The analytic response theory at density functional theory level is applied to investigate onephoton and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical res...The analytic response theory at density functional theory level is applied to investigate onephoton and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical results show that there are a few charge-transfer states for each compound in the lower energy region. The one-photon absorption properties of the five investigated compounds are highly consistent with those given by experimental measurements. The two-photon absorption intensities of the compounds are greatly enhanced with the increments of the molecular sizes, in which the two-photon absorption cross section of the four-branched compound is about 5.6 times of that of the mono-branched molecule. Fhrthermore, it is shown that the two-photon absorption properties are sensitive to the geometrical arrangements.展开更多
By numerically solving the Maxwell-Bloch equations using an iterative predictor-corrector finite-difference time-domain technique, we investigate propagating properties of a few-cycle laser pulse in a 4,4＇-bis（di-n-...By numerically solving the Maxwell-Bloch equations using an iterative predictor-corrector finite-difference time-domain technique, we investigate propagating properties of a few-cycle laser pulse in a 4,4＇-bis（di-n-butylamino） stilbene （BDBAS） molecular medium when a static electric field exists. Dynamical two-photon absorption （TPA） cross sections are obtained and optical limiting （OL） behavior is displayed. The results show that when the static electric field intensity increases, the dynamical TPA cross section is enhanced and the OL behavior is improved. Moreover, both even- and odd-order harmonic spectral components are generated with existence of the static electric field because it breaks the inversion symmetry of the BDBAS molecule. This work provides a method to modulate the nonlinear optical properties of the BDBAS compounds.展开更多
Using an excitonic basis, we investigate the intraband polarization, optical absorption spectra, and terahertzemission of semiconductor superlattice with the density matrix theory. The excitonic Bloch oscillation is d...Using an excitonic basis, we investigate the intraband polarization, optical absorption spectra, and terahertzemission of semiconductor superlattice with the density matrix theory. The excitonic Bloch oscillation is driven by thedc and ac electric fields. The slow variation in the intraband polarization depends on the ac electric field frequency. Theintraband polarization increases when the ac electric field frequency is below the Bloch frequency. When the ac electricfield frequency is above the Bloch frequency, the intraband polarization downwards and its intensity decreases. Thesatellite structures in the optical absorption spectra are presented. Due to excitonic dynamic localization, the emissionlines of terahertz shift in different ac electric field and dc electric field.展开更多
If a coherent perturbation field is used to couple the excited level of the coupling transition in the five-level K-type atom with another higher excited level, the two-photon electromagnetically induced transparency ...If a coherent perturbation field is used to couple the excited level of the coupling transition in the five-level K-type atom with another higher excited level, the two-photon electromagnetically induced transparency can be locally modulated by altering the parameters of the additional perturbation field. With different detunings of the coherent perturbation field, the absorption peak or transparency window with sharp and high-contrast speetrM feature can be generated in the two-photon absorption spectrum. The physical interpretation of these phenomena is given in terms of the dressed states.展开更多
文摘The analytic response theory at density functional theory level is applied to investigate onephoton and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical results show that there are a few charge-transfer states for each compound in the lower energy region. The one-photon absorption properties of the five investigated compounds are highly consistent with those given by experimental measurements. The two-photon absorption intensities of the compounds are greatly enhanced with the increments of the molecular sizes, in which the two-photon absorption cross section of the four-branched compound is about 5.6 times of that of the mono-branched molecule. Fhrthermore, it is shown that the two-photon absorption properties are sensitive to the geometrical arrangements.
文摘By numerically solving the Maxwell-Bloch equations using an iterative predictor-corrector finite-difference time-domain technique, we investigate propagating properties of a few-cycle laser pulse in a 4,4＇-bis（di-n-butylamino） stilbene （BDBAS） molecular medium when a static electric field exists. Dynamical two-photon absorption （TPA） cross sections are obtained and optical limiting （OL） behavior is displayed. The results show that when the static electric field intensity increases, the dynamical TPA cross section is enhanced and the OL behavior is improved. Moreover, both even- and odd-order harmonic spectral components are generated with existence of the static electric field because it breaks the inversion symmetry of the BDBAS molecule. This work provides a method to modulate the nonlinear optical properties of the BDBAS compounds.
基金Supported by National Science Foundation of China under Grant No.10647132the Scientific Research Fund of Hunan Provincial Education Department under Grant No.05B014
文摘Using an excitonic basis, we investigate the intraband polarization, optical absorption spectra, and terahertzemission of semiconductor superlattice with the density matrix theory. The excitonic Bloch oscillation is driven by thedc and ac electric fields. The slow variation in the intraband polarization depends on the ac electric field frequency. Theintraband polarization increases when the ac electric field frequency is below the Bloch frequency. When the ac electricfield frequency is above the Bloch frequency, the intraband polarization downwards and its intensity decreases. Thesatellite structures in the optical absorption spectra are presented. Due to excitonic dynamic localization, the emissionlines of terahertz shift in different ac electric field and dc electric field.
基金Supported by National Natural Science Foundation of China under Grant Nos.10775100 and 10974137
文摘If a coherent perturbation field is used to couple the excited level of the coupling transition in the five-level K-type atom with another higher excited level, the two-photon electromagnetically induced transparency can be locally modulated by altering the parameters of the additional perturbation field. With different detunings of the coherent perturbation field, the absorption peak or transparency window with sharp and high-contrast speetrM feature can be generated in the two-photon absorption spectrum. The physical interpretation of these phenomena is given in terms of the dressed states.
