subjects for elements monitoring program.展开更多
The effects of Zn content on strength and wear performance of Al-12Si-3 Cu alloy synthesized by gravity casting were systematically investigated.The microstructure and mechanical properties of the alloys were evaluate...The effects of Zn content on strength and wear performance of Al-12Si-3 Cu alloy synthesized by gravity casting were systematically investigated.The microstructure and mechanical properties of the alloys were evaluated using OM,XRD,SEM as well as hardness,tension,compression and Charpy impact tests.Their dry sliding wear tests were carried out with a ball-on-disk tester.Microscopic examinations revealed that the microstructure of the base alloy consisted of theα(Al)dendrites,needle-type and coarse Si particles,and CuAl2(θ)phase.The addition of Zn to this alloy resulted in the formation ofα-solid solution phase and the increase of coarse Si particles.The hardness,yield,tensile and compressive strengths,elongation to fracture and impact toughness of the Al-12Si-3 Cu-Zn alloys increased with increasing Zn content,but tendency in the tensile and compressive strengths and ductility reversed after adding 1.5%-2%Zn.In addition,the friction coefficient and volume loss of the Al-12Si-3 Cu-Zn alloys decreased with increasing Zn content.The study showed that the addition of Zn to Al-12Si-3 Cu alloy can improve its potential applications as tribological material.展开更多
Zinc is common metal used for steel protection from corrosion.The addition of further element,such as Ni,can modify the corrosion rate and maintain sacrificial protection.The anodic dissolution behavior of Zn,Ni and Z...Zinc is common metal used for steel protection from corrosion.The addition of further element,such as Ni,can modify the corrosion rate and maintain sacrificial protection.The anodic dissolution behavior of Zn,Ni and Zn-Ni alloys with different Ni contents（from 0.5% to 10%,mass fraction） in 3.5% Na Cl solution was investigated using potentiodynamic,potentiostatic and galvanostatic techniques.The composition and microstructure of the corrosion layer on Zn,Ni and Zn-Ni alloys were characterized by energy-dispersive X-ray spectroscopy analysis（EDX） and scanning electron microscopy（SEM）.The galvanostatic curves show that the anodic behavior of all investigated electrodes exhibits active/passive transition and the tendency of the alloys to passivity decreases with the increase in Ni content,except for 99.5Zn-0.5Ni alloy.While the potentiodynamic curves exhibit active passive transition only for pure Zn.Surface analysis reveals the presence of oxides,chlorides and metal hydroxide chloride in corrosion products,and very small cracks are observed for 90Zn-10 Ni alloy compared with that of Zn.展开更多
基金Project(2007CB613700)supported by the National Basic Research Program of ChinaProject(2007BAG06B04)supported by the National Science and Technology Pillar Program During the 11th Five-Year Plan Period,China+1 种基金Project(50725413)supported by the National Natural Science Foundation of ChinaProject(CDJXS10132202)supported by the Fundamental Research Funds for the Central Universities,China
文摘The roles of Zn content and thermo-mechanical treatment in affecting microstructures and mechanical properties of Mg-x%Zn-1%Mn（mass fraction,x=4,5,6,7,8,9） wrought Mg alloys were investigated.The microstructure was extremely refined by dynamic recrystallization（DRC） during extrusion.With increasing Zn content,the DRC grains tended to grow up,at the same time,more second phase streamlines would be present,which restricted the further growing.During solution treatment,the DRC grains would rapidly grow up;however,higher Zn content could hinder the grain boundary expanding,which results in finer ultimate grains.MgZn2 dispersoid particles which are coherent with the matrix would precipitate from the supersaturated solid solution during the one-step aging process,and nano-sized GP zones formed during the pre-aging stage of the two-step aging provide a huge amount of effective nuclei for the MgZn2 phases formed in the second stage,which makes the MgZn2 particles much finer and more dispersed.The mechanical properties of as-extruded samples were not so sensitive to the variation of Zn content,the tensile strength fluctuates between 300 and 320 MPa,and the elongation maintains a high value between 11% and 14%.The strength of aged samples rises as a parabolic curve with increasing Zn content,specifically,the tensile strength of one-step aged samples rises from 278 to 374 MPa,and that of two-step aged ones rises from 284 to 378 MPa,yet the elongation of all aged samples is below 8%.When Zn content exceeds its solid solution limit in Mg-Zn system（6.2%,mass fraction）,the strength rises slowly but the elongation deteriorates sharply,so a Mg-Zn-Mn alloy with 6% Zn possesses the best mechanical properties,that is,the tensile strengths after one-and two-step aging are 352 and 366 MPa,respectively,and the corresponding elongations are 7.98% and 5.2%,respectively.
基金supported by the National Natural Science Foundation of China (Nos. 51674166, U1902220)the National Key R&D Program of China (No. 2021YFB3701303)。
文摘Effects of Mg content on the microstructure and mechanical properties of low Zn-containing Al−xMg−3Zn−1Cu cast alloys(x=3−5,wt.%)were investigated.As Mg content increased in the as-cast alloys,the grains were refined due to enhanced growth restriction,and the formation ofη-Mg(AlZnCu)_(2) and S-Al_(2)CuMg phases was inhibited while the formation of T-Mg_(32)(AlZnCu)_(49 )phase was promoted when Mg content exceeded 4 wt.%.The increase of Mg content encumbered the solution kinetics by increasing the size of eutectic phase but accelerated and enhanced the age-hardening through expediting precipitation kinetics and elevating the number density of the precipitates.As Mg content increased,the yield strength and tensile strength of the as-cast,solution-treated and peak-aged alloys were severally improved,while the elongation of the alloys decreased.The tensile strength and elongation of the peak-aged Al−5Mg−3Zn−1Cu alloy exceed 500 MPa and 5%,respectively.Precipitation strengthening implemented by T′precipitates is the predominant strengthening mechanism in the peak-aged alloys and is enhanced by increasing Mg content.
基金Projects(2020YFB0311400ZL, 2020YFF0218202) supported by the National Key R&D Program of ChinaProject supported by Youth Fund Project of GRINM Group Co.,Ltd.,China。
文摘In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cast microstructure characteristics including grains and phases were thoroughly investigated. The results indicated that fine grain boundaries existed in these alloys and fine MgZn2phases discontinuously distributed on them. Besides,AlZnMgCu eutectic phases and Sc, Zr-containing phases with flocculent morphology were observed. As scandium contents vary from 0.06 wt.% to 0.17 wt.%, the average grain size continuously decreased and its equiaxial characteristics were strengthened. Meanwhile, the content of AlZnMgCu eutectic phase showed a decrease trend. When scandium contents were 0.20 wt.% and 0.25 wt.%, no further enhancement on grain refinement was observed, so as to the reduction of AlZnMgCu eutectic phase content. Besides, Sc, Zr-containing phases with blocky morphology were observed and the alloy with a scandium content of 0.25 wt.% possessed a larger amount of blocky Sc, Zr-containing phase than the alloy with a scandium content of 0.20 wt.%. Grain refinement and reduction of AlZnMgCu eutectic phase content associated with scandium addition were discussed.
文摘Zn plays an important role in the protection of iron and steel from corrosion in sea water, and the alloying of Zn and Ni can improve its corrosion resistance. The corrosion behavior of Zn？Ni alloys in synthetic sea water （3.5% NaCl, mass fraction） was studied using Tafel plot and electrochemical impedance spectroscopy （EIS） techniques. The corrosion resistance of the investigated alloys with various Ni contents （0.5%？10%, mass fraction） was compared with that of Zn. The results show that the corrosion resistance of Zn？Ni alloys （except 0.5% Ni） is superior to that of Zn. The 10% Ni gives the highest corrosion resistance due to the formation ofγ-Zn3Ni withγ-ZnNi phases in the alloy. In the case of alloy I （0.5% Ni）, it exhibits a higher corrosion rate （less corrosion resistance） than Zn.
基金This project is supported by National Natural Science Foundation of China （No. 41176090）.
文摘Mangrove sediments were sampled form 14 main mangrove reserves of China. Concentrations of Cu, Pb, Zn, Cr and Cd were analyzed with a PE ICP-MS, and physical and physicochemical factors such as particle size distribution, pH, salinity and Total Organic Matter （TOM） were also determined. In the mangrove sediments of China, the average contents of heavy metals decreased in the order ofZn 〉 Pb 〉 Cu 〉 Cr 〉 Cd. The average contents of heavy metals were： Cu = 22.8 4- 16.46 mg/kg, Pb = 76.1 4- 52.33 mg/kg, Zn = 86.3 4- 42.65 mg/kg, Cr = 18.4 4- 5.83 mg/kg and Cd = 0.21 4- 0.25 mg/kg. Compared with previous studies, levels of heavy metals increased greatly. Contents of Cd, Cu, Pb and Zn were higher than the Background Values （BV）. However, the contents of Cr was under the BV. The results revealed that levels of heavy metals changes significantly with anthropogenic input, physical and physicochemical factors. Significant correlations were found between concentrations of Cu, Ph and pH, TOM.
文摘Elements （vanadium and zinc） were determined in the two most abundant species of shell mollusks （Unio tigridis and Fiviparous bengalensis） and the water where they live in five stations in the Iraqi marshes. The study of concentrations elements was a target organ for aquatic environmental. Comparison between the mean concentrations of the elements in the water concentration levels of all studied elements was the highest with the mollusks. The results show that the station 5 is where the highest concentrations are found in water and in the two species. There is a significant correlation （P = 0.224） for concentrations of vanadium and P = 0.735 for zinc in two species of mollusks relative to their concentrations in surface water. All significant differences were accepted at a level of P 〈 0.05. The potential uptake of elements including V and Zn, as Viviparous bengalensi 〉 Unio tigridis, The mechanism for elements uptake determined by water for organisms confined to the contaminated areas seemed to be largely independent of species, mollusks demonstrated a significant positive relationship with water. These results have important implications for the utility of marshes biota as subjects for elements monitoring program.
文摘The effects of Zn content on strength and wear performance of Al-12Si-3 Cu alloy synthesized by gravity casting were systematically investigated.The microstructure and mechanical properties of the alloys were evaluated using OM,XRD,SEM as well as hardness,tension,compression and Charpy impact tests.Their dry sliding wear tests were carried out with a ball-on-disk tester.Microscopic examinations revealed that the microstructure of the base alloy consisted of theα(Al)dendrites,needle-type and coarse Si particles,and CuAl2(θ)phase.The addition of Zn to this alloy resulted in the formation ofα-solid solution phase and the increase of coarse Si particles.The hardness,yield,tensile and compressive strengths,elongation to fracture and impact toughness of the Al-12Si-3 Cu-Zn alloys increased with increasing Zn content,but tendency in the tensile and compressive strengths and ductility reversed after adding 1.5%-2%Zn.In addition,the friction coefficient and volume loss of the Al-12Si-3 Cu-Zn alloys decreased with increasing Zn content.The study showed that the addition of Zn to Al-12Si-3 Cu alloy can improve its potential applications as tribological material.
文摘Zinc is common metal used for steel protection from corrosion.The addition of further element,such as Ni,can modify the corrosion rate and maintain sacrificial protection.The anodic dissolution behavior of Zn,Ni and Zn-Ni alloys with different Ni contents（from 0.5% to 10%,mass fraction） in 3.5% Na Cl solution was investigated using potentiodynamic,potentiostatic and galvanostatic techniques.The composition and microstructure of the corrosion layer on Zn,Ni and Zn-Ni alloys were characterized by energy-dispersive X-ray spectroscopy analysis（EDX） and scanning electron microscopy（SEM）.The galvanostatic curves show that the anodic behavior of all investigated electrodes exhibits active/passive transition and the tendency of the alloys to passivity decreases with the increase in Ni content,except for 99.5Zn-0.5Ni alloy.While the potentiodynamic curves exhibit active passive transition only for pure Zn.Surface analysis reveals the presence of oxides,chlorides and metal hydroxide chloride in corrosion products,and very small cracks are observed for 90Zn-10 Ni alloy compared with that of Zn.
